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Study on Limiting Factors of Electron Mobility in SiC MOS Inversion Channel with Improved Quality Interface

Research Project

Project/Area Number 15H03969
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionThe University of Tokyo

Principal Investigator

Kita Koji  東京大学, 大学院工学系研究科(工学部), 准教授 (00343145)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2015: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords電気・電子材料 / 半導体物性 / パワーデバイス / 電界効果移動度 / デバイスプロセス / 熱酸化膜 / 炭化ケイ素 / 電界効果トランジスタ / 界面特性 / 電子・電気材料 / 表面・界面物性 / 省エネルギー / 電子デバイス・機器 / 欠陥準位 / 移動度
Outline of Final Research Achievements

It is well know that the channel mobility of SiC MOSFETs is significantly affected by the interface formation processes. In this study, we found that a slight amount of additional oxidation in H2O (wet oxidation) of SiC after a conventional dry oxidation can improve the channel mobility on Si-face significantly, and that the required oxidation thickness to be grown in the wet oxidation is only less than 1nm. It was also clarified that the mobility was most efficiently improved for the case of wet oxidation at low temperature in the ambient with both H2O and O2. From the infrared analysis of the near-interface SiO2 structure in the region within 2 nm from SiC, we found that wet oxidation results in less strained structure than dry oxidation, which suggests the possibility that such structural relaxation would reduce the defect state density in oxide film.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (51 results)

All 2018 2017 2016 2015 Other

All Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 5 results) Presentation (40 results) (of which Int'l Joint Research: 19 results,  Invited: 5 results) Remarks (2 results)

  • [Journal Article] Thermal-oxidation-induced local lattice distortion at surface of 4H-SiC(0001) characterized by in-plane X-ray diffractometry",2018

    • Author(s)
      Adhi Dwi Hatmanto and Koji Kita
    • Journal Title

      Applied Physics Express

      Volume: 11 Issue: 1 Pages: 011201-011201

    • DOI

      10.7567/apex.11.011201

    • NAID

      210000136054

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effects of high-temperature diluted-H2 annealing on effective mobility of SiC MOSFETs estimated by split capacitance-voltage technique2017

    • Author(s)
      Hirohisa Hirai and Koji Kita
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 11 Pages: 1113021-4

    • DOI

      10.7567/jjap.56.111302

    • NAID

      210000148419

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Difference of Near-Interface SiO2 Structures between O2-oxidation and H2O-oxidation of 4H-SiC (0001) and Its Impact on MOS Interface Characteristics2017

    • Author(s)
      Koji Kita, Hirohisa Hirai, and Kei Ishinoda
    • Journal Title

      ECS Transactions

      Volume: 80 (7) Issue: 7 Pages: 123-128

    • DOI

      10.1149/08007.0123ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of origins of the critically different MOS interface characteristics between dry-oxidized and wet-oxidized silicon carbide2017

    • Author(s)
      Koji Kita, Hirohisa Hirai, Hiroyuki Kajifusa, Kohei Kuroyama, Kei Ishinoda
    • Journal Title

      Microelectronic Engineering

      Volume: 178 Pages: 186-189

    • DOI

      10.1016/j.mee.2017.05.042

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Difference of near-interface strain in SiO2 between thermal oxides grown on 4H-SiC by dry-O2 oxidation and H2O oxidation characterized by infrared spectroscopy2017

    • Author(s)
      Hirohisa Hirai and Koji Kita
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 15 Pages: 152104-152104

    • DOI

      10.1063/1.4980093

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of Al2O3/SiO2 laminated stacks with multiple interface dipole layers to achieve large flatband voltage shifts of MOS capacitors2017

    • Author(s)
      Hironobu Kamata and Koji Kita
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 10

    • DOI

      10.1063/1.4978223

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Estimation of near-interface oxide trap density at SiO2/SiC metal-oxide-semiconductor interfaces by transient capacitance measurements at various temperatures2016

    • Author(s)
      Yuki Fujino and Koji Kita
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 8

