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Stability of complex alloy compounds - approach from TEM -

Research Project

Project/Area Number 15H04141
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

KONNO TOYOHIKO  東北大学, 金属材料研究所, 教授 (90260447)

Co-Investigator(Kenkyū-buntansha) 嶋田 雄介  東北大学, 金属材料研究所, 助教 (20756572)
長迫 実  東北大学, 金属材料研究所, 助手 (30436167)
木口 賢紀  東北大学, 金属材料研究所, 准教授 (70311660)
佐藤 和久  大阪大学, 超高圧電子顕微鏡センター, 准教授 (70314424)
Research Collaborator HAMAOKA Takumi  
AKAMA Akihiro  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥14,820,000 (Direct Cost: ¥11,400,000、Indirect Cost: ¥3,420,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywords合金材料 / 相安定性 / 透過電子顕微鏡 / 金属材料 / 透過型電子顕微鏡 / 社会基盤構造材料 / 相安定化機構 / 振動エントロピー / 合金の相安定性 / 散漫散乱 / 第一原理計算 / ヒュームロザリー相 / 合金の相安定化
Outline of Final Research Achievements

Non-stoichiometry in metals and alloys play a key role in the stabilization of complex phases. In this study, we applied transmission electron microscopy to elucidate several key factors that bring about the stability of the crystal structures. Sysmtems investigated include the G-phase in ferrite-based stainless steel, where the role of the third element and emergence of five-fold sysmetry have extensively investigated, a long-range stacking order in magnesium-based alloy systems, and nano-size metal particles, where core-shell structure and the surface effects are non-negligible.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (21 results)

All 2018 2017 2016 2015

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Open Access: 3 results,  Acknowledgement Compliant: 5 results) Presentation (11 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Surface-segregation-induced phase separation in epitaxial Au/Co nanoparticles: Formation and stability of core-shell structures2017

    • Author(s)
      Sato Kazuhisa, Matsushima Yuta, Konno Toyohiko J.
    • Journal Title

      AIP Adv.

      Volume: 7 Issue: 6 Pages: 065309-065309

    • DOI

      10.1063/1.4986905

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Composition dependence of open-volume relaxation in Zr-Cu-Al bulk amorphous alloys studied by positron annihilation2017

    • Author(s)
      Hori F,. Ishii A., Ishiyama T., Iwase A., Yokoyama Y., Konno T. J.
    • Journal Title

      J. Alloy. Compd.

      Volume: 707 Pages: 73-77

    • DOI

      10.1016/j.jallcom.2016.12.416

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of molybdenum on precipitation behaviours in aged cast stainless steels2016

    • Author(s)
      Hamaoka, Takumi Konno, Toyohiko J. Sawabe, Takashi Nishida, Kenji Dohi, Kenji
    • Journal Title

      Philos. Mag.

      Volume: 96 Issue: 24 Pages: 2518-2536

    • DOI

      10.1080/14786435.2016.1205231

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic-resolution analysis for the effects of heat treatment temperatures on the growth of chemically-ordered regions in Pb(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub> thin films2016

    • Author(s)
      C. Fan, T. Kiguchi, A. Akama, and T.J. Konno
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 6 Pages: 697-701

    • DOI

      10.2109/jcersj2.16036

    • NAID

      130005155640

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 時効硬化したダイカスト用アルミニウム合金の析出相の透過電子顕微鏡観察2016

    • Author(s)
      今野豊彦、佐々木翔平、濱岡巧
    • Journal Title

      軽金属

      Volume: 66 Pages: 291-297

    • NAID

      130005253779

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid state epitaxy of (Hf,Zr)O<sub>2</sub> thin films with orthorhombic phase2016

    • Author(s)
      Kiguchi, Takanori Nakamura, Shogo Akama, Akihiro Shiraishi, Takahisa Konno, Toyohiko J.
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 6 Pages: 689-693

    • DOI

      10.2109/jcersj2.16073

    • NAID

      130005155642

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Focal Depth of HAADF-STEM Imaging on the Solute Enriched Layers in Mg Alloys2015

    • Author(s)
      T. Kiguchi, Y. Yohei, S. Tashiro, K. Sato, and T.J. Konno
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 56 Issue: 10 Pages: 1633-1638

    • DOI

      10.2320/matertrans.MAW201505

    • NAID

      130005099178

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Local Strain Fields of LPSO in Mg-Based Ternary Alloys2015

