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organic/inorganic core-shall elastic spherical blast materials having One-Stop super abrasive properties

Research Project

Project/Area Number 15H04137
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Composite materials/Surface and interface engineering
Research InstitutionKumamoto Industrial Research Institute

Principal Investigator

Nagaoka Shoji  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究主幹 (10227994)

Co-Investigator(Kenkyū-buntansha) 伊原 博隆  熊本大学, 大学院先端科学研究部(工), 教授 (10151648)
堀川 真希  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究主任 (50588465)
城崎 智洋  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究主任 (70554054)
龍 直哉  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究員 (90743641)
Co-Investigator(Renkei-kenkyūsha) SAGAWA Takashi  京都大学, 大学院・エネルギー科学研究科, 教授 (20225832)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2015: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Keywords表面・界面物性 / 複合粒子 / 研磨材 / 有機/無機複合粒子 / 精密研磨 / 有機/無機複合粒子
Outline of Final Research Achievements

We examined the core-shell microspheres composed of polybutadiene (PBD, syndiotactic 1,2-polybutadiene (SPBD) and cis and trans 1,4-polybutadiene (CPBD) ) and ceramic materials were prepared, with a control of facial and elastic property, in order to develop the elastic blasting materials. The PBD microsphers were obtained using suspension evaporation method. The typical spherical particulates were obtained. On the other hand, the surface-modification on the ceramic materials, i.e. Al2O3 particles, was performed using (3-mercaptopropyl) trimethoxysilane (MPS). Immobilization of MPS-ceramic materials on surface of SPBD/CPBD microsphere were carried out by the ene-thiol reaction between double bonds in SPBD and SH groups in MPS-modified ceramic particles. As a result, the surface of microsphere could be covered with ceramic particles. In addition, we confirmed that the elasticity of microspheres could be controlled by the addition of CPBD to SPBD.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (8 results)

All 2018 2017 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Cellulose/boron nitride core/shell microbeads providing high thermal conductivity for thermally conductive composite sheets2016

    • Author(s)
      Shoji Nagaoka, Takuma Jodai, Yoshihiro Kameyama, Maki Horikawa, Tomohiro Shirosaki, Naoya Ryu, Makoto Takafuji, Hideo Sakurai and Hirotaka Ihara
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 39 Pages: 33036-33042

    • DOI

      10.1039/c6ra02950g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Development of Soft-Rigid Layer Core-Shell Microsphere using Polybutadiene and Inorganic Materials2018

    • Author(s)
      Shoji Nagaoka , Hideo Sakurai, Yangwon Kang, Tomohiro Shirosaki, Maki Horikawa, Naoya Ryu, Makoto Takafuji, and Hirotaka Ihara
    • Organizer
      The 6th Asian Symposium on Emulsion Polymerization and Functional Polymeric Microspheres, Fukui, Japan, 2018. 03
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エラストマーと無機材複合化による柔軟・剛直二層コアシェル粒子の開発とその力学特性2017

    • Author(s)
      Kang Yangwon,城崎智洋,堀川真希,龍直哉,高藤誠,永岡昭二,伊原博隆
    • Organizer
      第54回化学関連支部合同九州大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Preparation of cellulose microbeads having “card house structure” constituted of h-boron nitride crystal and their high thermal conductivity2017

    • Author(s)
      Shoji Nagaoka, Takuma Jodai, Maki Horikawa, Tomohiro Shirosaki, Naoya Ryu, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      The 4th International Cellulose Conference ICC 2017, Fukuoka, Japan, 2017. 10
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Facial control for polybutadiene/inorganic materials particles composite microsphere based on ene-thiol reaction2016

    • Author(s)
      Shoji Nagaoka, Yangwon Kang, Tomohiro Shirosaki, Maki Horikawa, Naoya Ryu, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      The 11th SPSJ International Polymer Conference (IPC2016)
    • Place of Presentation
      Fukuoka, Japan
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of polybutadiene/inorganic particles core-shell microspheres and their characterization2016

    • Author(s)
      Yangwon Kang, Shoji Nagaoka, Tomohiro Shirosaki, Maki Horikawa, Naoya Ryu, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      The 11th International Student Conference on Advanced Science and Technology (ICAST 2016)
    • Place of Presentation
      Kumamoto, Japan
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 懸濁蒸発法によるエラストマー球状粒子の調製と無機微粒子複合化2016

    • Author(s)
      永岡昭二、Kang Yangwon、城崎智洋、堀川真希、龍直哉、高藤誠、伊原博隆
    • Organizer
      第19回高分子ミクロスフェア討論会
    • Place of Presentation
      千葉市
    • Year and Date
      2016-11-07
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 複合粒子およびその製造方法2015

    • Inventor(s)
      永岡昭二、三好明子、堀川真希、城崎智洋、龍直哉、高藤誠、伊原博隆
    • Industrial Property Rights Holder
      熊本県、熊本大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-04-28
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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