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Self-assemble structure and functional properties of self-bonding inorganic filler / networked polymer alloy composites

Research Project

Project/Area Number 15H04135
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionUniversity of Hyogo

Principal Investigator

KISHI HAJIME  兵庫県立大学, 工学研究科, 教授 (60347523)

Co-Investigator(Renkei-kenkyūsha) MATSUDA Satoshi  兵庫県立大学, 大学院工学研究科, 准教授 (40316047)
KAKIBE Takeshi  兵庫県立大学, 大学院工学研究科, 助教 (00633728)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywordsエポキシ / 相構造 / フィラー / 複合材 / 伝導 / 複合材料 / エポキシ樹脂 / ポリマーアロイ / 自己組織化 / 熱伝導
Outline of Final Research Achievements

Our research aimed to find leading principles on self-assembling and self-bonding of fillers in filler reinforced composites using epoxy polymer alloys as the matrix. In order to shorten the distance between the fillers and to make their continuous structure, co-continuous phase structures of the epoxy polymer alloys were applied as the templates. Various surface treatments were performed on the fillers and the correlation between the filler location in the composites and the surface treatments was studied. In case using a silane coupling treatment, alumina fillers were selectively located at the interface of the phase structures in aromatic amine cured epoxy / polyethersulfone blends, resulting in the continuous channel of the fillers. In detail, the location of the fillers was influenced by the filler size. The interfacial arrangement of the alumina fillers was generated in case of sub-micrometer fillers, but the micrometer-size fillers remained selectively in the epoxy-rich phase.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (14 results)

All 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results)

  • [Journal Article] Peel Adhesive Properties of Epoxy / Acrylic Block Copolymer Blends;Effect of in-situ Formed Nanophase Structures2017

    • Author(s)
      山田和義,岸 肇
    • Journal Title

      Journal of The Adhesion Society of Japan

      Volume: 53 Issue: 9 Pages: 296-302

    • DOI

      10.11618/adhesion.53.296

    • NAID

      130007495167

    • ISSN
      0916-4812, 2187-4816
    • Year and Date
      2017-09-01
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical Properties of Epoxy / Acrylic Block CopolymerBlends; Effect of in-situ Formed Nanophase Structure2017

    • Author(s)
      山田和義,岸 肇
    • Journal Title

      Journal of The Adhesion Society of Japan

      Volume: 53 Issue: 7 Pages: 228-234

    • DOI

      10.11618/adhesion.53.228

    • NAID

      130007493331

    • ISSN
      0916-4812, 2187-4816
    • Year and Date
      2017-07-01
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of nanostructures in epoxy/acrylic block copolymer blends by the in situ generation of functional groups2017

    • Author(s)
      Kazuyoshi Yamada, Hajime Kishi
    • Journal Title

      Polymer Journal

      Volume: 49 Issue: 8 Pages: 617-623

    • DOI

      10.1038/pj.2017.26

    • NAID

      40021272587

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between the mechanical properties of epoxy/PMMA-b-PnBA-b-PMMA block copolymer blends and their three-dimensional nanostructures2017

    • Author(s)
      Hajime Kishi, Yumi Kunimitsu, Yasuaki Nakashima, Jin Imade, Shinya Oshita, Yoshihiro Morishita, Mitsunori Asada
    • Journal Title

      Express Polymer Letters

      Volume: 11 Issue: 10 Pages: 765-777

    • DOI

      10.3144/expresspolymlett.2017.74

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Self-assembled three dimensional structure of epoxy / polyethersulphone / silver adhesives with electrical conductivity2016

    • Author(s)
      Hajime Kishi, Sanae Tanaka, Yasuaki Nakashima, Takashi Saruwatari
    • Journal Title

      Polymer

      Volume: 82 Pages: 93-99

    • DOI

      10.1016/j.polymer.2015.11.043

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of miscible PMMA chain length on disordered morphologies in epoxy/PMMA-b-PnBA-b-PMMA blends by in situ simultaneous SAXS/DSC2016

    • Author(s)
      Mitsunori Asada, Shinya Oshita, Yoshihiro Morishita, Yasuaki Nakashima, Yumi Kunimitsu, Hajime Kishi
    • Journal Title

      Polymer

      Volume: 105 Pages: 172-179

    • DOI

      10.1016/j.polymer.2016.10.025

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] エポキシ/ブロック共重合体ポリマーブレンドのナノ相構造とin-situ界面制御2017

    • Author(s)
      岸 肇、山田和義
    • Organizer
      第66回高分子討論会(高分子学会主催)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] エポキシポリマーブレンドの物性発現機構2017

    • Author(s)
      岸 肇
    • Organizer
      第67回ネットワークポリマー講演討論会(合成樹脂工業協会主催)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Control of nanostructures and mechanical properties of epoxy / acrylic block copolymer blends using a small amount of catalyst or different blending process2016

    • Author(s)
      Hajime Kishi, Kazuyoshi Yamada, Jin Kimura
    • Organizer
      The 11th European Adhesion Conference (EURADH2016)
    • Place of Presentation
      Glasgow, UK
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of nano-phase structures of epoxy / acrylic block copolymer blends using a small amount of catalyst2016

    • Author(s)
      Kazuyoshi Yamada, Jin Kimura, Hajime Kishi
    • Organizer
      The 6th Asian Conference on Adhesion (ACA 2016)
    • Place of Presentation
      Tokyo Ins. of Tech., Tokyo, Japan
    • Year and Date
      2016-06-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリマーアロイによるエポキシ樹脂高機能化2016

    • Author(s)
      岸 肇
    • Organizer
      エポキシ樹脂技術協会研究委員会・特別講演会
    • Place of Presentation
      グランドヒル市ヶ谷(東京都)
    • Year and Date
      2016-03-31
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] エポキシポリマーアロイを活用したフィラー系複合材料の機能発現2016

    • Author(s)
      岸 肇
    • Organizer
      高分子学会H27年度東海シンポジウム
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Year and Date
      2016-01-25
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Epoxy / functional filler composites using phase structures of epoxy polymer alloys2015

    • Author(s)
      Hajime Kishi
    • Organizer
      The 5th Asian Symposium on Advanced Materials
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2015-11-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Functional networked polymers derived from nanostructured epoxy / block co-polymer blends2015

    • Author(s)
      Hajime Kishi
    • Organizer
      IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      Yokohma, Japan
    • Year and Date
      2015-10-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2015-04-16   Modified: 2019-03-29  

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