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Light manipulation of inroganic nanosheet liquid crystals and their functions

Research Project

Project/Area Number 15H03878
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionKyushu Institute of Technology

Principal Investigator

Nakato Teruyuki  九州工業大学, 大学院工学研究院, 教授 (10237315)

Co-Investigator(Kenkyū-buntansha) 川俣 純  山口大学, 大学院創成科学研究科, 教授 (40214689)
岩井 俊昭  東京農工大学, 工学(系)研究科(研究院), 教授 (80183193)
Co-Investigator(Renkei-kenkyūsha) MOURI Emiko  九州工業大学, 大学院工学研究院, 助教 (60380721)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2017: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Keywords無機ナノシート / ナノ材料 / 液晶 / コロイド / レーザー / 光操作 / 階層構造 / ナノシート / 光ピンセット / 無機工業材料 / 層状・層間化合物
Outline of Final Research Achievements

We investigated optical manipulation of liquid crystalline inorganic nanosheets to obtain hierarchical and local structures in a colloidal system. Laser irradiation to colloidal niobate nanosheets aligned them in the direction of the incident laser beam. At the focal point, the nanosheet orientation depended on the polarization direction of the laser beam. In contrast, a giant tree-ring-like nanosheet texture of more than 100 micrometers, and which is independent of the polarization direction, was organized at the periphery of the focal point. While the alignment at the focal point was common to both liquid crystalline and isotropic nanosheets, the tree-ring-like structure was observed only for the liquid crystalline samples. The latter organization resulted from a cooperative effect between the liquid-crystalline nanosheets, which indicates an effectiveness of optical manipulation to construct hierarchical colloidal structures with the aid of interparticle interactions.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (22 results) (of which Int'l Joint Research: 9 results,  Invited: 6 results) Book (3 results)

  • [Journal Article] Radiation Pressure Induced Hierarchical Structure of Liquid Crystalline Inorganic Nanosheets2018

    • Author(s)
      Tominaga Makoto、Nagashita Takashi、Kumamoto Takuya、Higashi Yuki、Iwai Toshiaki、Nakato Teruyuki、Suzuki Yasutaka、Kawamata Jun
    • Journal Title

      ACS Photonics

      Volume: 5 Issue: 4 Pages: 1288-1293

    • DOI

      10.1021/acsphotonics.7b01230

    • NAID

      120006976067

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Prepublication: Optical trapping and orientation manipulation of 2D inorganic materials using a linearly polarized laser beam2018

    • Author(s)
      Tominaga Makoto、Higashi Yuki、Kumamoto Takuya、Nagashita Takashi、Nakato Teruyuki、Suzuki Yasutaka、Kawamata Jun
    • Journal Title

      Clays and Clay Minerals

      Volume: 66

    • DOI

      10.1346/ccmn.2017.064075

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Assembled Structure of a Nanosheet Liquid Crystal Induced by Laser Beam Using an Objective Lens witj a Low Numerical Aperture2018

    • Author(s)
      T. Nagashita, Y. Higashi, A. Ikeda, M. Tominaga, T. Kumamoto, Y.Suzuki, T. Nakato, J. Kawamata
    • Journal Title

      Clay Science

      Volume: 22

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electric Alignment of Liquid Crystalline Colloidal Nanosheets Prepared by Exfoliation of Layered Oxides2017

    • Author(s)
      T. Nakato
    • Journal Title

      Clay Science

      Volume: 21 Pages: 13-20

    • NAID

      130006770102

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Textural Diversity of Hierarchical Macroscopic Structures of Colloidal Liquid Crystalline Nanosheets Organized under Electric Fields2017

    • Author(s)
      T. Nakato, Y. Nono, E. Mouri
    • Journal Title

      Colloids and Surfaces A

      Volume: 印刷中 Pages: 373-381

    • DOI

      10.1016/j.colsurfa.2017.02.092

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 無機ナノシートの液晶形成と機能2016

    • Author(s)
      中戸晃之
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 61 Pages: 821-826

