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Development of vanadate glass with high electrical conductivity and its application for a cathode active material of secondary batteries

Research Project

Project/Area Number 15H03882
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

KUBUKI Shiro  首都大学東京, 理工学研究科, 准教授 (90321489)

Co-Investigator(Kenkyū-buntansha) 岡田 重人  九州大学, 先導物質化学研究所, 教授 (10304841)
吉岡 聰  九州大学, 工学研究院, 助教 (50452818)
Co-Investigator(Renkei-kenkyūsha) NISHIDA Tetsuaki  近畿大学, 工学部, 教授 (10112286)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2017: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywordsメスバウアー分光法 / バナジン酸塩ガラス / 二次電池正極材 / 二次電池正極材料 / 導電性 / 導電性ガラス
Outline of Final Research Achievements

In this project, we investigated a relationship between the structure and electrical properties of sodium phosphovanadate glass with the composition of xNa2O・10P2O5・(90-x)V2O5 ('x' = 5-45 mol%, abbreviated as xNPV) as a cathode active material with high performance. DTA curves of xNPV glass showed a decrease in glass transition temperature (Tg) from 235 to 195 oC, while electrical conductivity (EC) decreased from 3.6×10-6 to 6.4×10-8 S cm-1 with the increase of‘x’from 5 to 45. These results suggested that the cleavage of the 3D-network structure caused the decrease in Tg and EC . Charge-discharge capacity of as-quenched xNPV glass showed a larger initial capacity than that of heat-treated samples. In particular, 45NPV glass had a large initial capacity of 258 mAh/g while it showed a very small irreversible capacity (21 mAh/g). These results suggest that 45NPV glass is a one of the good candidates for a cathode active material of sodium ion batteries.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (40 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (9 results) Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results) Presentation (22 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results) Funded Workshop (2 results)

  • [Int'l Joint Research] エトボシュローランド大学(ハンガリー)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ルジェルボスコヴィッチ研究所(クロアチア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] アルアズハル大学(エジプト)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] オロモウツ大学(チェコ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] エトボシュ ローランド大学(ハンガリー)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ルジェルボスコヴィッチ研究所(クロアチア)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] エトボシュローランド大学(ハンガリー)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] ルジェルボスコヴィッチ研究所(クロアチア)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] アルアズハル大学(エジプト)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Highly conductive barium iron vanadate glass containing different metal oxides2017

    • Author(s)
      T. Nishida, Y.Izutsu, M. Fujimura, K. Osouda, Y. Otsuka, S. Kubuki and N. Oka
    • Journal Title

      Pure and Applied Chemistry

      Volume: 89(4) Pages: 419-428

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Relaxation and Electrical Conductivity of molybdovandate glass2017

    • Author(s)
      T. Nishida, I. Furumoto, Y. Fujita, S. Kubuki, and N. Oka
    • Journal Title

      J. Mater. Sci.: Mater Electron.

      Volume: 29(4) Pages: 2654-2659

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Role of Sulfur as a Reducing Agent for the Transition Metals Incorporated into Lithium Silicate Glass2016

    • Author(s)
      M. Y. Hassaan, M. M. El-Desoky, M. G. Moustafa, Y. Iida, S. Kubuki, T. Nishida
    • Journal Title

      Croat. Chem. Acta

      Volume: 88 Issue: 4 Pages: 1-6

    • DOI

      10.5562/cca2785

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Characterization and Conduction Mechanism of Highly Conductive Vanadate Glass2015

    • Author(s)
      T. Nishida, S. Kubuki, K. Matsuda, Y. Otsuka
    • Journal Title

      Croat. Chem. Acta

      Volume: 88 Issue: 4 Pages: 1-9

    • DOI

      10.5562/cca2760

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The STEM Study of Crystallized Iron Vanadate Glasses Containing Alkaline Earth Oxide2015

    • Author(s)
      Y. Kobayashi, S. Yoshioka, T. Yamamoto, S. Kubuki, S. Matsumura
    • Journal Title

      Microscopy

      Volume: 64

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A relationship between enhancement of electrical conductivity and structural relaxation of 10SnO2・10Fe2O3・10P2O5・xAgI・(70-x)V2O5 glass caused by isothermal annealing2015

