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An investigation of elecrodes interaction and optimal cell shape towards super-high current density operation of anode supported SOFCs

Research Project

Project/Area Number 15H03930
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionKyoto University

Principal Investigator

Iwai Hiroshi  京都大学, 工学研究科, 准教授 (00314229)

Co-Investigator(Kenkyū-buntansha) 吉田 英生  京都大学, 工学研究科, 教授 (50166964)
齋藤 元浩  京都大学, 工学研究科, 助教 (90314236)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2015: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywords固体酸化物形燃料電池 / 薄膜電解質 / 電極微構造 / 数値解析 / 実験 / 熱工学 / 燃料電池
Outline of Final Research Achievements

Recent SOFCs often utilize thin electrolytes of the order of a few microns. Its scale is approaching to the microstructure scale of porous electrodes. It means a change of the potential field in an electrode may affect the poential field in the thin electrolyte and the other electrode. In the first half of this study, we numerically investigated the interaction between a thin electrolyte and porous electrodes to find a non-uniform distribution of current density in the thin electrolyte. It also shows that the electrochemical reaction is most active near the interface. On the basis of this simulation results, the effects of the shape modification of thin electrolyte are investigated in the second half. It is found that the average current density of cells with shape-modification can be enhanced as a result of combined effects of the decrease of activation overpotential and ohmic loss.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (18 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results) Presentation (12 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results)

  • [Int'l Joint Research] AGH University of Science and Technology(ポーランド)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Institute of Materials Science of Aragon(スペイン)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Improved controllability of wet infiltration technique for fabrication of solid oxide fuel cell anodes2017

    • Author(s)
      Kishimoto Masashi、Kawakami Yuki、Otani Yuki、Iwai Hiroshi、Yoshida Hideo
    • Journal Title

      Scripta Materialia

      Volume: 140 Pages: 5-8

    • DOI

      10.1016/j.scriptamat.2017.06.054

    • NAID

      120006949381

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chromium poisoning in (La,Sr)MnO3 cathode: Three-dimensional simulation of a solid oxide fuel cell2016

    • Author(s)
      Kota Miyoshi, Hiroshi Iwai, Masashi Kishimoto, Saito Motohiro, Hideo Yoshida
    • Journal Title

      Journal of Power Sources

      Volume: 326 Pages: 331-340

    • DOI

      10.1016/j.jpowsour.2016.06.110

    • NAID

      120005997947

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exchange current model for (La0.8Sr0.2)0.95MnO3 (LSM) porous cathode for solid oxide fuel cells2016

    • Author(s)
      Kota Miyoshi, Takuma Miyamae, Hiroshi Iwai, Motohiro Saito, Masashi Kishimoto, Hideo Yoshida
    • Journal Title

      Journal of Power Sources

      Volume: 315 Pages: 63-69

    • DOI

      10.1016/j.jpowsour.2016.02.076

    • NAID

      120005997944

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local Evolution of Triple Phase Boundary in Solid Oxide Fuel Cell Stack after Long-Term Operation2015

    • Author(s)
      G. Brus, H. Iwai, Y. Otani, M. Saito, H. Yoshida, J.S. Szmyd
    • Journal Title

      Fuel Cells

      Volume: 15 Issue: 3 Pages: 545-548

    • DOI

      10.1002/fuce.201500027

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 固体酸化物形燃料電池の Ni-YSZ 多孔質燃料極への含浸法による Ni ナノ粒子導入の影響2018

    • Author(s)
      濱口直大,岸本将史,岩井裕,齋藤元浩,吉田英生
    • Organizer
      日本機械学会 関西学生会2017年度学生員卒業研究発表講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電極―電解質界面に微細な凹凸形状をもつ SOFC 単セルの三次元数値解析2018

    • Author(s)
      中川大志,岸本将史,岩井裕,齋藤元浩,吉田英生
    • Organizer
      日本機械学会 関西学生会2017年度学生員卒業研究発表講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Current Density Distribution in Thin Electrolyte of SOFC2017

    • Author(s)
      Hiroshi Iwai, Yuki Tanaka, Motohiro Saito, Masashi Kishimoto, Hideo Yoshida
    • Organizer
      The 11th Pacific Symposium on Flow Visualization and Image Processing
    • Related Report
      2017 Annual Research Report
  • [Presentation] 薄膜電解質を有するSOFCセルにおける電極間相互作用に関する数値解析2017

    • Author(s)
      門宮龍馬,岩井裕,岸本将史,齋藤元浩,吉田英生
    • Organizer
      第22回動力・エネルギー技術シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Determination of Representative Area for Two-Dimensional Analysis of SOFC Anode Microstructure2017

    • Author(s)
      Masashi Kishimoto, Grzegorz Brus, Katarzyna Berent, Hiroshi Iwai, Hideo Yoshida, Janusz Szmyd
    • Organizer
      第26回SOFC研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 3D Simulation of a Patterned LSM Cathode Considering Reaction on LSM/pore Double-Phase Boundary2016

    • Author(s)
      Takuma Miyamae, Hiroshi Iwai, Motohiro Saito, Masashi Kishimoto, Hideo Yoshida
    • Organizer
      12th European SOFC & SOE Forum
    • Place of Presentation
      ルツェルン、スイス
    • Year and Date
      2016-07-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Numerical study on current density distribution in a thin YSZ electrolyte of an SOFC2016

    • Author(s)
      Hiroshi Iwai, Yuki Tanaka, Motohiro Saito, Masashi Kishimoto, Hideo Yoshida
    • Organizer
      World Hydrogen Energy Conference 2016
    • Place of Presentation
      サラゴサ、スペイン
    • Year and Date
      2016-06-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Three-dimensional Numerical Simulation of a Solid Oxide Fuel Cell Based on Porous Microstructure of Electrodes Obtained by FIB-SEM2016

    • Author(s)
      Hiroshi Iwai
    • Organizer
      Energy Materials Nanotechnology Meeting on Fuel Cells
    • Place of Presentation
      済州島, 韓国
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 2D Numerical Simulation of Anode Supported Planner SOFC Considering Microstructure of Electrodes2015

    • Author(s)
      Nurul Zieyana,岩井裕,Grzegorz Brus,岸本将史,齋藤元浩,吉田英生
    • Organizer
      日本機械学会熱工学コンファレンス2015
    • Place of Presentation
      大阪大学(大阪)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Evaluation of Exchange Current Density for LSM Porous Cathode Based on Measurement of Three-Phase Boundary Length2015

    • Author(s)
      Kota Miyoshi, Takuma Miyamae, Hiroshi Iwai, Motohiro Saito, Masashi Kishimoto, Hideo Yoshida
    • Organizer
      14th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      グラスゴー(英国)
    • Year and Date
      2015-07-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Local Evolution of Three-Dimensional Microstructure Morphology of Planar Anode-Supported SOFC2015

    • Author(s)
      G. Brus, H. Iwai, Y. Otani, A. Sciazko, M. Saito, H. Yoshida, J. S. Szmyd
    • Organizer
      14th International Symposium on Solid Oxide Fuel Cells
    • Place of Presentation
      グラスゴー(英国)
    • Year and Date
      2015-07-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SOFC 用 LSM 空気極の多孔質微構造にもとづく交換電流密度の定式化2015

    • Author(s)
      三好航太,宮前卓磨,岩井裕,齋藤元浩, 吉田英生
    • Organizer
      第52回伝熱シンポジウム
    • Place of Presentation
      福岡国際会議場(福岡)
    • Year and Date
      2015-06-03
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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