| Budget Amount *help |
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2015: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
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| Outline of Final Research Achievements |
We have studied on a porous polymer synthesized by the template polymerization of the salt of a polymerizable carboxylic acid and a chiral amine. Recently, we established a method to prepare films of the porous polymer in which the chiral pores are unidirectionally oriented over ~10 cm2. In the present study, we studied on the structure and functions of the porous polymer with a macroscopically oriented configuration. Thus, we obtained the detailed structure of the porous polymer using a method similar to single crystal X-ray study. In addition, we also found that the porous polymer works as a template to align a p-nitroaniline derivative that exhibit notable nonlinear optical properties, as was as a medial for the enantio-separation of the racemic form of the template chiral amine.
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