| Budget Amount *help |
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2017: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2016: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
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| Outline of Final Research Achievements |
The purposes of this research project is development of novel enantioselective synthetic methods of various chiral transition-metal complexes utilizing well-developed stereoselective organic transformations. The target complexes in this study are potential chiral catalysts, and thus, application of the products in the subsequent "second" asymmetric reactions as chiral catalysts or chiral ligands was also examined. The stereoselective organic transformations used in this study are mainly transition-metal-catalyzed asymmetric reactions, but other stoichiometric asymmetric processes are also used. Through this study, we have successfully established multiple methods of preparing various planar-chiral transition-metal complexes in highly enantiomerically enriched forms.
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