Chiral Covelane Framework with Macroscopically Oriented Structure
| Project/Area Number |
15H03820
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Institute of Physical and Chemical Research |
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Principal Investigator |
Yasuhiro Ishida 国立研究開発法人理化学研究所, 創発物性科学研究センター, チームリーダー (20343113)
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| Co-Investigator(Renkei-kenkyūsha) |
HASHIZUME Daisuke 国立研究開発法人理化学研究所, 創発物性科学研究センター, ユニットリーダー (00293126)
ARAOKA Fumito 国立研究開発法人理化学研究所, 創発物性科学研究センター, ユニットリーダー (10467029)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2015: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
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| Keywords | 液晶 / 有機ゼオライト / キラリティ / 配向 / 多孔性材料 / 非線形光学 / 光学分割 / ナノ材料 / 高分子合成 / 分子認識 / 自己組織化 / 複合材料・物性 |
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| Outline of Final Research Achievements |
We have studied on a porous polymer synthesized by the template polymerization of the salt of a polymerizable carboxylic acid and a chiral amine. Recently, we established a method to prepare films of the porous polymer in which the chiral pores are unidirectionally oriented over ~10 cm2. In the present study, we studied on the structure and functions of the porous polymer with a macroscopically oriented configuration. Thus, we obtained the detailed structure of the porous polymer using a method similar to single crystal X-ray study. In addition, we also found that the porous polymer works as a template to align a p-nitroaniline derivative that exhibit notable nonlinear optical properties, as was as a medial for the enantio-separation of the racemic form of the template chiral amine.
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Report
(4 results)
Research Products
(30 results)