    • Author(s)
      K. Matsuda, S. Kubuki, K. Akiyama, Z. Homonnay, K. Sinko, E. Kuzmann, T. Nishida
    • Journal Title

      J. Ceram. Soc. Jpn.

      Volume: 123 Pages: 121-128

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] メスバウアー分光法を用いた導電性バナジン酸塩ガラスのキャラクタリゼーション2015

    • Author(s)
      松田 弘賢、久冨木 志郎、西田 哲明
    • Journal Title

      Isotope News

      Volume: 733 Pages: 7-10

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Structural Analysis and Electrical Conductivity of Tin Phosphate -containing Vanadate Glass2018

    • Author(s)
      Y. Kobayashi, S. Shiba, K. Akiyama, S. Kubuki
    • Organizer
      第19回メスバウアー分光研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local Structure and Electrical Properties of Sodium Phosphovanadate Glass2018

    • Author(s)
      S. Shiba, K. Osouda, S. Kubuki, K. Nomura, K. Akiyama, A. Kitajou, S. Okada, T. Nishida
    • Organizer
      第19回メスバウアー分光研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Substitutional Effect of Metal Oxides on Conductive Vanadate Glass and its Application to Metal-Air Rechargeable Battery2018

    • Author(s)
      N. Oka, H. Miyamoto, Y. Fujita, S. Masuda, M. Yuasa, S. Kubuki, T. Nishida
    • Organizer
      第19回メスバウアー分光研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナトリウムを含むバナジン酸塩ガラスの局所構造と電気的特性2017

    • Author(s)
      柴 祥矢,久冨木 志郎,秋山 和彦, 西田 哲明
    • Organizer
      第18回メスバウアー分光研究会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸化スズを含む高導電性バナジン酸塩ガラスのメスバウアースペクトルと電気伝導度2017

    • Author(s)
      藤田 裕樹,岡 伸人, 久冨木 志郎, 西田 哲明
    • Organizer
      第18回メスバウアー分光研究会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Naイオン二次電池正極材としてのバナジン酸塩ガラスの開発2017

    • Author(s)
      久冨木志郎, 襲田圭人, 柴祥矢
    • Organizer
      ダイナミックアライアンスG2分科会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化モリブデンを含む導電性バナジン酸塩ガラスのメスバウアースペクトルと電気伝導度2017

    • Author(s)
      西田哲明, 古本功, 藤田裕樹, 岡伸人, 久冨木志郎
    • Organizer
      第54回アイソトープ・放射線研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Local Structure and Electrical Property of Sodium Vanadate Glass2017

    • Author(s)
      S. Shiba, S. Kubuki, K. Osouda, K. Akiyama, A. Kitajou, S. Okada, E. Kuzmann, Z. Homonnay, N. Oka, T. Nishida
    • Organizer
      第54回アイソトープ・放射線研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 57Fe-Mössbauer Study of Sodium Phosphovanadate Glass2017

    • Author(s)
      S. Shiba, K. Osouda, A. Kitajou, S. Okada, J. Okabayashi, T. Nishida , S. Kubuki
    • Organizer
      The 34thd International Conference on the Application of the Mössbauer Effect (ICAME2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 57Fe-Mossbauer Study of Sodium Vanadate Glass with High Electrical Conductivity2016

    • Author(s)
      S. Kubuki, S. Shiba, K. Osouda, K. Akiyama, E. Kuzmann, Z. Homonnay, N. Oka and T. Nishida
    • Organizer
      XV Latin American Conference on the Application of the Mossbauer Effect
    • Place of Presentation
      パナマシティー(パナマ)
    • Year and Date
      2016-11-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アルミニウムを含むバナジン酸塩ガラスの電気物性と局所構造2016

    • Author(s)
      襲田 圭人, 久冨木 志郎, 秋山 和彦, Z. Homonnay, E. Kuzmann, 西田 哲明,
    • Organizer
      第53回アイソトープ・放射線研究発表会
    • Place of Presentation
      東京大学農学部(東京都文京区)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属並みに電気を通す酸化物ガラスの導電機構とメスバウアースペクトル2016

    • Author(s)
      西田 哲明, 井筒 有紀美, 藤村 美菜, 大塚 祐希, 久冨木 志郎
    • Organizer
      第53回アイソトープ・放射線研究発表会
    • Place of Presentation
      東京大学農学部(東京都文京区)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrical Conductivity and Local Structure of Aluminum-Containing Vanadate Glass2016

