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Influence of charge states on structure and property of ferroelectric interfaces

Research Project

Project/Area Number 15H04145
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionNagoya University

Principal Investigator

NAKAMURA ATSUTOMO  名古屋大学, 工学研究科, 准教授 (20419675)

Co-Investigator(Kenkyū-buntansha) 栃木 栄太  東京大学, 大学院工学系研究科(工学部), 助教 (50709483)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2016: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2015: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Keywordsドメインウォール / 強誘電体 / 双結晶 / ひずみ / 電気伝導 / 表面・界面物性 / 格子欠陥 / 極性界面 / 電気伝導特性 / 電子顕微鏡
Outline of Final Research Achievements

Physical and chemical properties of crystalline materials are dependent on atomic structure of interfaces between neighboring crystals. This is true for charged interfaces such as ferroelectric domain-walls or boundaries. Accordingly, it is essential to investigate relationship between atomic structures of the interfaces and their properties. However, only a little is known about the relationship because it is difficult to perform systematic study on the charged interfaces. In this study, we artificially fabricated charged interfaces using the bicrystal method, analyzed their structure by transmission electron microscopy and evaluated the electric properties by scanning probe microscopy. It was found that the electrical conductivity at charged interfaces depends on their structures and charge states. Dislocations at the interfaces do not affect their property so much if the density is low. In contrast, polarization states at interfaces strongly influence the electrical conductivity.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (42 results)

All 2018 2017 2016 2015 Other

All Journal Article (20 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 20 results,  Acknowledgement Compliant: 9 results,  Open Access: 3 results) Presentation (21 results) (of which Int'l Joint Research: 15 results,  Invited: 8 results) Remarks (1 results)

  • [Journal Article] Structure of the Basal Edge Dislocation in ZnO2018

    • Author(s)
      Nakamura Atsutomo、Tochigi Eita、Nagahara Ryota、Furushima Yuho、Oshima Yu、Ikuhara Yuichi、Yokoi Tatsuya、Matsunaga Katsuyuki
    • Journal Title

      Crystals

      Volume: 8 Issue: 3 Pages: 127-127

    • DOI

      10.3390/cryst8030127

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dislocation Structures in Low-Angle Grain Boundaries of α-Al2O32018

    • Author(s)
      Tochigi Eita、Nakamura Atsutomo、Shibata Naoya、Ikuhara Yuichi
    • Journal Title

      Crystals

      Volume: 8 Issue: 3 Pages: 133-133

    • DOI

      10.3390/cryst8030133

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct Observation of Impurity Segregation at Dislocation Cores in an Ionic Crystal2017

    • Author(s)
      Eita Tochigi, Yuki Kezuka, Akiho Nakamura, Atsutomo Nakamura, Naoya Shibata, Yuichi Ikuhara
    • Journal Title

      Nano Letters

      Volume: 17 Issue: 5 Pages: 2908-2912

    • DOI

      10.1021/acs.nanolett.7b00115

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Another origin of yield drop behavior in sapphire deformed via basal slip: Recombination of climb-dissociated partial dislocations2017

    • Author(s)
      A. Nakamura, K. Matsunaga, E. Tochigi, N. Shibata, Y. Ikuhara, K.P.D. Lagerlof
    • Journal Title

      Scripta Materialia

      Volume: 138 Pages: 109-113

    • DOI

      10.1016/j.scriptamat.2017.06.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nonstoichiometric [012] dislocation in strontium titanate2017

    • Author(s)
      Y. Furushima, Y. Arakawa, A. Nakamura, E. Tochigi, K. Matsunaga
    • Journal Title

      Acta Materialia

      Volume: 135 Pages: 103-111

    • DOI

      10.1016/j.actamat.2017.06.017

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Room-Temperature Plastic Deformation of Strontium Titanate Crystals Grown from Different Chemical Compositions2017

    • Author(s)
      Nakamura Atsutomo、Yasufuku Kensuke、Furushima Yuho、Toyoura Kazuaki、Lagerlof K.P.D.、Matsunaga Katsuyuki
    • Journal Title

      Crystals

      Volume: 7 Issue: 11 Pages: 351-351

    • DOI

      10.3390/cryst7110351

    • NAID

      120006501328

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] <10-10> dislocation at a {2-1-10} low-angle grain boundary in LiNbO32017

    • Author(s)
      Furushima Yuho、Nakamura Atsutomo、Tochigi Eita、Ikuhara Yuichi、Toyoura Kazuaki、Matsunaga Katsuyuki
    • Journal Title

      Journal of Materials Science

      Volume: 53 Issue: 1 Pages: 333-344

    • DOI

      10.1007/s10853-017-1532-5

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] First-principles calculations on slip system activation in the rock salt structure: Electronic origin of ductility in silver chloride2017