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Photoinduced electron transfer between semiconducting nanosheets and acceptor molecules in the presence of colloidal clay particles2016

    • Author(s)
      Teruyuki Nakato, Manami Shimizu, Hitomi Edakubo, Emiko Mouri
    • Journal Title

      Applied Clay Science

      Volume: 未定 Pages: 76-82

    • DOI

      10.1016/j.clay.2016.03.007

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of sol-gel transition of clay colloids on the spectroscopic behavior of cationic dye adsorbed on the clay particles2015

    • Author(s)
      Teruyuki Nakato, Yusuke Nakano, Emiko Mouri
    • Journal Title

      Applied Clay Science

      Volume: 118 Pages: 29-37

    • DOI

      10.1016/j.clay.2015.08.032

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 円偏光の照射によるニオブ酸ナノシートの回転とその制御2018

    • Author(s)
      東 裕貴,池田 暉,長下 敬,富永 亮,鈴木康孝,川俣 純,熊本拓哉,中戸晃之
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] レーザー光の放射圧によるニオブ酸ナノシート液晶の配向制御~ナノシートの配向の偏光依存性~2017

    • Author(s)
      長下 敬,東 裕貴,富永 亮,鈴木康孝,川俣 純,熊本拓哉,中戸晃之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] レーザーの放射圧による無機ナノシート液晶の局所操作2017

    • Author(s)
      熊本拓哉,富永亮,長下 敬,毛利恵美子,鈴木康孝,川俣 純,中戸晃之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 無機ナノシートの基礎~その多様な側面~2017

    • Author(s)
      中戸晃之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Radiation Pressure Induced Orientation of Colloidal Oxide Nanosheets2017

    • Author(s)
      M. Tominaga, T. Nagashita, Y. Higashi, T. Kumamoto, T. Nakato, Y. Suzuki, J. Kawamata
    • Organizer
      16th Int. Clay Conf.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Orientation of Niobate Nanosheet Liquid Crystals by Radiation Pressure of Laser Beam: Orientation on Polarization Direction of the Laser Beam2017

    • Author(s)
      T. Nagashita, Y. Higashi, M. Tominaga, Y. Suzuki, J. Kawamata, T. Kumamoto, T. Nakato
    • Organizer
      16th Int. Clay Conf.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hierarchical Organization of Liquid Crystalline Oxide Nanosheets2017

    • Author(s)
      T. Nakato
    • Organizer
      France-Japan Workshop 2017 on Functional Nanomaterials and Soft Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organization of Diverse Macroscopic Structures in Liquid Crystalline Colloids of Exfoliated Oxide Nanosheets2017

    • Author(s)
      T. Nakato, Y. Nono, E. Mouri
    • Organizer
      2017 Int. Conf. on Nanospace Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光の放射圧を用いたナノシートの配向制御2017

    • Author(s)
      鈴木康孝,富永 亮,長下 敬,東 祐貴,川俣 純,熊本拓哉,中戸晃之
    • Organizer
      2017年光化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] らせん状の波面を持つ光照射によるニオブ酸ナノシート液晶配向2017

    • Author(s)
      長下 敬,東 裕貴,熊本拓哉,富永 亮,鈴木康孝,中戸晃之,川俣 純
    • Organizer
      第61回粘土科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] レーザーの放射圧による無機ナノシート液晶の光操作2017

    • Author(s)
      熊本拓哉,富永 亮,長下 敬,毛利恵美子,鈴木康孝,川俣 純,中戸晃之
    • Organizer
      平成29年度九州支部秋季合同研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nanosheet Liquid Crystals: Structured Colloids Constructed by Inorganic 2D Particles2017

    • Author(s)
      T. Nakato
    • Organizer
      Symposium on Applied Engineering and Sciences (SAES2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] レーザー光の放射圧によるコロイド中のニオブ酸ナノシートの配向2016

