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AFM observation of the dynamics of polymer blend monolayers

Research Project

Project/Area Number 15H03861
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionYamagata University

Principal Investigator

Kumaki Jiro  山形大学, 大学院有機材料システム研究科, 教授 (00500290)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2017: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2015: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Keywords高分子の構造・物性 / 走査プローブ顕微鏡 / 高分子超薄膜 / ナノ材料 / 表面・界面物性 / 高分子構造・物性 / 超薄膜 / 表面・界面特性 / 原子間力顕微鏡
Outline of Final Research Achievements

Polymers are generally composed of long flexible chains, and the structures and dynamics of these flexible chains determine the properties of polymer materials. Using atomic force microscopy (AFM), movements of isolated polymer chains on substrates have been observed at a molecular level, however, those in aggregates such as solids or melts have not been visualized, yet. In this work, we visualized movements of isolated chains solubilized in Langmuir-Blodgett (LB) films under high humidity, and found that the movements of the chains were strongly affected by the nature of matrix polymers. We also successfully observed the formation of a stereocomplex from isolated chains which were solubilized in LB films.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (29 results)

All 2018 2017 2016 2015 Other

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (22 results) (of which Int'l Joint Research: 6 results,  Invited: 9 results) Remarks (3 results)

  • [Journal Article] Molecular Combing of a Flexible Polymer Chain by Simple Spin Casting2018

    • Author(s)
      Chisato Shimanuki, Yuuma Matsuta, Ryo Fujita, Jiro Kumaki
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 4 Pages: 3983-3990

    • DOI

      10.1021/acsomega.8b00325

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 単分子膜を用いた高分子鎖構造の原子間力顕微鏡観察の進展2017

    • Author(s)
      熊木治郎
    • Journal Title

      高分子

      Volume: 66 Pages: 567-571

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Journal Article] Morphology Control Through Hierarchical Phase Separation in Langmuir Monolayers of Poly(methyl methacrylate)-b-Poly(n-butyl acrylate)2017

    • Author(s)
      Atsushi Watanabe, Jiro Kumaki
    • Journal Title

      J. Colloid Interface Sci.

      Volume: 486 Pages: 316-324

    • DOI

      10.1016/j.jcis.2016.10.004

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Observation of Polymer Chain Structures in Two-Dimensional Films by Atomic Force Microscopy2016

    • Author(s)
      Jiro Kumaki
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 1 Pages: 3-14

    • DOI

      10.1038/pj.2015.67

    • NAID

      40020685211

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] AFMを用いた高分子鎖構造の直接観察2018

    • Author(s)
      熊木治郎
    • Organizer
      平成29年度東海シンポジウム(高分子学会東海支部)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Visualization of Polymer Chain Structures in Two-Dimensional Films by Atomic Force Microscopy2018

    • Author(s)
      Jiro Kumaki
    • Organizer
      2018 Special Seminar Series (The University of Akron)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 基板上に展開するブレンド融液中の高分子孤立鎖のin-situ AFM観察2017

    • Author(s)
      渡邉康宏、熊木治郎
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Visualization of Polymer Chain Structures in Two-Dimensional Films by Atomic Force Microscopy2017

    • Author(s)
      Jiro Kumaki
    • Organizer
      Japan-Taiwan Bilateral Polymer Symposium (JTBPS 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Polymer Chain Structures Observed by Atomic Force Microscopy2017

    • Author(s)
      Jiro Kumaki
    • Organizer
      Workshop: Recent Advances in Polymer Dynamics and Crystallization, University of Freiburg
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystallization Behavior of Polymer Langmuir Monolayers Observed by High-Resolution Atomic Force Microscopy2017

    • Author(s)
      Kenta Iwashima, Kenji Watanabe, Jiro Kumaki
    • Organizer
      International Discussion Meeting on Polymer Crystallization 2017 (IDMPC 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単分子膜を用いた高分子結晶の高分解能原子間力顕微鏡観察2017

    • Author(s)
      熊木治郎
    • Organizer
      第26回有機結晶シンポジウム(日本化学会有機結晶部会)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 平行、逆平行型環状ポリ乳酸ステレオブロック共重合体の単分子膜中でのステレオコンプレックス形成挙動AFM観察2016