    • DOI

      10.1063/1.4961871

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effects of High-Temperature Diluted-H2 Annealing on Effective Mobility of 4H-SiC MOSFETs with Thermally-Grown SiO22016

    • Author(s)
      Hirohisa Hirai and Koji Kita
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 4S Pages: 04ER16-04ER16

    • DOI

      10.7567/jjap.55.04er16

    • NAID

      210000146430

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quantitative Characterization of Near-Interface Oxide Traps in 4H-SiC MOS Capacitors by Transient Capacitance Measurements2015

    • Author(s)
      Yuki Fujino and Koji Kita
    • Journal Title

      ECS Transactions

      Volume: 69 (5) Issue: 5 Pages: 219-225

    • DOI

      10.1149/06905.0219ecst

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 窒化処理後に低温ウェット酸化処理をした4H-SiC MOS構造における界面準位密度とウェット酸化膜成長量の関係性2018

    • Author(s)
      作田良太,西田水輝,平井悠久,喜多浩之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Photo-assisted CV測定で評価するNITにみるNO-POAとwet-POA界面特性の違い2018

    • Author(s)
      西田水輝,作田良太,平井悠久,喜多浩之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] SiC MOSキャパシタにおけるバイアス印加時のVFB安定性に低温ウェット酸化が与える効果2018

    • Author(s)
      小柳 潤,平井悠久,喜多浩之
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Thermal-oxidation-induced lattice distortion at 4H-SiC (0001) surface and its recovery by Ar annealing2018

    • Author(s)
      Adhi Dwi Hatmanto and Koji Kita
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 4H-SiC MOS界面特性の制御のための熱酸化プロセスの設計2017

    • Author(s)
      喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 4H-SiC C面上MOS界面特性のウェット酸化による酸化膜成長量依存性にみられる界面欠陥減少過程と膜中欠陥変化過程の速度的差異2017

    • Author(s)
      平井悠久,喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸化レートの変化からみた4H-SiC Si面ウェット酸化雰囲気中に共存する酸素の役割2017

    • Author(s)
      石野田圭,平井悠久,喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] O2共存H2O雰囲気での界面近傍酸化膜成長による4H-SiC MOSFET移動度の向上2017

    • Author(s)
      平井悠久,喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 希土類元素存在下でのSiC/SiO2界面での酸窒化の促進2017

    • Author(s)
      作田良太,平井悠久,喜多浩之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Control of thermal oxidation of 4H-SiC (0001) to enhance MOSFET channel mobility by tuning partial pressures of oxidants (O2 and H2O) and oxidation temperature2017

    • Author(s)
      Hirohisa Hirai, Kei Ishinoda and Koji Kita
    • Organizer
      48th IEEE Semiconductor Interface Specialists Conference (SISC2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Change of SiO(N) Thermal Growth Kinetics and Element Distribution on 4H-SiC by Foreign Elements (La and N) Introduction2017

    • Author(s)
      Ryota Sakuta, Hirohisa Hirai and Koji Kita
    • Organizer
      2017 International Workshop on Dielectric Thin Films for Future Electron Devices (2017 IWDTF)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-Plane X-ray Diffractometry Study on Thermal Oxidation-induced Anomalous Lattice Distortion at 4H-SiC Surfaces2017

    • Author(s)
      Adhi Dwi Hatmanto and Koji Kita
    • Organizer
      2017 International Workshop on Dielectric Thin Films for Future Electron Devices (2017 IWDTF)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Lattice Distortion Existing Locally on the Surface of Thermally Oxidaized 4H-SiC (0001)2017

    • Author(s)
      Adhi Dwi Hatmanto and Koji Kita
    • Organizer
      応用物理学会先進パワー半導体分科会 第4回講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 異種元素導入(La, N)による4H-SiC上のSiO(N)成長速度と元素分布の変化2017

