| Budget Amount *help |
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2017: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2016: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
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| Outline of Final Research Achievements |
A number of recent studies have addressed the issue of the synthesis of sequence-regulated polymers. Over the years, an enormous amount of research has been devoted to controlling monomer sequences on polymer backbones. However, it is still challenging to control the monomer sequences on graft-copolymers and ABC-terpolymers. We set out that the use of supramolecular interactions allows access to control the monomer sequence on graft-copolymers and ABC-terpolymers. To examine the hypothesis, we chose silver bridged self-assembled capsule-biphenyl, calix[5]arene(C5A)-C60, bisporphyrin(bisPor)-trinitrofluorenone(TNF) complexes that were investigated by our group. The selective binding of the capsule to a biphenyl, C5A to C60 and bisPor to TNF precisely conducted the monomer sequence regulation on polymer backbones.
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