    • Author(s)
      岩島健太、石原智美、手塚育志、山本拓矢、熊木治郎
    • Organizer
      2016高分子学会東北支部研究発表会
    • Place of Presentation
      山形大学工学部(米沢)
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 基板上に展開するブレンド融液中の高分子孤立鎖のin-situ AFM観察2016

    • Author(s)
      渡邉康宏、一戸捷人、熊木治郎
    • Organizer
      2016高分子学会東北支部研究発表会
    • Place of Presentation
      山形大学工学部(米沢)
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] 平行、逆平行型環状ポリ乳酸ステレオブロック共重合体の単分子膜中でのコンプレックス形成挙動AFM観察2016

    • Author(s)
      岩島健太、石原智美、手塚育志、山本拓矢、熊木治郎
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 基板上に展開するブレンド融液中の高分子孤立鎖のin-situ AFM観察2016

    • Author(s)
      渡邉康宏、一戸捷人、熊木治郎
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ブレンドLB単分子膜に可溶化した高分子孤立鎖の運動挙動AFM観察2016

    • Author(s)
      大友政明、熊木治郎
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 合成高分子鎖の原子間力顕微鏡観察2016

    • Author(s)
      熊木治郎
    • Organizer
      16-1 高分子学会高分子基礎物性研究会(高分子1分子計測と基礎物性)
    • Place of Presentation
      京都テレサ(京都)
    • Year and Date
      2016-07-25
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 高分子ブレンド単分子膜中の高分子鎖の運動挙動観察2016

    • Author(s)
      大友政明、熊木治郎
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(神戸)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 平行、逆平行型環状ポリ乳酸ステレオブロック共重合体の水面上でのステレオコンプレックス形成挙動2016

    • Author(s)
      岩島健太、石原智美、手塚育志、山本拓矢、熊木治郎
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(神戸)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Evaluation of the End-to-End Distance of Chains Solubilized in a Polymer Langmuir Monolayer by Atomic Force Microscopy2016

    • Author(s)
      Jiro Kumaki
    • Organizer
      American Physical Society (APS) March Meeting 2016
    • Place of Presentation
      Baltimore Convention Center (Maryland, USA)
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子鎖構造の高分解能原子間力顕微鏡観察2016

    • Author(s)
      熊木治郎
    • Organizer
      平成28年東北ポリマー懇話会総会講演会
    • Place of Presentation
      盛岡市産学官連携研究センター(岩手)
    • Year and Date
      2016-01-28
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 高分子ブレンド単分子膜中の高分子鎖の運動挙動観察2015

    • Author(s)
      大友政明、熊木治郎
    • Organizer
      2015高分子学会東北支部研究発表会
    • Place of Presentation
      秋田大学(秋田)
    • Year and Date
      2015-11-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] Visualization of the End-to-End Distance of Chains in a Polymer Langmuir Monolayer2015

    • Author(s)
      Fumiki Honma, Kenta Iwashima, Jiro Kumaki
    • Organizer
      IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering (APME2015)
    • Place of Presentation
      Pacifico Yokohama (Yokohama)
    • Year and Date
      2015-10-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Visualization of Polymer Chain Structures by AFM Using Their Two-Dimensional Films2015

    • Author(s)
      Jiro Kumaki
    • Organizer
      Yamagata University-France-Brazil Advanced Polymer Chemistry Symposium in Yonezawa
    • Place of Presentation
      Yamagata University (Yonezawa)
    • Year and Date
      2015-06-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 孤立鎖状態からのPMMAステレオコンプレックス形成挙動観察2015

    • Author(s)
      影山諒、熊木治郎
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(札幌)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高分子鎖構造の高分解能原子間力顕微鏡観察2015

    • Author(s)
      熊木治郎
    • Organizer
      第346回ゴム技術フォーラム月例会講演
    • Place of Presentation
      東部ビル(東京)
    • Year and Date
      2015-04-03
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Remarks] 山形大学 熊木研究室

    • URL

      http://kumaki-lab.yz.yamagata-u.ac.jp/index.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 山形大学教員情報

    • URL

      http://yudb.kj.yamagata-u.ac.jp/html/100000173_ja.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report 2015 Annual Research Report
  • [Remarks] 山形大学 熊木研究室

    • URL

      http://kumaki-lab.yz.yamagata-u.ac.jp

    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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