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A study of contact resistance between phase change material and electrode for next generation PCRAM

Research Project

Project/Area Number 15H04113
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals/Metal-base materials
Research InstitutionTohoku University

Principal Investigator

Sutou Yuji  東北大学, 工学研究科, 准教授 (80375196)

Co-Investigator(Renkei-kenkyūsha) KOIKE Junichi  東北大学, 未来科学技術共同研究センター, 教授 (10261588)
ANDO Daisuke  東北大学, 大学院工学研究科, 助教 (50615820)
KOBAYASHI Keisuke (SAITO Yuta)  高知工科大学, 総合研究所, 客員教授 (50372149)
Research Collaborator SONG Yun-Heub  
SHINDO Satoshi  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords相変化メモリ / 不揮発性メモリ / アモルファス / 結晶 / 接触抵抗 / 表面・界面物性 / 電子・電気材料 / 金属物性 / 電極材料 / 結晶化
Outline of Final Research Achievements

With the scaling down of PCRAM cells, contact resistance between phase change material (PCM) and an electrode becomes a dominant factor in determining the memory cell resistance. In this study, we investigated the contact resistivity of PCM to a metal electrode. Then, we discussed the effect of the contact resistivity on the performance of the memory cell.
We found that an amorphous Cu2GeTe3 (CGT)/W contact shows schottky conduction, i.e., a CGT/W is dominated by interface conduction. Moreover, we found new PCM, Cr2Ge2Te6 (CrGT) with a high thermal stability in amorphous state. The CrGT showed inverse resistance change upon phase change (Ramo<Rcry). Although the resistivity change of the CrGT was only one order of magnitude, the contact resistivity change was found to reach two orders of magnitude upon phase change. I was also found that the CrGT memory cell achieves more than an 85% reduction in total operation energy compared with a conventional GST memory cell.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (48 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (20 results) (of which Int'l Joint Research: 10 results,  Peer Reviewed: 12 results,  Open Access: 1 results,  Acknowledgement Compliant: 7 results) Presentation (24 results) (of which Int'l Joint Research: 8 results,  Invited: 2 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Hanyang University(韓国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Hanyang University(韓国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Hanyang University(韓国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Inverse Resistance Change Cr2Ge2Te6-Based PCRAM Enabling Ultralow-Energy Amorphization2018

    • Author(s)
      Shogo Hatayama, Yuji Sutou, Satoshi Shindo, Yuta Saito, Yun-Heub Song, Daisuke Ando, and Junichi Koike
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 3 Pages: 2725-2734

    • DOI

      10.1021/acsami.7b16755

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Investigation of bias polarity dependence of set operation in GeCu2Te3 phase change memory2018

    • Author(s)
      J.S. An, K.J. Kim, C.M. Choi, S. Shindo, Y. Sutou, Y.H. Song
    • Journal Title

      Electronics Letters

      Volume: 54 Issue: 6 Pages: 350-351

    • DOI

      10.1049/el.2017.3902

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electronic Structure of Transition-Metal Based Cu2GeTe3 Phase Change Material: Revealing the Key Role of Cu d Electrons2017

    • Author(s)
      Y. Saito, Y. Sutou, P.Fons, S. Shindo, X. Kozina, J.M. Skelton, A.V. Kolovov, K. Kobayashi
    • Journal Title

      Chemistry of Materials

      Volume: 29 Issue: 17 Pages: 7440-7449

    • DOI

      10.1021/acs.chemmater.7b02436

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Molybdenum oxide-base phase change resistive switching material2017

    • Author(s)
      Y. Ogawa, S. Shindo, Y. Sutou, J. Koike
    • Journal Title

      Applied Physics Letters

      Volume: 111 Issue: 16 Pages: 163105-163105

    • DOI

      10.1063/1.5000410

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inverse resistance change behavior of Cr2Ge2Te6 phase change material2017

    • Author(s)
      S. Hatayama, Y. Sutou, S. Shindo, Y. Saito, Y.H. Song, D. Ando, J. Koike
    • Journal Title