    • Author(s)
      作田良太,平井悠久,喜多浩之
    • Organizer
      応用物理学会先進パワー半導体分科会 第4回講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Difference of Near-Interface SiO2 Structures between O2-oxidation and H2O-oxidation of 4H-SiC (0001) and Its Impact on MOS Interface Characteristics2017

    • Author(s)
      Koji Kita, Hirohisa Hirai, and Kei Ishinoda
    • Organizer
      232nd The Electrochemical Society (ECS) Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interface-Selective Low-Temperature Wet-O2 Annealing to Enhance 4H-SiC (0001) MOSFET Mobility by Improving Near Interface SiO2 Quality2017

    • Author(s)
      Hirohisa Hirai, Kei Ishinoda and Koji Kita
    • Organizer
      International Conference on Silicon Carbide and Related Materials (ICSCRM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxidation-induced Lattice Distortion at 4H-SiC (0001) Surface Characterized by Surface Sensitive In-plane X-ray Diffractometry2017

    • Author(s)
      Adhi Dwi Hatmanto and Koji Kita
    • Organizer
      2017 International Conference on Solid State Devices and Materials (SSDM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics of Enhanced Oxide Growth on 4H-SiC in O2 and H2O Coexisting Ambient2017

    • Author(s)
      Kei Ishinoda and Koji Kita
    • Organizer
      2017 International Conference on Solid State Devices and Materials (SSDM 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of Origins of the Critically Different MOS Interface Characteristics between Dry-oxidized and Wet-Oxidized Silicon Carbide2017

    • Author(s)
      Koji Kita, Hirohisa Hirai, Hiroyuki Kajifusa, Kohei Kuroyama and Kei Ishinoda
    • Organizer
      20th Conference on Insulating Films on Semiconductors (INFOS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 4H-SiC C 面(000-1)のドライ及びウェット酸化条件によるMOS 界面特性への影響の理解2016

    • Author(s)
      梶房裕之,喜多浩之
    • Organizer
      応用物理学会先進パワー半導体分科会 第3回講演会
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2016-11-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] ウェット酸化雰囲気に共存する酸素の効果の理解に基づく4H-SiC 各結晶面のウェット酸化プロセスの設計2016

    • Author(s)
      平井悠久,喜多浩之
    • Organizer
      応用物理学会先進パワー半導体分科会 第3回講演会
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2016-11-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Impact of Sacrificial Cosumption of Substrate By Thermal Oxidation on Electron Mobility of 4H-SiC MOSFETs2016

    • Author(s)
      Koji Kita and Hirohisa Hirai
    • Organizer
      Pacific Rim Meeting on Electrochemcal and Solid State Science / 230th ECS Meeting
    • Place of Presentation
      Honolulu, HI, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Impacts on 4H-SiC MOSFET Mobility of High Temperatue Annealing in Oxidizing Or Inert Ambient before Gate Oxide Growth2016

    • Author(s)
      Hirohisa Hirai and Koji Kita
    • Organizer
      International Conference of Solid State Device and Materials 2016
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on the Guideline to Control Dry and Wet Oxidation Conditions to Improve 4H-SiC (000-1) C-face MOS Interface Characteristics2016

    • Author(s)
      Hiroyuki Kajifusa and Koji Kita
    • Organizer
      International Conference of Solid State Device and Materials 2016
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Opportunities to Design Thermal Oxidation and Post-Oxidation Processes to Control 4H-SiC MOS Interface Characteristics2016

    • Author(s)
      Koji Kita
    • Organizer
      International Conference of Solid State Device and Materials 2016
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ウェット酸化条件の制御による4H-SiC C面上MOS界面特性への影響2016

    • Author(s)
      梶房裕之,喜多浩之
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸化性および還元性雰囲気におけるゲート酸化膜成長前の高温熱処理がSiC MOSFET移動度に与える影響2016

    • Author(s)
      平井悠久,喜多浩之
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 4H-SiCの熱酸化過程の理解に基づくMOS特性の制御とその課題2016

    • Author(s)
      喜多浩之
    • Organizer
      第35回電子材料シンポジウム(EMS-35)
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県守山市)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Control of SiC thermal oxidation processes for the improvement of MOSFET performance2016

