Development of polar materials by the control of the arrangement of cations and the Coulomb repulsion between cations
| Project/Area Number |
15H04128
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic materials/Physical properties
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| Research Institution | Gakushuin University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
勝又 哲裕 東海大学, 理学部, 教授 (90333020)
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| Co-Investigator(Renkei-kenkyūsha) |
MORI Daisuke 三重大学, 工学研究科, 准教授 (00432021)
UEDA Koichiro 学習院大学, 理学部, 助教 (60794089)
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| Research Collaborator |
KOJITANI Hiroshi
AKAOGI Masaki
NAKAYAMA Masanobu
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| Project Period (FY) |
2015-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2017: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
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| Keywords | 極性化合物 / 高圧合成 / リチウムナイベート / ペロブスカイト / 強誘電性 / 陽イオン反発 / リチウムナイオベート型化合物 / ペロブスカイト型酸化物 / セラミックス / リチウムナイオベート / ぺロブスカイト / 極性 |
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| Outline of Final Research Achievements |
Polar materials exhibit functionalities attributable to the non-centrosymmetry such as ferroelectricity, piezoelectricity, pyroelectricity, and second-order nonlinear optical behavior, and are technologically important because they can be applied to electronic and optical devices such as memory and laser materials. In this study, we aimed to develop polar oxide-based materials by the control of the arrangement of cations and the Coulomb repulsion between cations. Consequently, we have successfully synthesized several polar materials under high-pressure of several GPa. We have analyzed the crystal structure, evaluated the physical properties, and elucidated the relationship between the structure and polarity.
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Report
(4 results)
Research Products
(23 results)
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[Journal Article] New Mechanism for Ferroelectricity in the Perovskite Ca2-xMnxTi2O6 Synthesized by Spark Plasma Sintering2018
Author(s)
Zongyao Li, Yujin Cho, Xiang Li, Xinyu Li, Akihisa Aimi, Yoshiyuki Inaguma, Jose A. Alonso, Maria T. Fernandez-Diaz, Jiaqiang Yan, Michael C. Downer, Graeme Henkelman, John B. Goodenough, and Jianshi Zhou
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Journal Title
J. Am. Chem. Soc.
Volume: 140
Issue: 6
Pages: 2214-2220
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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