    • Author(s)
      A. Nakamura, M. Ukita, N. Shimoda, Y. Furushima, K. Toyoura, K. Matsunaga
    • Journal Title

      Philosophical Magazine

      Volume: 97 Issue: 16 Pages: 1281-1310

    • DOI

      10.1080/14786435.2017.1294270

    • NAID

      120006331821

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A First-Principles Study on Proton Conductivity of Acceptor-Doped Tin Pyrophosphate2017

    • Author(s)
      K. Toyoura, J. Terasaka, A. Nakamura, K. Matsunaga
    • Journal Title

      Physical Chemistry C

      Volume: 121 Issue: 3 Pages: 1578-1584

    • DOI

      10.1021/acs.jpcc.6b12532

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative oxide-ion conduction in apatite-type lanthanum germanate&mdash;A first principles study2017

    • Author(s)
      K. Imaizumi, K. Toyoura, A. Nakamura, K. Matsunaga
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 3 Pages: 105-111

    • DOI

      10.2109/jcersj2.16260

    • NAID

      130005401700

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dislocation structures and electrical conduction properties of low angle tilt grain boundaries in LiNbO32016

    • Author(s)
      Yuho Furushima, Atsutomo Nakamura, Eita Tochigi, Yuichi Ikuhara, Toyoura Kazuaki, Matsunaga Katsuyuki
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 14 Pages: 142107-142107

    • DOI

      10.1063/1.4961706

    • NAID

      120006331828

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pressure-induced phase transition of calcite and aragonite: A first principles study2016

    • Author(s)
      M. Ukita, K. Toyoura, A. Nakamura, K. Matsunaga
    • Journal Title

      Journal of Applied Physics

      Volume: 120 Issue: 14 Pages: 142118-142118

    • DOI

      10.1063/1.4961723

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic Structure Characterization of Stacking Faults on the {1-100} plane in α-Alumina by Scanning Transmission Electron Microscopy2016

    • Author(s)
      Eita Tochigi, Scott D. Findlray, Eiji Okunishi, Teruyasu Mizoguchi, Atsutomo Nakamura, Naoya Shibata, Yuichi Ikuhara
    • Journal Title

      AIP Conference Proceedings

      Volume: 1763 Pages: 50003-50003

    • DOI

      10.1063/1.4961356

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Adsorption sites of single noble metal atoms on the rutile TiO2 (110) surface influenced by different surface oxygen vacancies2016

    • Author(s)
      K. Matsunaga, T.-Y. Chang, R. Ishikawa, Q. Dong, K. Toyoura, A. Nakamura, Y. Ikuhara and N. Shibata
    • Journal Title

      J. Phys.: Condens. Matter.

      Volume: 28 Issue: 17 Pages: 175002-175002

    • DOI

      10.1088/0953-8984/28/17/175002

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Room-temperature deformation behavior of SrTiO3 single crystals with different chemical compositions2016

    • Author(s)
      A. Nakamura, K. Yasufuku, Y. Furushima, K. Toyoura, K. Matsunaga
    • Journal Title

      AMTC Letters

      Volume: 5 Pages: 184-185

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dislocation structures at (0001)/<112-0> low-angle tilt grain boundaries in lithium niobate2016

    • Author(s)
      Y. Furushima, A. Nakamura, E. Tochigi, Y. Ikuhara, K. Toyoura, K. Matsunaga
    • Journal Title

      AMTC Letters

      Volume: 5 Pages: 40-41

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dissociation of the 1/3<-1101> Dislocation and Formation of the Anion Stacking Fault on the Basal Plane in α-Al2O32015

    • Author(s)
      Eita Tochigi, Atsutomo Nakamura, Teruyasu Mizoguchi, Naoya Shibata, Yuichi Ikuhara
    • Journal Title

      Acta Materialia

      Volume: 91 Pages: 152-161

    • DOI

      10.1016/j.actamat.2015.02.033

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] First-principles calculations of divalent substitution of Ca2+ in tricalcium phosphates2015

    • Author(s)
      K. Matsunaga, T. Kubota, K. Toyoura, A. Nakamura
    • Journal Title

      Acta Biomaterialia

      Volume: 23 Pages: 329-337

    • DOI

      10.1016/j.actbio.2015.05.014

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydroxide-ion incorporation and conduction mechanisms in tin pyrophosphate &#8211; a firstprinciples study2015

    • Author(s)
      Junya Terasaka, Kazuaki Toyoura, Atsutomo Nakamura, Katsuyuki Matsunaga
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 3 Issue: 22 Pages: 11905-11911

    • DOI

      10.1039/c5ta01676b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] First-principles study on phase transition and ferroelectricity in pseudo-Ilmenite lithium niobate and tantalate2015

