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Preparation of superstrong and transparent films using truxillic acid as a molecular spring

Research Project

Project/Area Number 15H03864
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

Kaneko Tatsuo  北陸先端科学技術大学院大学, 先端科学技術研究科, 教授 (20292047)

Co-Investigator(Kenkyū-buntansha) 桶葭 興資  北陸先端科学技術大学院大学, 先端科学技術研究科, 講師 (50557577)
Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Keywords透明樹脂 / バイオプラスチック / 高分子合成 / 分子設計 / パイ電子 / シクロブタン / 高性能高分子 / ポリアミド / 光反応 / 分子バネ / 構造物性 / バイオベースポリマー / 力学物性 / 芳香族 / 脂環 / 光二量化 / 芳香族ポリマー
Outline of Final Research Achievements

The synthesis of various aromatic polyamides (aramids) was carried out using truxillic/truxinic acid derivatives. In particular, it was found to proceed polymerization for aramids including an α-type having a bending angle of 156 degree and a δ-type structure having a bending angle of about 101 degree and their transparent film were obtained. On the other hand, polymerization and molding were difficult for β-type having a bending angle of about 70 degree. As a result, the α-type and δ-type structures provided well-balanced transparent films having both transparency and thermal/mechanical properties.

Academic Significance and Societal Importance of the Research Achievements

有機ガラスは軽量で安全なガラスとして従来の無機ガラスに取って代わる重要な材料である。一方、既存の有機ガラスは透明であるがゆえに分子間力が小さくその熱的力学的物性が低い。そこで、本研究では剛直構造を維持しつつ着色のしにくいトルキシン酸構造を積極的に取り入れた。その結果、屈曲角の小さいα型トルキシン酸と屈曲角が中程度のδ型トルキシニン酸を導入することが重合性、成型性、物性の観点から優れた有機ガラスを与えることが分かった。これにより、軽量な透明材料が得られ建材や輸送機器の窓剤などへの応用研究につながると考えられる。

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (36 results)

All 2019 2018 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (2 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (30 results) (of which Int'l Joint Research: 15 results,  Invited: 7 results) Book (2 results)

  • [Int'l Joint Research] VISTEC(タイ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Jiangnan university(中国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Fluorinated and Bio-Based Polyamides with High Transparencies and Low Yellowness Index2018

    • Author(s)
      Kenji Takada, Yuko Mae, Tatsuo Kaneko
    • Journal Title

      polymers

      Volume: 10 Issue: 12 Pages: 1311-1311

    • DOI

      10.3390/polym10121311

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Ultra-strong, transparent polytruxillamides derived from microbial photodimers2016

    • Author(s)
      Seiji Tateyama, Shunsuke Masuo, Phruetchika Suvannasara, Yuuki Oka, Akio Miyazato, Katsuaki Yasaki, Thapong Teerawatananond, Nongnuj Muangsin, Shengmin Zhou, Yukie Kawasaki, Longbao Zhu, Zhemin Zhou, Naoki Takaya,Tatsuo Kaneko
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 9 Pages: 3336-3342

    • DOI

      10.1021/acs.macromol.6b00220

    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 屈曲型4-アミノ桂皮酸二量体から設計したバイオベースポリアミドの構造物性相関2019

    • Author(s)
      野田拓海・高田健司・金子達雄
    • Organizer
      18-3 エコマテリアル研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 4-アミノ桂皮酸由来水溶性バイオポリアミドの合成と物性評価2019

    • Author(s)
      舟橋靖芳・高田健司・金子達雄
    • Organizer
      18-3 エコマテリアル研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Superhigh performance bioplastics having deformable rigid backbone2019

    • Author(s)
      Tatsuo Kaneko
    • Organizer
      JWC2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Macromolecular design of high-performance, degradable plastics2019

    • Author(s)
      Tatsuo Kaneko
    • Organizer
      VISTEC seminar
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organic glass innovation made by white-biotechnology2019

    • Author(s)
      Tatsuo Kaneko
    • Organizer
      Mini-Symposium in Macromolecular Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Exotic Amino Acids Leading to Water-Soluble High-Performance Polymers2019

    • Author(s)
      Tatsuo Kaneko
    • Organizer
      Seminar for Chulalongkorn University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 桂皮酸誘導体をベースとした高性能バイオプラスチックの開発2018

    • Author(s)
      Kenji Takada, Tatsuo Kaneko
    • Organizer
      第67回 高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミノ酸誘導体のビルディングブロックを利用したバイオベースポリマーの分子設計2018

    • Author(s)
      Kenji Takada, Tatsuo Kaneko
    • Organizer
      第67回 高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] キラルな桂皮酸二量体を用いた芳香族バイオベースポリマーの合成と熱力学物性2018

    • Author(s)
      野田拓海・奥田淳也・高田健司・金子達雄
    • Organizer
      第67回 高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 微生物産生資源を用いた高透明・高耐熱性材料の開発2018

    • Author(s)
      野田拓海
    • Organizer
      第1回COI学会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 屈曲型桂皮酸二量体の光学分割と芳香族バイオベースポリマーの合成2018

    • Author(s)
      野田拓海・奥田淳也・高田健司・金子達雄
    • Organizer
      第67回 高分子学会北陸支部研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 4-アミノ桂皮酸由来バイオポリアミド共重合体のフィルム化と光・力学物性2018

    • Author(s)
      舟橋靖芳・吉中陽平・高田健司・金子達雄
    • Organizer
      第67回 高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 4-アミノ桂酸由来水溶性ポリアミドの合成と光学物性評価2018

    • Author(s)
      舟橋靖芳・高田健司・金子達雄
    • Organizer
      平成30年度 高分子若手研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] How to create bioplastics having degradability and durability2018

