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Silver Electrodeposition Based Full-Color Electrochromic Device with Control of Plasmonic Absorption of Silver Nanodeposit

Research Project

Project/Area Number 15H03880
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionChiba University

Principal Investigator

Kobayashi Norihisa  千葉大学, 大学院工学研究院, 教授 (50195799)

Co-Investigator(Kenkyū-buntansha) 中村 一希  千葉大学, 大学院工学研究院, 准教授 (00554320)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Keywords先端機能デバイス / ディスプレイ / エレクトロクロミズム / プラズモン共鳴 / 電気化学素子
Outline of Final Research Achievements

Electrochromic (EC) device is expected to be a potential candidate for novel reflective display and energy conservation system. We have demonstrated world's first Ag-electrodeposition based multi-color EC device by focusing on the result that Ag nanoparticles exhibit various optical states based on their localized surface plasmon resonance (LSPR). In this research, we achieved the memory property for two hours, which was the image retention properties without power supply and was essentially required for tone representation. Further, representation of the color with high lightness value (L value) was successfully demonstrated with the EC cell by optimizing the electrolyte component. It was revealed that the relation between the optical state and Ag particle structure was theoretically explained by FDTD modeling analysis. Consequently, we first realized the Ag LSPR based EC device which showed black, mirror, CMY and RGB and indicated the possibility to enable wide color gamut.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (33 results)

All 2018 2017 2016 2015 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 6 results) Presentation (13 results) (of which Int'l Joint Research: 13 results,  Invited: 10 results) Book (4 results) Remarks (2 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Effects of silver halide complexes on optical and electrochemical properties of silver deposition-based electrochromic device2018

    • Author(s)
      R. Kimura, A. Tsuboi, K. Nakamura and N. Kobayashi
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 177 Pages: 128-133

    • DOI

      10.1016/j.solmat.2017.01.014

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of color retention properties of Ag deposition-based electrochromic device by introducing anion exchange membrane2018

    • Author(s)
      S. Kimura, R. Onodera, K.Nakamura and N. Kobayashi
    • Journal Title

      MRS Communications

      Volume: 8 Issue: 2 Pages: 498-503

    • DOI

      10.1557/mrc.2018.55

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ measurements of electrode potentials of anode and cathode in organic electrochromic devices2017

    • Author(s)
      S. Tsuneyasu, Y. Watanabe, K. Nakamura and N. Kobayashi
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 163 Pages: 200-203

    • DOI

      10.1016/j.solmat.2017.01.035

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Coloration mechanisms of Ag deposition-based multicolor electrochromic device investigated by morphology of Ag deposit and its optical properties2016

    • Author(s)
      R. Onodera, A. Tsuboi, K. Nakamura and N. Kobayashi
    • Journal Title

      J. Soc. Info. Display,

      Volume: 24 Issue: 7 Pages: 424-432

    • DOI

      10.1002/jsid.451

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electro-responsive dual functional displaying device enabling both emissive and reflective modes by combining electrochemiluminescent and liquid crystal materials2016

    • Author(s)
      S. Tsuneyasu, K. Nakamura and N. Kobayashi
    • Journal Title

      Chem. Lett

      Volume: 45 Pages: 949-952

    • NAID

      130005254570

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermally controlled dual-mode display media with red-green-blue coloration and fluorescence via energy transfer between emission materials and leuco dyes2016

    • Author(s)
      Kouki OGASAWARA, Kazuki NAKAMURA, Norihisa KOBAYASHI
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 4 Issue: 21 Pages: 4805-4813

    • DOI

      10.1039/c6tc01027j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Why were Alternating- Current-Driven Electrochemiluminescence Properties from a Ru(bpy)32+ Dramatically Improved by the Addition of Titanium Dioxide Nanoparticles?2016

    • Author(s)
      S.Tsuneyasu, K. Ichihara, K. Nakamura and N. Kobayashi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 24 Pages: 16317-16324

    • DOI

      10.1039/c6cp02881k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] An Electrochemically-Driven Dual-Mode Display Device with Both Reflective and Emissive Modes Using Poly( p-phenylenevinylene) Derivatives2016

    • Author(s)
      S. Tsuneyasu, L. Jin, K. Nakamura and N. Kobayashi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 4 Pages: 041601-041601

    • DOI

      10.7567/jjap.55.041601

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electroswitchable optical device enabling both luminescence and coloration control consisted of fluoran dye and 1,4-benzoquinone2016

    • Author(s)
      Kenji KANAZAWA, Kazuki NAKAMURA, Norihisa KOBAYAHI
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 145 Pages: 42-53

    • DOI

      10.1016/j.solmat.2015.06.061

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chromatic Control of Multicolor Electrochromic Device with Localized Surface Plasmon Resonance of Silver Nanoparticles by Voltage-step Method2016

    • Author(s)
      A. Tsuboi, K. Nakamura and N. Kobayashi
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 145 Pages: 16-25

    • DOI

      10.1016/j.solmat.2015.07.034

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Luminescence Modulation in a Eu(III) Complex-Modified TiO2 Electrode2015

    • Author(s)
      K. Kanazawa, K. Nakamura and N. Kobayashi
    • Journal Title

      J. Mater. Chem. C

      Volume: 3 Issue: 27 Pages: 7135-7142

    • DOI

      10.1039/c4tc02996h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Novel Dual Mode Display with Electrochemistry2017

