| Project/Area Number |
15H03851
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Energy-related chemistry
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| Research Institution | Tokyo University of Science |
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Principal Investigator |
Tadokoro Makoto 東京理科大学, 理学部第一部化学科, 教授 (60249951)
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| Co-Investigator(Kenkyū-buntansha) |
松井 広志 東北大学, 理学研究科, 准教授 (30275292)
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| Co-Investigator(Renkei-kenkyūsha) |
ISODA Kyousuke 東京理科大学, 理学部, 助教 (20568620)
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| Research Collaborator |
Suzuki YOU
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2017: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
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| Keywords | nanoporous crystal / water cluster / gas hydrate / methane hydrate / nanofluidics / ionic conductivity / Solid-state NMR / メタンハイドレート / 水クラスター / 分子性ナノ細孔 / 電解質溶液 / 水素結合 / Ru錯体 / キセノンハイドレート / イオン伝導度 / 水ナノクラスター / ナノフルイディクス / プロトン伝導 / イオン伝導 / クラスレートハイドレート / 固体ＮＭＲ / Xeハイドレート / 分子ナノフルイディクス / 水和イオン / ナノ多孔質結晶 / 超分子結晶 / ナノ分子流体 / イオンハイドレート / ガスハイドレート / 超分子 |
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| Outline of Final Research Achievements |
The 1-D water nanotube-like cluster (WNT) stabilized by channel pores in a nanoporous molecular crystal can confine some gases as methane and xenon. Their WNT forms a gas hydrate stabilized even at room temperature and in the high pressure at ~20 atm, we have found that they reversibly can take and release a great deal of methane and xenon gas. Meanwhile, when the electrolytic ions are confined to WNT, the ionic conductivity is as high as that in bulk aqueous solution. That is the reason why the coherent interaction would be probably caused of the electrolytic ions with 1-D regular arrays.
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