    • Author(s)
      Koji Kita, Hirohisa Hirai, Yuki Fujino and Hiroyuki Kajifusa
    • Organizer
      229th Meeting of the Electrochemical Society
    • Place of Presentation
      San Diego, CA, USA
    • Year and Date
      2016-05-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 4H-SiC m面上に形成された熱酸化膜の界面近傍における微視的構造の特徴の赤外分光法による解析2016

    • Author(s)
      黒山 滉平,平井 悠久,山本 建策,金村 髙司,喜多 浩之
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 4H-SiC MOSFET移動度に対する熱酸化による基板特性劣化とダメージ層除去効果の競合2016

    • Author(s)
      平井悠久,作田良太,喜多浩之
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 4H-SiC C面における高温・低O2分圧下ドライ酸化によるMOS界面特性の制御2016

    • Author(s)
      梶房裕之,喜多浩之
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 4H-SiC MOSキャパシタ界面近傍における電子と正孔の膜中トラップ密度分布の比較2016

    • Author(s)
      藤野雄貴,喜多浩之
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 4H-SiC/SiO2界面に対する高温ドライ酸化および高温希釈水素POAの効果2015

    • Author(s)
      平井悠久, 喜多浩之
    • Organizer
      応用物理学会先進パワー半導体分科会 第2回講演会
    • Place of Presentation
      大阪国際交流センター(大阪府大阪市)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Quantitative Characterization of Near-Interface Oxide Traps in 4H-SiC MOS Capacitors by Transient Capacitance Measurements2015

    • Author(s)
      Yuki Fujino and Koji Kita
    • Organizer
      228th Meeting of the Electrochemical Society
    • Place of Presentation
      Phoenix, AZ, USA
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Combination of High‐temperature Oxidation and Low‐temperature O2‐Annealing toward Nearly‐Ideal MOS Characteristics on 4H‐SiC (0001)2015

    • Author(s)
      Koji Kita, Richard Heihachiro Kikuchi, and Hirohisa Hirai
    • Organizer
      2015 Int. Conf. on Silicon Carbide and Related Materials
    • Place of Presentation
      Giardini Naxos, Italy
    • Year and Date
      2015-10-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Extraction of electron effective mobility of 4H‐SiC MOS inversion channel with thermally‐grown SiO2 by high‐frequency split C‐V technique2015

    • Author(s)
      Hirohisa Hirai and Koji Kita
    • Organizer
      2015 Int. Conf. on Silicon Carbide and Related Materials
    • Place of Presentation
      Giardini Naxos, Italy
    • Year and Date
      2015-10-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Removal of Near-Interface Oxide Traps at SiO2/SiC Interface by Post-Oxidation Annealing in Reducing Ambient2015

    • Author(s)
      Hiroyuki Kajifusa and Koji Kita
    • Organizer
      2015 Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      札幌コンベンションセンター(北海道 札幌市)
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of Near-Interface Oxide Trap Density in SiC MOS Capacitors by Transient Capacitance Measurements at Various Temperatures2015

    • Author(s)
      Yuki Fujino and Koji Kita
    • Organizer
      2015 Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      札幌コンベンションセンター(北海道 札幌市)
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of High-Temperature Diluted-H2 Annealing on Effective Mobility of 4H-SiC MOSFETs with Thermally-Grown SiO22015

    • Author(s)
      Hirohisa Hirai and Koji Kita
    • Organizer
      2015 Int. Conf. on Solid State Devices and Materials
    • Place of Presentation
      札幌コンベンションセンター(北海道 札幌市)
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 東京大学大学院工学系研究科マテリアル工学専攻 機能性ナノ薄膜工学 喜多研究室

    • URL

      http://www.scio.t.u-tokyo.ac.jp/index.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 東京大学大学院工学系研究科マテリアル工学専攻 喜多研究室

    • URL

      http://www.scio.t.u-tokyo.ac.jp/index.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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