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Investigation of the carrier transport process in organic photovoltaics

Research Project

Project/Area Number 15H03883
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

Kobayashi Takashi  大阪府立大学, 工学(系)研究科(研究院), 准教授 (10342784)

Co-Investigator(Kenkyū-buntansha) 内藤 裕義  大阪府立大学, 工学(系)研究科(研究院), 教授 (90172254)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2017: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2015: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Keywords有機薄膜太陽電池 / キャリア輸送 / 移動度 / 光誘導吸収 / 変調光電流測定 / 輸送過程 / ドリフト移動度
Outline of Final Research Achievements

To improve the solar conversion efficiency of organic photovoltaics, it is essential to reveal the operation mechanism, in particular, the carrier transport process. In this study, we develop spectroscopic techniques to determine the associated physical constants, such as the carrier drift mobility, carrier lifetime, and built-in potential, in photovoltaic devices. Photoinduced absorption spectroscopy reveals that the hole drift mobility can be selectively determined by applying a reverse bias to the photovoltaic device. We also establish a modulated photocurrent technique to simultaneously measure the electron and hole mobilities in a photovoltaic device. Using these techniques, we investigate the carrier transport process in organic photovoltaic devices fabricated with various conditions.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (28 results)

All 2018 2017 2016 2015

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results,  Open Access: 2 results) Presentation (23 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results)

  • [Journal Article] Emission properties of thermally activated delayed fluorescence emitters: analysis based on a four level model considering a higher triplet excited state2018

    • Author(s)
      Takashi Kobayashi, Akitsugu Niwa, Shota Haseyama, Kensho Takaki, Takashi Nagase, Kenichi Goushi, Chihaya Adachi, Hiroyoshi Naito
    • Journal Title

      Journal of Photonics for Energy

      Volume: 8 Issue: 03 Pages: 1-1

    • DOI

      10.1117/1.jpe.8.032104

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Contributions of a higher triplet excited state to the emission properties of a thermally activated delayed-fluorescence emitter2017

    • Author(s)
      T. Kobayashi, A. Niwa, K. Takaki, S. Haseyama, T. Nagase, K. Goushi, C. Adachi, H. Naito
    • Journal Title

      Physical Review Applied

      Volume: 7 Issue: 3 Pages: 034002-034002

    • DOI

      10.1103/physrevapplied.7.034002

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of the Singlet - Triplet Energy Gap in a Thermally Activated Delayed Fluorescence Emitter by Using a Polar Host Matrix2017

    • Author(s)
      S. Haseyama, A. Niwa, A. T. Kobayashi, T. Nagase, K. Goushi, C. Adachi, H. Naito
    • Journal Title

      Nanoscale Research Letters

      Volume: 12 Issue: 1 Pages: 268-268

    • DOI

      10.1186/s11671-017-2012-1

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Relation between active-layer thickness and power conversion efficiency in P3HT:PCBM inverted organic photovoltaics2017

    • Author(s)
      S. Nakami, T. Narioka, T. Kobayashi, T. Nagase, H. Naito
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photoluminescence in a thermally activated delayed fluorescence emitter for organic light-emitting diodes2016

    • Author(s)
      A. Niwa, K. Takaki, T. Kobayashi, T. Nagase, K. Goushi, C. Adachi, and H. Naito
    • Journal Title

      Journal of the Imaging Society of Japan

      Volume: 55 Pages: 143-143

    • NAID

      130005144932

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 変調光電流法による有機薄膜太陽電池の電子・正孔移動度同時評価2018

    • Author(s)
      野島 大希, 小林 隆史, 永瀬 隆, 内藤 裕義
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 四準位モデルに基づく4CzIPNの緩和速度の検討2018

    • Author(s)
      川手大輔, 丹羽顕嗣, 石井智也, 小林隆史, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 発光緩和過程におけるスカイブルー発光を示す熱活性化遅延蛍光材料の高次の三重項励起状態の寄与2018

    • Author(s)
      石井智也, 丹羽顕嗣, 川手大輔, 小林隆史, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] P3HT:PCBM逆構造有機薄膜太陽電池における最適膜厚についての検討2018

    • Author(s)
      久茂田 耀,中美 総司, 小林 隆史, 永瀬 隆, 内藤 裕義
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 強度変調光電流分光法及び光誘導吸収法による有機薄膜太陽電池の解析2017

