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Development of polar materials by the control of the arrangement of cations and the Coulomb repulsion between cations

Research Project

Project/Area Number 15H04128
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionGakushuin University

Principal Investigator

Inaguma Yoshiyuki  学習院大学, 理学部, 教授 (00240755)

Co-Investigator(Kenkyū-buntansha) 勝又 哲裕  東海大学, 理学部, 教授 (90333020)
Co-Investigator(Renkei-kenkyūsha) MORI Daisuke  三重大学, 工学研究科, 准教授 (00432021)
UEDA Koichiro  学習院大学, 理学部, 助教 (60794089)
Research Collaborator KOJITANI Hiroshi  
AKAOGI Masaki  
NAKAYAMA Masanobu  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Keywords極性化合物 / 高圧合成 / リチウムナイベート / ペロブスカイト / 強誘電性 / 陽イオン反発 / リチウムナイオベート型化合物 / ペロブスカイト型酸化物 / セラミックス / リチウムナイオベート / ぺロブスカイト / 極性
Outline of Final Research Achievements

Polar materials exhibit functionalities attributable to the non-centrosymmetry such as ferroelectricity, piezoelectricity, pyroelectricity, and second-order nonlinear optical behavior, and are technologically important because they can be applied to electronic and optical devices such as memory and laser materials. In this study, we aimed to develop polar oxide-based materials by the control of the arrangement of cations and the Coulomb repulsion between cations. Consequently, we have successfully synthesized several polar materials under high-pressure of several GPa. We have analyzed the crystal structure, evaluated the physical properties, and elucidated the relationship between the structure and polarity.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (23 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] University of Texas at Austin(米国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Synthesis of new LiNbO3-type oxynitrides, Mn(Mn1/6Ta5/6)O2.5N0.5under high pressure and at high temperature2018

    • Author(s)
      Tetsuhiro Katsumata, Chizuru Ohba, Ayana Tobe, Atsushi Takeda, Mei Shoji, Akihisa Aimi, Daisuke Mori, and Yoshiyuki Inaguma
    • Journal Title

      Chem. Lett.

      Volume: 47 Issue: 1 Pages: 37-39

    • DOI

      10.1246/cl.170851

    • NAID

      130006301996

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] New Mechanism for Ferroelectricity in the Perovskite Ca2-xMnxTi2O6 Synthesized by Spark Plasma Sintering2018

    • Author(s)
      Zongyao Li, Yujin Cho, Xiang Li, Xinyu Li, Akihisa Aimi, Yoshiyuki Inaguma, Jose A. Alonso, Maria T. Fernandez-Diaz, Jiaqiang Yan, Michael C. Downer, Graeme Henkelman, John B. Goodenough, and Jianshi Zhou
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 140 Issue: 6 Pages: 2214-2220

    • DOI

      10.1021/jacs.7b11219

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Phase transitions and dielectric properties of perovskite-type oxyfluorides (1-x)KNbO3-xKMgF32018

    • Author(s)
      Tetsuhiro Katsumata, Nobuhiro Sawada, Ryosuke Kuraya, Takuma Hamagaki, Akihisa Aimi, Daisuke Mori, Yoshiyuki Inaguma, Ruing Ping Wang
    • Journal Title

      J. Fluorine Chemistry

      Volume: 209 Pages: 65-72

    • DOI

      10.1016/j.jfluchem.2018.02.010

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-pressure high-temperature phase relations in FeTiO3 up to 35 GPa and 1600 ºC2017

    • Author(s)
      M. Akaogi, K. Abe, H. Yusa, T. Ishii, T. Tajima, H. Kojitani, D. Mori, Y. Inaguma
    • Journal Title

      Phys. Chem. Minerals

      Volume: 44 Issue: 1 Pages: 63-73

    • DOI

      10.1007/s00269-016-0836-3

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, direct formation under high pressure, structure, and electronic properties of LiNbO3-type oxide PbZnO32015

    • Author(s)
      Daisuke Mori, Kie Tanaka, Kie, Hiroyuki Saitoh, Takumi Kikegawa, Yoshiyuki Inaguma
    • Journal Title

      Inorg. Chem.