    • Author(s)
      S. Matsunaga, T. Kiguchi, K. Sato, and T.J. Konno
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 56 Issue: 7 Pages: 923-927

    • DOI

      10.2320/matertrans.MH201404

    • NAID

      130005083546

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Three-Dimensional Imaging of Dislocations in a Ti-35 mass%Nb Alloy by Electron Tomography2015

    • Author(s)
      K. Sato, S. Semboshi, T. J. Konno
    • Journal Title

      Materials

      Volume: 8 Issue: 4 Pages: 1924-1933

    • DOI

      10.3390/ma8041924

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Three-Dimensional Shapes and Distributions of Long-Period Stacking Ordered Structures in Mg<sub>97</sub>Zn<sub>1</sub>Gd<sub>2</sub> Cast Alloys Characterized by Electron Tomography2015

    • Author(s)
      K. Sato, S. Matsunaga, S. Tashiro, Y. Yohei, T. Kiguchi, and T.J. Konno
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 56 Issue: 7 Pages: 928-932

    • DOI

      10.2320/matertrans.MH201406

    • NAID

      130005083565

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] MA-HIP法により作製したODS-Cu合金の微細組織観察2018

    • Author(s)
      一川誠、嶋田雄介、菱沼良光、池田賢一、能登裕之、室賀健夫、竹口雅樹、今野豊彦
    • Organizer
      第162回日本金属学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Precipitation Mechanism of Mg-Zn-Gd alloys2016

    • Author(s)
      T. Kiguchi, K. Sato, T.J. Konno
    • Organizer
      The 3rd International Symposium on Long-Period Stacking Ordered Structure and Its Related Materials (LPSO2016)
    • Place of Presentation
      京都市
    • Year and Date
      2016-12-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mg-Zn-Gd合金における析出挙動に及ぼす溶質濃度の影響2016

    • Author(s)
      木口賢紀, 山口陽平, 田代 峻也, 佐藤 和久, 今野 豊彦
    • Organizer
      日本金属学会春季(第158回)大会
    • Place of Presentation
      東京理科大学 葛飾キャンパス
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 多結晶超伝導材料の臨界電流特性と結晶粒構造2016

    • Author(s)
      嶋田雄介
    • Organizer
      第72回日本顕微鏡学会
    • Place of Presentation
      仙台市
    • Related Report
      2016 Annual Research Report
  • [Presentation] Influence of synthesis condition on grain structure of Ba(Fe,Co)2As2 polycrystalline bulks2016

    • Author(s)
      嶋田雄介
    • Organizer
      PRICM-9
    • Place of Presentation
      京都市
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mg-Zn-Gd系合金の析出挙動に及ぼす母相溶質濃度の影響のHAADF-STEM観察2016

    • Author(s)
      木口 賢紀, 佐藤 和久, 今野 豊彦
    • Organizer
      第72回日本顕微鏡学会
    • Place of Presentation
      仙台市
    • Related Report
      2016 Annual Research Report
  • [Presentation] Mg-Zn-Gd 合金における析出構造の成長機構2016

    • Author(s)
      木口 賢紀, 佐藤 和久, 今野 豊彦
    • Organizer
      日本金属学会2016 年秋期講演(第159 回)大会
    • Place of Presentation
      豊中市
    • Related Report
      2016 Annual Research Report
  • [Presentation] Mg97Zn1Gd2合金におけるLPSO形成初期過程の電子線トモグラフィーによる観察2015

    • Author(s)
      田代 峻也, 山口 陽平, 佐藤 和久, 木口 賢紀, 今野 豊彦
    • Organizer
      日本金属学会 第157回秋期講演大会
    • Place of Presentation
      九州大学 伊都キャンパス
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mg-Zn-Gd 3元系合金におけるGPゾーンの構造2015

    • Author(s)
      田代 峻也, 山口 陽平, 木口 賢紀, 佐藤 和久, 今野 豊彦
    • Organizer
      日本金属学会 第157回秋期講演大会
    • Place of Presentation
      九州大学 伊都キャンパス
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] Mg-Zn-Gd合金におけるGPゾーン形成過程のSTEM観察2015

    • Author(s)
      木口 賢紀、山口陽平、田代峻也、佐藤和久、今野豊彦
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] アルミニウムダイカスト合金ADC12の時効析出相2015

    • Author(s)
      今野 豊彦、佐々木翔平、濱岡巧
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都国際会館
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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