    • Author(s)
      Norihisa Kobayashi
    • Organizer
      4th International Workshop on Nano and Bio-Photonics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] LSPR Band Tunable Ag Electrodeposition Based Electrochromic Cell Enabling Multicolor Representation2017

    • Author(s)
      Norihisa Kobayashi
    • Organizer
      MRS Fall 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Localized Surface Plasmon Resonance (LSPR) Based Electrochromic Cell for Multicolor Representation2017

    • Author(s)
      Norihisa Kobayashi
    • Organizer
      4th International Workshop on Chromogenic Materials and Devices
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Localized Surface Plasmon Resonance Based Electrochromic Cell for Multicolor Representation2016

    • Author(s)
      Norihisa Kobayashi
    • Organizer
      14th International Conference on Frontiers of Polymers and Advanced Materials
    • Place of Presentation
      Deajeon, South Korea
    • Year and Date
      2016-10-31
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Silver Electrodeposition Based Multicolor Electrochromic Cell Toward Energy Saving Applications2016

    • Author(s)
      N. Kobayashi, K. Nakamura, J. Hong and R. Tejima
    • Organizer
      PRiME 2016
    • Place of Presentation
      Honolulu
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Multicolor Electrochromic Device with LSPR of Silver Electrodeposition toward Color Reflective Display2016

    • Author(s)
      N. Kobayashi, K. Nakamura, J. Hong and R. Tejima
    • Organizer
      2016 Printing for Fabrication (NIP32)
    • Place of Presentation
      Manchester
    • Year and Date
      2016-09-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Silver Electrodeposition-Based Multicolor Electrochromic Device toward Color e-Paper2016

    • Author(s)
      N. Kobayashi, R. Onodera and K. Nakamura
    • Organizer
      SID Display Week 2016
    • Place of Presentation
      San Francisco
    • Year and Date
      2016-05-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemiluminescence toward Light Emitting Devices and Dual Mode Diplays2016

    • Author(s)
      Norihisa Kobayashi
    • Organizer
      46th Korean Soc. Image Sci and Tech Fall Meeting 2016
    • Place of Presentation
      Busan, South Korea
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Multicolor Electrochromic Device with Localized Surface Plasmon Resonance of Silver Nano-electrodeposit2015

    • Author(s)
      N. Kobayashi
    • Organizer
      3rd International Workshop on Nano and Photonics
    • Place of Presentation
      Cabourg (France)
    • Year and Date
      2015-12-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Color Change Device with Silver Electrodeposition and Its Mechanism2015

    • Author(s)
      N. Kobayashi
    • Organizer
      44th KSIST fall meeting
    • Place of Presentation
      Busan (South Korea)
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Silver Electrodeposition Based Multicolor Electrochromic Device Showing CMY Three Primary Color States2015

    • Author(s)
      N. Kobayashi, K. Nakamura, R. Onodera and A. Tsuboi
    • Organizer
      NIP31 and Digital Fablication 2015
    • Place of Presentation
      Portland (USA)
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Color e-Paper Technology with Electrochemistry2015

    • Author(s)
      N. Kobayashi
    • Organizer
      227th ECS meeting
    • Place of Presentation
      Chicago (USA)
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Electrochromism toward Color e-Paper and Energy-saving Technology2015

    • Author(s)
      N. Kobayashi
    • Organizer
      The 2015 EMN Optoelectronics Meeting
    • Place of Presentation
      Beijing (China)
    • Year and Date
      2015-04-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] Control of Emission and Coloration in Electrochemical Systems and Its Applications in "Luminescence in Electrochemistry"2017

    • Author(s)
      K. Kanazawa, K. Nakamura and N. Kobayashi
    • Total Pages
      361
    • Publisher
      Springer
    • ISBN
      9783319491356
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Book] Electrochromic Display in "Handbook of Visual Display Technology"2016

    • Author(s)
      J. Chen, W. Cranton, M. Fihn (Eds.), N. Kobayashi
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report
  • [Book] Application of DNA to Materials Science 2 in "DNA Engineering : Properties and Applications"2016

    • Author(s)
      H. Mizoguchi and H. Sakamoto (Eds.), N. Kobayashi and K. Nakamura
    • Publisher
      Pan Stanford Publishing
    • Related Report
      2015 Annual Research Report
  • [Book] DNA electronics and photonics in "Electronic Processes in Organic Electronics"2015

    • Author(s)
      H. Ishii, K. Kudo, T. Nakayama and N. Ueno (Eds.), N. Kobayashi and K. Nakamura
    • Total Pages
      432
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report
  • [Remarks] 小林範久・中村一希研究室

    • URL

      http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] エレクトロクロミック表示素子2017

    • Inventor(s)
      小林範久,木村俊輔,中村一希
    • Industrial Property Rights Holder
      小林範久,木村俊輔,中村一希
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-118174
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 調光発電ハイブリッド素子及びこれを用いた発電方法2016

    • Inventor(s)
      小林範久
    • Industrial Property Rights Holder
      小林範久
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-182456
    • Filing Date
      2016-09-18
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] エレクトロクロミック表示素子2016

    • Inventor(s)
      小林範久,中村一希,小野寺涼
    • Industrial Property Rights Holder
      小林範久,中村一希,小野寺涼
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-016790
    • Filing Date
      2016-01-31
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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