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Formation of graphene with low density of defects by plasma-assisted anneal on flat SiC(0001) surfaces

Research Project

Project/Area Number 15H03902
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Production engineering/Processing studies
Research InstitutionOsaka University

Principal Investigator

Arima Kenta  大阪大学, 工学研究科, 准教授 (10324807)

Research Collaborator HOSOO Kohei  
ITO Ryota  
MINAMI Ouki  
LI Shaoxian  
HIRANO Tomoki  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2017: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2016: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2015: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywordsグラフェン / シリコンカーバイド / プラズマ / 表面改質 / ウェットエッチング / 酸化膜 / プラズマ酸化 / SiC表面 / 構造制御 / 超平坦表面 / 生産工学 / ナノ材料 / 表面科学 / 表面 / 酸化
Outline of Final Research Achievements

Graphene is a promising material for future electronic devices. Although the epitaxial growth of graphene by thermal decomposition of SiC in vacuum is familiar, the control of defects on graphene is difficult. We have developed a method to form graphene with low density of defects on a flattened SiC surface by the combined process of plasma treatment, wet etching and thermal anneal. A key in this process is the deposition of an additional carbon layer at the monolayer level on SiC by the plasma treatment. In this study, we investigate the fundamental property of surface modification of SiC by plasma as well as the effect of the carbon layer on the quality of graphene.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (18 results)

All 2018 2017 2016 Other

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results) Presentation (11 results) (of which Int'l Joint Research: 9 results,  Invited: 4 results) Remarks (1 results)

  • [Journal Article] Chemical etching of a semiconductor surface assisted by single sheets of reduced graphene oxide2018

    • Author(s)
      Hirano Tomoki、Nakade Kazuki、Li Shaoxian、Kawai Kentaro、Arima Kenta
    • Journal Title

      Carbon

      Volume: 127 Pages: 681-687

    • DOI

      10.1016/j.carbon.2017.11.053

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Etch Pits on Germanium Surfaces Loaded with Reduced Graphene Oxide in Water2017

    • Author(s)
      Kazuki Nakade, Tomoki Hirano, Shaoxian Li, Yusuke Saito, Daichi Mori, Mizuho Morita, Kentaro Kawai and Kenta Arima
    • Journal Title

      ECS Transactions

      Volume: 78

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Comparative study of GeO2/Ge and SiO2/Si structures on anomalous charging of oxide films upon water adsorption revealed by ambient-pressure X-ray photoelectron spectroscopy2016

    • Author(s)
      Daichi Mori, Hiroshi Oka, Takuji Hosoi, Kentaro Kawai, Mizuho Morita, Ethan J. Crumlin, Zhi Liu, Heiji Watanabe, and Kenta Arima
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 9 Pages: 0953061-10

    • DOI

      10.1063/1.4962202

    • NAID

      120007145772

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of metal particles on the Si etching rate with N-fluoropyridinium salts2016

    • Author(s)
      Masaki Otani, Kentaro Kawai, Kentaro Tsukamoto, Takabumi Nagai, Kenji Adachi, Junichi Uchikoshi, Kenta Arima, and Mizuho Morita
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 10 Pages: 1080031-3

    • DOI

      10.7567/jjap.55.108003

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pit Formation, Patterning and Flattening of Ge Surfaces in O2-Containing Water by Metal-Assisted Chemical Etching2016

    • Author(s)
      Tatsuya Kawase, Atsushi Mura, Yusuke Saito, Takeshi Okamoto, Kentaro Kawai, Yasuhisa Sano, Kazuto Yamauchi, Mizuho Morita, and Kenta Arima
    • Journal Title

      ECS Transactions

      Volume: 75 Issue: 1 Pages: 107-112

    • DOI

      10.1149/07501.0107ecst

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Segregation of ions in deliquesced droplets of alkali-halide nano-crystals on SiO22016