    • Author(s)
      K. Osouda, S. Kubuki, K.Akiyama and T. Nishida
    • Organizer
      Mediterranean Conference on the Application of the Mossbauer Effect (MECAME2016)
    • Place of Presentation
      ドブロブニク(クロアチア)
    • Year and Date
      2016-05-31
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Substitution of Ga2O3 and GeO2 for Fe2O3 in Conductive Barium Iron Vanadate Glass2016

    • Author(s)
      T. Nishida, Y. Izutsu, M. Fujimura, K. Osouda, Y. Otsuka and S. Kubuki
    • Organizer
      Mediterranean Conference on the Application of the Mossbauer Effect (MECAME2016)
    • Place of Presentation
      ドブロブニク(クロアチア)
    • Year and Date
      2016-05-31
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アルミニウムを含むバナジン酸塩ガラスの物性と構造解析2016

    • Author(s)
      襲田 圭人、久冨木志郎、秋山和彦、西田哲明
    • Organizer
      第17回メスバウアー分光研究会
    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2016-03-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] メスバウアー分光法を用いた機能性ガラスセラミックスのキャラクタリゼーション~導電性ガラスから酸化鉄ナノ材料まで~2016

    • Author(s)
      久冨木志郎
    • Organizer
      日本セラミックス協会 表面分析技術研究会
    • Place of Presentation
      日本セラミックス協会(東京都新宿区)
    • Year and Date
      2016-02-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Property and structural characterization of Al3+ containing vanadate glass2016

    • Author(s)
      K. Osouda, K. Akiyama, S. Kubuki
    • Organizer
      -The Global Human Resource Program Bridging across Physics and Chemistry-
    • Place of Presentation
      Hachi-Oji, Tokyo, Japan
    • Year and Date
      2016-01-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] メスバウアー分光法を用いた機能性ガラスセラミックスのキャラクタリゼーション~導電性ガラスから光触媒ガラスまで~2015

    • Author(s)
      久冨木志郎
    • Organizer
      九州大学先導物質化学研究所セミナー
    • Place of Presentation
      九州大学先導物質化学研究所(福岡県春日市)
    • Year and Date
      2015-11-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrical Conductivity and Local Structure of xZnO・(20-x)BaO・70V2O5・10Fe2O3 glass Investigated by 57Fe-Mossbauer Spectroscopy2015

    • Author(s)
      Y. Otsuka, S. Kubuki, K. Akiyama, Z. Homonnay, E. Kuzmann and T. Nishida
    • Organizer
      The 33rd International Conference on the Application of the Mossbauer Effect (ICAME2015)
    • Place of Presentation
      Hamburg, Germany
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 導電性バナジン酸塩ガラスの構造緩和と導電機構2015

    • Author(s)
      西田 哲明、藤村 美菜、井筒 有紀美、大塚 祐希、久冨木 志郎
    • Organizer
      第52回アイソトープ・放射線研究発表会
    • Place of Presentation
      東京大学農学部(東京都文京区)
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Role of Sulfur Addition as a Reducing Agent on the Ionic State of the Transition Metals in Lithium Silicate Glass Containing Fe and Ni Ions2015

    • Author(s)
      M. Y. Hassaan, M. M. Desoky, M. G. Moustafa, Y. Iida, S. Kubuki and T. Nishida
    • Organizer
      Mediterranean Conference on the Application of the Mossbauer Effect (MECAME2015)
    • Place of Presentation
      Zadar, Croatia
    • Year and Date
      2015-06-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization and Conduction Mechanism of Highly Conductive Vanadate Glass2015

    • Author(s)
      T. Nishida, Y. Otsuka and S. Kubuki
    • Organizer
      Mediterranean Conference on the Application of the Mossbauer Effect (MECAME2015)
    • Place of Presentation
      Zadar, Croatia
    • Year and Date
      2015-06-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Funded Workshop] 第19回メスバウアー分光研究会2018

    • Related Report
      2017 Annual Research Report
  • [Funded Workshop] 第17回メスバウアー分光研究会2016

    • Place of Presentation
      首都大学東京南大沢キャンパス
    • Year and Date
      2016-03-17
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2022-10-19  

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