      Volume: 54 Issue: 23 Pages: 11405-11410

    • DOI

      10.1021/acs.inorgchem.5b02049

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 正方晶PbFeO2Fの合成と結晶構造2017

    • Author(s)
      勝又哲裕、佐藤直人、植田紘一郎、稲熊宜之
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 極性構造をもつぺロブスカイト関連極性化合物の高圧合成と機能開拓2017

    • Author(s)
      稲熊宜之、相見晃久、森大輔、勝又哲裕、濵嵜容丞、植田紘一郎
    • Organizer
      第58回高圧討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Synthesis and structure of perovskite-type oxyfluorides2017

    • Author(s)
      T. Katsumata, M. Nakashima, Y. Inaguma, D. Mori, A. Aimi
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] High-pressure synthesis, structure, and properties of perovskite-related transition-metal oxides, fluorides, and mixed-anion compounds2017

    • Author(s)
      Y. Inaguma, K. Sugimoto, A. Ichihara, D. Mori, K. Ueda, T. Katsumata
    • Organizer
      International Union of Materials Research Society-15th International Conference of Advanced Materials (IUMRS-ICAM)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of mixed-anion compounds under high pressure and high temperature2016

    • Author(s)
      Tetsuhiro Katsumata, Mamoru Nakashima, Daisuke Mori, Yoshiyuki Inaguma, Akihisa Aimi
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      万国橋会議センター(神奈川)
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 高温高圧発生装置、トポケミカル反応を使用したリチウムナイオベート酸化物、Cu1-xLixTaO3の合成2016

    • Author(s)
      岡崎有莉香、勝又哲裕
    • Organizer
      第11回セラミックスフェスタin神奈川
    • Place of Presentation
      神奈川大学 横浜キャンパス(神奈川)
    • Year and Date
      2016-12-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] リチウムナイオベート型酸化物固溶体、(1-x)LiTaO3-xMn(Mn1/3Ta2/3)O3の構造と相転移2016

    • Author(s)
      勝又哲裕, 乙部嵯稀, 植田紘一郎, 佐山暁久, 森大輔, 稲熊宜之, 相見晃久
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス(広島)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] A サイト秩序型二重ペロブスカイト酸化物 CaMn1-xZnxTi2O6の高圧合成、構造、誘電性2016

    • Author(s)
      森大輔、赤間洋平、相見晃久、稲熊宜之
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス(広島)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] リチウムナイオベート型酸化物,xLiTaO3-(1-x)Mn4Ta2O9,固溶体の合成2016

    • Author(s)
      乙部嵯稀、勝又哲裕
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学 京田辺(京都)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] High-pressure synthesis and ferroelectricity of A-site ordered double perovskite oxide CaA’Ti2O6 (A’: divalent cation)2015

    • Author(s)
      Y. Akama, D. Mori, Y. Inaguma
    • Organizer
      PACIFICHEM 2015 (The 2015 International Chemical Congress of Pacific Basin Societies)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-pressure synthesis, formation behavior, structure, and electronic conductivity of PbZnO3 with LiNbO3-type structure2015

    • Author(s)
      D. Mori, K. Tanaka, Y. Inaguma
    • Organizer
      PACIFICHEM 2015 (The 2015 International Chemical Congress of Pacific Basin Societies)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 新規 LiNbO3型酸化物 PbZnO3の高圧合成および相変化挙動、構造、電気伝導性2015

    • Author(s)
      森大輔、田中樹恵、稲熊宜之
    • Organizer
      日本セラミックス協会 第28回秋季シンポジウム
    • Place of Presentation
      富山大学 五福キャンパス(富山)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 極性構造をもつぺロブスカイト関連化合物の探索―陽イオン配列と元素選択―2015

    • Author(s)
      稲熊宜之、相見晃久、森大輔、勝又哲裕、中山将伸
    • Organizer
      日本セラミックス協会 第28回秋季シンポジウム
    • Place of Presentation
      富山大学 五福キャンパス(富山)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Synthesis of mixed-anion compounds under high pressure and high temperature2015

    • Author(s)
      Tetsuhiro Katsumata, Ayana Tobe, Chizuru Ohba, Atsushi Takeda, Akihisa Aimi, Daisuke Mori, Yoshiyuki Inaguma
    • Organizer
      2015 E-MRS Spring Meeting
    • Place of Presentation
      Strasbourg, France
    • Year and Date
      2015-05-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Book] “Hand Book of Solid State Chemistry” edited by R. Dronskowski, S. Kikkawa, and A. Stein, Volume 2 Synthesis, Chapter 32017

    • Author(s)
      Yoshiyuki Inaguma
    • Total Pages
      58
    • Publisher
      Wiley VCH
    • Related Report
      2017 Annual Research Report
  • [Remarks] http://www-cc.gakushuin.ac.jp/~19990787/group/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 学習院大学稲熊研究室ホームページ

    • URL

      http://www-cc.gakushuin.ac.jp/~19990787/group/studies.html

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2022-08-26  

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