    • Author(s)
      Kenta Arima
    • Journal Title

      Journal of Material Sciences & Engineering

      Volume: 5 Issue: 02 Pages: 66-66

    • DOI

      10.4172/2169-0022.c1.011

    • Related Report
      2015 Annual Research Report
  • [Presentation] Surface Modification of SiC by Plasma Oxidation to Form Graphene/SiC Structure with Low Pit Density2018

    • Author(s)
      K. Arima, R. Ito, O. Minami, K. Hosoo, Y. Sano, and K. Kawai
    • Organizer
      45th Conference on the Physics & Chemistry of Surfaces & Interfaces
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プラズマ酸化を援用して形成した低欠陥密度グラフェンの構造評価とその起源2018

    • Author(s)
      南映希、伊藤亮太、細尾幸平、佐野泰久、川合健太郎、有馬健太
    • Organizer
      第23回電子デバイス界面テクノロジー研究会
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Presentation] Plasma-assisted Oxidation of SiC Surface to Assist Forming Graphene with Low Pit Density2017

    • Author(s)
      Ryota Ito, Kohei Hosoo, Ouki Minami, Mizuho Morita, Yasuhisa Sano, Kentaro Kawai, Kenta Arima
    • Organizer
      The 8th International Symposium on Surface Science
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced Etching of Ge Surfaces in Water by Single Flakes of Graphene Catalysts2017

    • Author(s)
      K. Nakade, T. Hirano, S. Li, K. Kawai, M. Morita and K. Arima
    • Organizer
      Symposium on Surface Science & Nanotechnology - 25th Anniversary of SSSJ Kansai -
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbon Overlayer on 4H-SiC Surfaces by Plasma Oxidation at near Room Temperature Followed by Wet Etching2017

    • Author(s)
      K. Hosoo, R. Ito, K. Kawai, Y. Sano, M. Morita and K. Arima
    • Organizer
      Symposium on Surface Science & Nanotechnology - 25th Anniversary of SSSJ Kansai -
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Segregation of ions in deliquesced droplets of alkali-halide nano-crystals on SiO22016

    • Author(s)
      Kenta Arima
    • Organizer
      International Conference and Exhibition on Materials Chemistry
    • Place of Presentation
      Valencia, Spain
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ion Segregation in Deliquesced Droplets of Alkali Halide Nanocrystals on SiO2 Approached by both Surface Science Techniques and Electrical Characteristics2016

    • Author(s)
      Kenta Arima, Yoshie Kawai, Kentaro Kawai and Mizuho Morita
    • Organizer
      Collaborative Conference on 3D & Materials Research
    • Place of Presentation
      Seoul, South Korea
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pit Formation, Patterning and Flattening of Ge Surfaces in O2-Containing Water by Metal-Assisted Chemical Etching2016

    • Author(s)
      T. Kawase, A. Mura, Y. Saito, T. Okamoto, K. Kawai, Y. Sano, K. Yamauchi, M. Morita, and K. Arima
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2016
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of Aggregated Carbon Compounds at SiO2/SiC Interface after Plasma Oxidation at Near Room Temperature2016

    • Author(s)
      K. Arima, K. Hosoo, R. Ito, N. Saito, K. Kawai, Y. Sano, and M. Morita
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science 2016
    • Place of Presentation
      Honolulu, USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atomic-Scale Analysis of Semiconductor Surfaces after Wet-Chemical Treatments Such as Cleaning and Polishing2016

    • Author(s)
      Kenta Arima, Kentaro Kawai and Mizuho Morita
    • Organizer
      BIT's 6th Annual World Congress of Nano Science & Technology -2016
    • Place of Presentation
      Singapore
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 洗浄技術のコツ --Si表面のウェット洗浄2016

    • Author(s)
      有馬健太
    • Organizer
      第77回 応用物理学会秋季学術講演会
    • Place of Presentation
      新潟市
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Remarks] 有馬健太 ホームページ

    • URL

      http://www-pm.prec.eng.osaka-u.ac.jp/kenta_arima/index.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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