      Proceedings of Eropean Phase Change and Ovonic Symposium

      Volume: 1 Pages: 174-175

    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] Phase chaneg behaviro of N-doped Cr-Ge-Te film2017

    • Author(s)
      Y. Shunag, S. Hatayama, S. Shindo, D. Ando, Y. Sutou, J. Koike
    • Journal Title

      Proceedings of European Phase Change and Ovonic Symposium

      Volume: 1 Pages: 176-177

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Interfaical properties of electrdes/GeCu2Te3 phase change material2017

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, J.S. An, Y.H. Song, Y. Saito, P. Fons, K. Kobayashi
    • Journal Title

      Proceedings of the 29th symposium on Phase Change Oriented Science

      Volume: 1 Pages: 33-34

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Inverse resistance switching behavior of Cr2Ge2Te6-based PCRAM2017

    • Author(s)
      S. Hatayama, Y. Sutou, S. Shindo, Y. Saito, Y.H. Song, D. Ando, J. Koike
    • Journal Title

      Proceedings of the 29th symposium on Phase Change Oriented Science

      Volume: 1 Pages: 35-36

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Effects of nitrogen doping on the properties of Cr-Ge-Te ternary compound film2017

    • Author(s)
      Y. Shuang, S. Hatayama, S. Shindo, D. Ando, Y. Sutou, J. Koike
    • Journal Title

      Proceedings of the 29th symposium on Phase Change Oriented Science

      Volume: 1 Pages: 55-56

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Effect of surface cleaning on contact resistivity of amorphous GeCu2Te3 to a W electrode2016

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, Y. Saito and Y.-H. Song
    • Journal Title

      MRS advances

      Volume: 1 Issue: 39 Pages: 2731-2736

    • DOI

      10.1557/adv.2016.310

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Resistance contrast of GeCu2Te3 phase change memeory cell2016

    • Author(s)
      S. Shindo, Y.Sutou, J. Koike, Y. Saito, J.S. An, Y.H. Song
    • Journal Title

      European/Phase Change and Ovonics Symposium (E/PCOS2016) Proceedings

      Volume: 1 Pages: 195-196

    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A study on phase transition behaviors of GeCu2Te3 phase change material for PCRAM application2016

    • Author(s)
      Y. Sutou, S. Shindo, Y. Saito, J. Koike, H.Y. Song
    • Journal Title

      Proceedings of the 28th Symposium on Phase Change Oriented Science (PCOS2016)

      Volume: 1 Pages: 52-55

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Switching behavior of GeCu2Te3 phase change memory cell2016

    • Author(s)
      S. Shindo, Y.Sutou, J. Koike, Y. Saito, J.S. An, Y.H. Song
    • Journal Title

      Proceedings of the 28th Symposium on Phase Change Oriented Science (PCOS2016)

      Volume: 1 Pages: 69-70

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] The doping effect of V, Cr and Ni on the crystallization behavior of GeTe amorphous film2016

    • Author(s)
      S. Hatayama, M. Shimoda, S. SHindo, Y. Sutou, J. Koike
    • Journal Title

      European/Phase Change and Ovonics Symposium (E/PCOS2016) Proceedings

      Volume: 1 Pages: 199-200

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Phase change behaviors of Cr-Ge-Te compound thin film2016

    • Author(s)
      S. Hatayama, S. SHindo, Y. Sutou, J. Koike
    • Journal Title

      Proceedings of the 28th Symposium on Phase Change Oriented Science (PCOS2016)

      Volume: 1 Pages: 71-72

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact of contact resistance on memory window in phase-change random access memory (PCRAM)2016

    • Author(s)
      J.S. An, C.M. Choi, S. Shindo, Y. Sutou, Y.W. Kwon, Y.H. Song
    • Journal Title

      Journal of Computational Electronics

      Volume: 15 Issue: 4 Pages: 1570-1576

    • DOI

      10.1007/s10825-016-0905-3

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Contact resistivity of amorphous and crystalline GeCu2Te3 to W electrode for phase change random access memory2016

    • Author(s)
      S. Shindo, Y, Sutou, J. Koike, Y. Saito, Y.H. Song
    • Journal Title