    • Author(s)
      長下 敬,中西 稜,富永 亮,熊本拓哉,中戸晃之,鈴木康孝,川俣 純
    • Organizer
      日本化学会低次元系光機能材料研究会第5回サマーセミナー in 島根
    • Place of Presentation
      美保館
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] 無機ナノシートコロイドの光ピンセット操作2016

    • Author(s)
      熊本拓哉,富永 亮,櫻井敏樹,長下 敬,毛利恵美子,鈴木康孝,川俣 純,中戸晃之
    • Organizer
      日本化学会低次元系光機能材料研究会第5回サマーセミナー in 島根
    • Place of Presentation
      美保館
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] 光ピンセットを用いたナノシートコロイドの局所的な配向制御2016

    • Author(s)
      富永 亮,長下 敬,熊本拓哉,中戸晃之,鈴木康孝,川俣 純
    • Organizer
      第60回粘土科学討論会
    • Place of Presentation
      九州大学病院キャンパス
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 粘土コロイドの液晶性と外場による制御2016

    • Author(s)
      中戸晃之
    • Organizer
      第60回粘土科学討論会
    • Place of Presentation
      九州大学病院キャンパス
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Local Manipulation of Colloidal Liquid Crystals of Inorganic Nanosheets by Optical Tweezers2016

    • Author(s)
      T. Nakato, M. Tominaga, T. Sakurai, R. Nakanishi, T. Nagashita, T. Kumamoto, E. Mouri, Y. Suzuki, T. Iwai, J. Kawamata
    • Organizer
      26th International Liquid Crystal Conference
    • Place of Presentation
      Kent, Ohio, U.S.A.
    • Year and Date
      2016-08-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Manipulation of Colloidal Liquid Crystals of Oxide Nanosheets by Optical Tweezers2016

    • Author(s)
      T. Nakato, M. Tominaga, T. Sakurai, R. Nakanishi, T. Nagashita, T. Kumamoto, E. Mouri, Y. Suzuki, T. Iwai, J. Kawamata
    • Organizer
      8th Mid-European Clay Conference
    • Place of Presentation
      Kosice, Slovakia
    • Year and Date
      2016-07-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 無機ナノシートによるコロイド液晶の形成と利用2016

    • Author(s)
      中戸晃之
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2016-06-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 光ピンセットによる無機ナノシート液晶の配向制御2016

    • Author(s)
      熊本拓哉,富永 亮,櫻井敏樹,中西 稜,長下 敬,毛利恵美子,鈴木康孝,岩井俊昭,川俣 純,中戸晃之
    • Organizer
      ナノ学会第14回大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Inorganic Nanosheet Liquid Crystals: Toward Hierarchical Macroscopic Soft Structures2016

    • Author(s)
      T. Nakato
    • Organizer
      Pure and Applied Chemistry International Conference 2016
    • Place of Presentation
      Bangkok, Thailand
    • Year and Date
      2016-02-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Formation of Vortex-shaped Orientation of Niobate Oxide Nanosheet Liquid Crystals by Irradiation of an Optical Vortex2015

    • Author(s)
      T. Sakurai, R. Nakanishi, M. Tominaga, Y. Suzuki, J. Kawamata, Y. Shimura, T. Iwai, Y. Nono, T. Nakato
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, U. S. A.
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Book] Inorganic Nanosheets and Nanosheet-Based Materials2017

    • Author(s)
      T. Nakato, J. Kawamata, S. Takagi (eds)
    • Total Pages
      542
    • Publisher
      Springer
    • Related Report
      2016 Annual Research Report
  • [Book] CSJカレントレビュー25 二次元物質の科学(第13章)2017

    • Author(s)
      中戸晃之, 宮元展義
    • Total Pages
      208
    • Publisher
      化学同人
    • Related Report
      2016 Annual Research Report
  • [Book] 機能性顔料の開発と応用(第26章)2016

    • Author(s)
      中戸晃之
    • Total Pages
      332
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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