Development of methods for lithium self-diffusion coefficient measurements in mixed conductors using isotope exchange
| Project/Area Number |
15H03872
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Tohoku University |
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Principal Investigator |
Kuwata Naoaki 東北大学, 多元物質科学研究所, 准教授 (00396459)
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| Co-Investigator(Renkei-kenkyūsha) |
KAWAMURA JUNICHI 東北大学, 多元物質科学研究所, 教授 (50142683)
MIYAZAKI TAKAMICHI 東北大学, 工学研究科, 技術職員 (20422090)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2017: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2015: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
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| Keywords | 混合伝導体 / 拡散係数 / 空孔拡散機構 / LiCoO2 / LiMn2O4 / 二次イオン質量分析 / 全固体電池 / インターカレーション / 同位体交換 / 化学拡散係数 / 化学ポテンシャル / リチウムイオン電池 / 混合導電体 / 固体イオニクス / トレーサー拡散係数 / 薄膜リチウム電池 / 同位体 / 二次電池 / イオニクス / 薄膜電池 / イオン交換 / 固体電解質 |
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| Outline of Final Research Achievements |
Lithium-ion battery electrode materials are mixed conductors which have significant conduction of both ionic and electronic. It is proved that a measurement of lithium diffusion coefficient in the mixed conductors is difficult, and the method for the diffusion measurement has not been established. The aim of this study is to develop the method to measure the tracer diffusion coefficient of the mixed conductors by using secondary ion mass spectrometry (SIMS), based on the idea that 6Li in the cathode material can be replaced with 7Li by electrochemical charge-discharge. As a result of this study, we succeeded to develop three kinds of ion-exchange methods and to clarify the diffusion coefficient of thin films a-Li3PO4, LiMn2O4 and LiCoO2 by using the developed methods. It has been found that the temperature and composition dependence of the diffusion coefficients in the intercalation electrodes are able to explain by vacancy diffusion mechanism.
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Report
(4 results)
Research Products
(40 results)
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[Journal Article] Direct measurement of nanoscale lithium diffusion in solid battery materials using radioactive tracer of 8Li2016
Author(s)
H. Ishiyama, S.C. Jeong, Y.X. Watanabe, Y. Hirayama, N. Imai, H.S. Jung, H. Miyatake, M. Oyaizu, A. Osa, Y. Otokawa, M. Matsuda, K. Nishio, H. Makii, T.K. Sato, N. Kuwata, J. Kawamura, H. Ueno, Y.H. Kim, S. Kimura, M. Mukai
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Journal Title
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
Volume: -
Pages: 379-381
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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