| Budget Amount *help |
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
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| Outline of Final Research Achievements |
The sandwich structures is one of the most important molecular designs for transition metal compounds. In this project, we aimed at developing the structural concept of sandwich compounds containing metal sheet clusters. We found that an eight-membered carbocylce, cyclooctatetraene, has the ability to stabilize the metal sheet sandwich clusters with cyclopentadienyl- or vinylarene counter-ligands. Furthermore, we also elucidated the coordination behavior of hetero-arenes to transition metals.
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