      Materials Science in Semiconductor Processing

      Volume: 47 Pages: 1-6

    • DOI

      10.1016/j.mssp.2016.02.006

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Contact resistivity change of GeCu2Te3 to W electrode by crystallization2015

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, Y. Saito
    • Journal Title

      Proceedings of the 27th Symposium on Phase Change Oriented Science

      Volume: 1 Pages: 67-68

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Contact resistivity of GeCu2Te3 phase change material on W electrode2015

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, Y. Saito
    • Journal Title

      European Symposium on Phase Change and Ovonic Science proceedings

      Volume: 1 Pages: 147-148

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Crysatlization behavior of Cr-Ge-Te thin films2015

    • Author(s)
      S. Hatayama, S. SHindo, Y. Sutou, J. Koike
    • Journal Title

      Proceedings of the 27th Symposium on Phase Change Oriented Science

      Volume: 1 Pages: 65-66

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Phase chnage characteristics of TM-Ge-Te (TM:Cu and Cr) compound films for PCRAM2018

    • Author(s)
      Y. Sutou, S. Shindo, S. Hatayama, Y. Shuang, J. Koike, Y. Saito
    • Organizer
      2018 MRS Spring meeting&exhibit
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Cr2Ge2Te6を用いた相変化メモリの動作特性2018

    • Author(s)
      畑山祥吾、須藤祐司、安藤大輔、小池淳一
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Inverse resistance change behavior of Cr2Ge2Te6 phase change material2017

    • Author(s)
      S. Hatayama, Y. Sutou, S. Shindo, Y. Saito, Y.H. Song, D. Ando, J. Koike
    • Organizer
      Eropean Phase Change and Ovonic Symposium (EPCOS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Phase chaneg behaviro of N-doped Cr-Ge-Te film2017

    • Author(s)
      Y. Shunag, S. Hatayama, S. Shindo, D. Ando, Y. Sutou, J. Koike
    • Organizer
      Eropean Phase Change and Ovonic Symposium (EPCOS2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interfaical properties of electrdes/GeCu2Te3 phase change material2017

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, J.S. An, Y.H. Song, Y. Saito, P. Fons, K. Kobayashi
    • Organizer
      The 29th symposium on Phase Change Oriented Science (PCOS2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Inverse resistance switching behavior of Cr2Ge2Te6-based PCRAM2017

    • Author(s)
      S. Hatayama, Y. Sutou, S. Shindo, Y. Saito, Y.H. Song, D. Ando, J. Koike
    • Organizer
      The 29th symposium on Phase Change Oriented Science (PCOS2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effects of nitrogen doping on the properties of Cr-Ge-Te ternary compound film2017

    • Author(s)
      Y. Shuang, S. Hatayama, S. Shindo, D. Ando, Y. Sutou, J. Koike
    • Organizer
      The 29th symposium on Phase Change Oriented Science (PCOS2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Transition metal-Ge-Te chalcogenides for PCRAM material2017

    • Author(s)
      Y. Sutou, S. Shindo, S. Hatayama, Y. Saito, J. Koike
    • Organizer
      2017 International Conference on Soilid State Devices and Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A study on phase transition behaviors of GeCu2Te3 phase change material for PCRAM application2016

    • Author(s)
      Y. Sutou, S. Shindo, Y. Saito, J. Koike, H.Y. Song
    • Organizer
      The 28th Symposium on Phase Change Oriented Science (PCOS2016)
    • Place of Presentation
      KKRホテル熱海、熱海
    • Year and Date
      2016-11-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] W電極/GeCu2Te3相変化材料間のコンタクト抵抗2016

    • Author(s)
      進藤怜史、須藤祐司、安藤大輔、小池淳一、齊藤雄太
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大阪大学、大阪
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] GeTe薄膜の相変化挙動に及ぼすCr添加の影響2016

    • Author(s)
      畑山祥吾、進藤怜史、須藤祐司、小池淳一、齊藤雄太
    • Organizer
      日本金属学会2016年秋期講演大会
    • Place of Presentation
      大阪大学、大阪
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Resistance contrast of GeCu2Te3 phase change memeory cell2016