    • Author(s)
      野島大希, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] CHARGE TRANSPORT PROCESS IN ORGANIC PHOTOVOLTAICS STUDIED WITH INTENSITY MODULATED PHOTOVOLTAGE AND PHOTOCURRENT MEASUREMENTS2017

    • Author(s)
      H. Nojima, T. Kobayashi, T. Nagase and H. Naito
    • Organizer
      The 17th International Discussion and Conference on NICE device
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TADF材料における発光減衰測定 -高次三重項励起準位を考慮した4準位モデルによる解析-2017

    • Author(s)
      丹羽顕嗣, 川手大輔,小林隆史, 永瀬 隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      有機EL討論会 第24回例会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 4CzIPN における緩和速度定数の溶媒極性依存性2017

    • Author(s)
      丹羽顕嗣, 川手大輔, 小林隆史, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 熱活性遅延蛍光材料の項間交差速度の評価2017

    • Author(s)
      川手大輔, 丹羽顕嗣, 小林隆史, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 2f成分を検出する強度変調光起電力分光及び強度変調光電流分光による有機薄膜太陽電池2017

    • Author(s)
      野島 大希, 小林 隆史, 永瀬 隆, 内藤 裕義
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 熱活性化遅延蛍光材料における発光ダイナミクス -高次三重項励起状態を考慮した解析-2017

    • Author(s)
      小林隆史, 丹羽顕嗣, 高木絢生, 長谷山翔太, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      日本学術振興会第142委員会 有機光エレクトロニクス部会 第77回研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 熱活性遅延蛍光材料の項間交差の温度依存性2017

    • Author(s)
      川手大輔, 丹羽顕嗣, 石井智也, 小林隆史, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      有機 EL 討論会第 第25回例会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 変調光起電力及び光電流測定を用いた有機薄膜太陽電池のキャリア輸送過程の解析2017

    • Author(s)
      野島 大希, 小林 隆史, 永瀬 隆, 内藤 裕義
    • Organizer
      大阪府立大学21世紀科学研究センター 分子エレクトロニックデバイス研究所 第19回研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カルバゾールジシアノベンゼン系TADF材料の交換交差の温度依存性2017

    • Author(s)
      川手大輔, 丹羽顕嗣, 石井智也, 小林隆史, 永瀬隆, 合志憲一, 安達千波矢, 内藤裕義
    • Organizer
      第28回光物性研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] A relationship between active layer thickness and carrier lifetime in P3HT:PCBM inverted organic photovoltaics2016

    • Author(s)
      S. Nakami, T. Kobayashi, T. Nagase, and H. Naito
    • Organizer
      12th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Kobe
    • Year and Date
      2016-12-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoluminescence Properties of Polymorphic Modifications of Low-Molecular-Weight Poly(3-hexylthiophene)2016

    • Author(s)
      T. Kobayashi, K. Kinoshita, A. Niwa, T. Nagase, H. Naito
    • Organizer
      12th International Conference on Nano-Molecular Electronics
    • Place of Presentation
      Kobe
    • Year and Date
      2016-12-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 逆構造有機薄膜太陽電池の最適膜厚と寿命の関係2016

    • Author(s)
      中美総司, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 変調分光法による有機薄膜太陽電池の移動度評価2016

    • Author(s)
      成岡達彦, 中美総司, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光誘導吸収測定による全高分子型薄膜太陽電池の物性評価2016

    • Author(s)
      中美総司, 成岡達彦, 丹羽顕嗣, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新しい評価法による有機薄膜太陽電池の輸送メカニズムの解明2016

    • Author(s)
      成岡達彦, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      応用物理学会関西支部 平成27年度第3回講演会
    • Place of Presentation
      大阪府立大学(大阪府堺市)
    • Year and Date
      2016-02-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機薄膜太陽電池におけるキャリア輸送過程の解明2015

    • Author(s)
      小林隆史
    • Organizer
      和歌山大学有機エレクトロニクス研究会
    • Place of Presentation
      和歌山大学(和歌山県和歌山市)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機薄膜太陽電池における光誘導吸収測定による移動度評価2015

    • Author(s)
      成岡達彦, 小林隆史, 永瀬 隆, 内藤裕義
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Determination of hole drift mobility in organic solar cells based on a low-bandgap polymer by modulation spectroscopy2015

    • Author(s)
      T. Kobayashi, T. Sunahara, E. Nakatsuka, T. Nagase, H. Naito
    • Organizer
      Eighth International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2015-06-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2019-03-29  

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