    • Author(s)
      Tatsuo Kaneko
    • Organizer
      Jiangnan Univ seminar
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structural-property relationships of bio-based polyamides with super-high mechanical toughness2018

    • Author(s)
      Yohei Yoshianka, Seiji Tateyama, Kenji Takada, Yasuyoshi Funahashi, Tatsuo Kaneko
    • Organizer
      255th ACS National Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Syntheses of bio-based co-polyamides with high mechanical properties from 4-aminociannamic acid2017

    • Author(s)
      Yohei Yoshinaka, Seiji Tateyama, and Tatsuo Kaneko
    • Organizer
      International Conference on Bio-based Plastics (ICBP 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Molecular design of bio-based polyamides with super-high mechanical toughness and structure-property relationships2017

    • Author(s)
      Yohei Yoshinaka, Seiji Tateyama, and Tatsuo Kaneko
    • Organizer
      JSPS-kick off Symposium Japan-South-East Asia Collaboration Hub of Bioplastics by JSPS
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Syntheses of high performance, transparent bio-polyamides from modified cinnamic acid photodimers2017

    • Author(s)
      Yuko Mae, Seiji Tateyama, Tatsuo Kaneko
    • Organizer
      JSPS-kick off Symposium Japan-South-East Asia Collaboration Hub of Bioplastics by JSPS
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Biopolyimide films and their silica composites with advanced mechanical and optoelectrical properties2017

    • Author(s)
      Shigeki Sakamoto, Sumant Dwivedi, Tatsuo Kaneko
    • Organizer
      JSPS-kick off Symposium Japan-South-East Asia Collaboration Hub of Bioplastics by JSPS
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Strong Organic Acid-Catalyzed Precise Synthesis of Acrylate Polymers2017

    • Author(s)
      Kenji Takada, Tatsuo Kaneko, Toshifumi Satoh, Toyoji Kakuchi
    • Organizer
      Satellite Symposium "Japan-South-East Asia Collaboration Hub of Bioplastics Study" JSPS-Core-to-Core Program
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Molecular design of bio-based polyamides with super-high mechanical toughness and structure-property relationships2017

    • Author(s)
      Yohei Yoshinaka, Seiji Tateyama, Kenji Takada, and Tatsuo Kaneko
    • Organizer
      第66回 高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 桂皮酸光二量体の化学修飾と高性能高透明性バイオベースポリアミドの合成2017

    • Author(s)
      前侑享・立山誠治・金子達雄
    • Organizer
      第66回 高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Eco-friendly organocatalytic precise synthesis of polyacrylates2017

    • Author(s)
      Kenji Takada, Toyoji Kakuchi, Tatsuo Kaneko
    • Organizer
      3rd Symposium of the Center for Nature-derived Materials (Excellent Core)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of bio-based polyamide fibers with high mechanical toughness2017

    • Author(s)
      Yohei Yoshinaka, Seiji Tateyama, Kenji Takada and Tatsuo Kaneko
    • Organizer
      International symposium on green technology for value chains 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Syntheses of optically-active δ-truxinic acid derivatives and its polymerization to prepare aromatic bio-based polyamides2016

    • Author(s)
      Jun-ya OKUDA, Seiji TATEYAMA, Tatsuo KANEKO
    • Organizer
      IPC2016
    • Place of Presentation
      福岡国際会議場(福岡県福岡市)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] バイオベース光学活性δ-トルキシン酸誘導体を用いたポリアミド合成2016

    • Author(s)
      奥田淳也・立山誠治・金子達雄
    • Organizer
      第24回芳香族・ポリイミド会議
    • Place of Presentation
      石川ハイテク交流センター(石川県能美市)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Syntheses and polymerization of optically-active derivatives of bio-based d-truxinic acid2016

    • Author(s)
      Jun-ya OKUDA, Seiji TATEYAMA, Tatsuo KANEKO
    • Organizer
      BICON 2016
    • Place of Presentation
      ジャイプール(インド)
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Syntheses of bio-base aromatic polyimides from mellophanic dianhydride,2016

    • Author(s)
      KARIKOME, Satoru; IBUKI, Yusuke; MAETANI, Shiho; TATEYAMA, Seiji; KANEKO Tatsuo
    • Organizer
      日本化学会第96回春季年会
    • Place of Presentation
      同志社大学, 京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Optical Resolution of d-Truxinic Acid Derivatives and Synthesis of Aromatic Bio-based Polyamide,2016

    • Author(s)
      OKUDA, Junya; MAETANI, Shiho; TATEYAMA, Seiji; KANEKO, Tatsuo
    • Organizer
      日本化学会第96回春季年会
    • Place of Presentation
      同志社大学, 京田辺キャンパス(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] トルキシン酸誘導体を用いたバイオポリアミドの合成2015

    • Author(s)
      奥田淳也、前谷枝保、立山誠治、金子達雄
    • Organizer
      平成27年度北陸地区高分子若手研究会
    • Place of Presentation
      石川ハイテク交流センター(石川県能美市)
    • Year and Date
      2015-11-14
    • Related Report
      2015 Annual Research Report
  • [Book] 次世代のポリマー・高分子開発、新しい用途展開と将来展望2019

    • Author(s)
      高田健司、金子達雄
    • Total Pages
      608
    • Publisher
      株式会社技術情報協会
    • ISBN
      9784861047381
    • Related Report
      2018 Annual Research Report
  • [Book] 高耐熱高分子材料の最新技術動向2018

    • Author(s)
      高田健司、金子達雄
    • Total Pages
      248
    • Publisher
      シー・エム・シー出版
    • ISBN
      9784781313436
    • Related Report
      2018 Annual Research Report

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Published: 2015-04-16   Modified: 2020-03-30  

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