    • Author(s)
      S. Shindo, Y.Sutou, J. Koike, Y. Saito, J.S. An, Y.H. Song
    • Organizer
      European/Phase Change and Ovonics Symposium (E/PCOS2016)
    • Place of Presentation
      Cambridge, United Kingdom
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The doping effect of V, Cr and Ni on the crystallization behavior of GeTe amorphous film2016

    • Author(s)
      S. Hatayama, M. Shimoda, S. SHindo, Y. Sutou, J. Koike
    • Organizer
      European/Phase Change and Ovonics Symposium (E/PCOS2016)
    • Place of Presentation
      Cambridge, United Kingdom
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Phase-change induced contact resistance changes of GeCu2Te3/metal contact due to phase change transitions2016

    • Author(s)
      S. Shindo, Y, Sutou, J. Koike, Y. Saito, H. Song
    • Organizer
      2016 MRS Spring Meeting&Exhibit
    • Place of Presentation
      Phoenix, United States of America
    • Year and Date
      2016-03-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cr-Ge-Te化合物薄膜の相変化挙動2016

    • Author(s)
      畑山 祥吾、進藤 怜史、安藤 大輔、須藤 祐司、小池 淳一
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東工大 大岡山キャンパス, 東京
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Switching behavior of GeCu2Te3 phase change memory cell2016

    • Author(s)
      S. Shindo, Y.Sutou, J. Koike, Y. Saito, J.S. An, Y.H. Song
    • Organizer
      The 28th Symposium on Phase Change Oriented Science (PCOS2016)
    • Place of Presentation
      KKRホテル熱海、熱海
    • Related Report
      2016 Annual Research Report
  • [Presentation] Phase change behaviors of Cr-Ge-Te compound thin film2016

    • Author(s)
      S. Hatayama, S. SHindo, Y. Sutou, J. Koike
    • Organizer
      The 28th Symposium on Phase Change Oriented Science (PCOS2016)
    • Place of Presentation
      KKRホテル熱海、熱海
    • Related Report
      2016 Annual Research Report
  • [Presentation] Crystallization behavior of Cr-Ge-Te thin films2015

    • Author(s)
      S.Hatayama, S. Shindo, Y. Suto, J. Koike
    • Organizer
      The 27th Symposium on Phase Change Oriented Science
    • Place of Presentation
      熱海ニューフジヤホテル, 熱海
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Contact resistivity change of GeCu2Te3 to W electrode by crystallization2015

    • Author(s)
      S.Shindo, Y. Sutou, J. Koike, Y. Saito
    • Organizer
      The 27th Symposium on Phase Change Oriented Science
    • Place of Presentation
      熱海ニューフジヤホテル, 熱海
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] GeTe-CuTe擬二元系薄膜の相変化挙動2015

    • Author(s)
      須藤祐司, 齊藤雄太, 進藤怜史, 小池淳一
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場, 名古屋
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Cr-Ge-Te薄膜の相変化挙動2015

    • Author(s)
      畑山祥吾, 安藤大輔, 須藤祐司, 小池淳一
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場, 名古屋
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] フェムト秒レーザパルスによるGeCuTe の相変化誘起と高速シャッターへの応用の検討2015

    • Author(s)
      秋本良太, 森本悠介, 須藤 祐司, 進藤 怜史, 桑原正史, 斎木敏治
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場, 名古屋
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] W電極上のGeCu2Te3の相変態に伴う界面接触抵抗変化2015

    • Author(s)
      進藤 怜史、須藤 祐司、小池 淳一、齊藤 雄太
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場, 名古屋
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Contact resistivity of GeCu2Te3 phase change material on W electrode2015

    • Author(s)
      S. Shindo, Y. Sutou, J. Koike, Y. Saito
    • Organizer
      European/Phase Change and Ovonics Symposium 2015
    • Place of Presentation
      Amsterdam, Netherlands
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] 相変化材料および相変化メモリ素子2015

    • Inventor(s)
      須藤祐司、畑山祥吾、進藤怜史、小池淳一、齊藤雄太
    • Industrial Property Rights Holder
      東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-246075
    • Filing Date
      2015-12-17
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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