    • Author(s)
      K. Toyoura, M. Ohta, A. Nakamura, K. Matsunaga
    • Journal Title

      Journal of Applied Physics

      Volume: 118 Issue: 6 Pages: 064103-064103

    • DOI

      10.1063/1.4928461

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Structure and electrical conduction property of dislocations in oxides2018

    • Author(s)
      Nakamura Atsutomo
    • Organizer
      6th ESISM International Workshop
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 機械・電気・光のマルチフィジックス 欠陥制御の新展開2018

    • Author(s)
      中村篤智
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Dopant segregation at (110) low-angle tilt grain boundaries in magnesium oxide2017

    • Author(s)
      A. Nakamura,K. Sawada, E. Tochigi, Y. Ikuhara, T. Yokoi, K. Matsunaga
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atomic structure of (001) low-angle tilt grain boundary with a slight twist component in strontium titanate2017

    • Author(s)
      Y.Furushima,Y. Arakawa, A. Nakamura, E. Tochigi, K. Matsunaga
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] LiNbO3における極性ドメインウォールの局所電気伝導とその応力依存性2016

    • Author(s)
      古嶋佑帆, 中村篤智, 栃木栄太, 佐藤幸生, 柴田直哉, 溝口照康, 幾原雄一, 豊浦和明, 松永克志
    • Organizer
      日本金属学会 2016年秋期(第159回)講演大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Room Temperature Deformation Behavior of SrTiO3 Single Crystals2016

    • Author(s)
      A. Nakamura, K. Yasufuku, Y. Furushima, K. Toyoura, K. Matsunaga
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structures and properties of low angle grain boundaries in lithium niobate2016

    • Author(s)
      A. Nakamura
    • Organizer
      European Confarence on Fracture (ECF21)
    • Place of Presentation
      Catania, Italy
    • Year and Date
      2016-06-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electric conductivity along lattice defects in lithium niobate2016

    • Author(s)
      A. Nakamura, Y. Furushima, E. Tochigi, Y. Ikuhara, K. Toyoura, K. Matsunaga
    • Organizer
      THERMEC 2016
    • Place of Presentation
      Graz, Austria
    • Year and Date
      2016-05-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Artificial fabrication and electrical conduction of charged domain-walls in ferroelectric materials2016

    • Author(s)
      A. Nakamura
    • Organizer
      The Energy, Materials, and Nanotechnology (EMN) Meeting on Ceramics 2016
    • Place of Presentation
      Kowloon, Hong Kong
    • Year and Date
      2016-01-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] LiNbO3のドメインウォールにおける電気伝導性の制御2015

    • Author(s)
      小林宗睦, 中村篤智,栃木栄太,柴田直哉,幾原雄一,豊浦和明,松永克志
    • Organizer
      日本機械学会 M&M2015材料力学カンファレンス
    • Place of Presentation
      慶應義塾大学 矢上キャンパス
    • Year and Date
      2015-11-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrical Conductivity at Artificial Charged Domain-Walls in LiNbO32015

    • Author(s)
      A. Nakamura
    • Organizer
      2nd International Symposium on Frontiers in Materials Science (FMS2015)
    • Place of Presentation
      Waseda University, Japan
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Correlation between Ionic Conduction and Crystal Structures in Proton-Conducting Oxides -A First-Principles Study2015

    • Author(s)
      K. Toyoura, A. Nakamura, K. Matsunaga
    • Organizer
      2nd International Symposium on Frontiers in Materials Science (FMS2015)
    • Place of Presentation
      Waseda University, Japan
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Atomic Structure and Electric Property of (0001)/<11-20>Low-Angle Tilt Grain Boundary in LiNbO32015

    • Author(s)
      Y. Furushima, A. Nakamura, E. Tochigi, Y. Ikuhara, K. Toyoura, K. Matsunaga
    • Organizer
      2nd International Symposium on Frontiers in Materials Science (FMS2015)
    • Place of Presentation
      Waseda University, Japan
    • Year and Date
      2015-11-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] セラミック結晶における転位の構造と機能2015

    • Author(s)
      中村篤智
    • Organizer
      第3回グリーンエネルギー材料のマルチスケール創製研究会
    • Place of Presentation
      沖縄,ユインチホテル南城
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Atomic structure and electric property of low-angle tilt grain boundaries in LiNbO32015

    • Author(s)
      Y. Furushima, A. Nakamura, E. Tochigi, Y. Ikuhara,K. Toyoura, K. Matsunaga
    • Organizer
      14th International Union of Materials Research Societies-International Conference on Advanced Materials (UMRS-ICAM 2015)
    • Place of Presentation
      Jeju Island, Korea
    • Year and Date
      2015-10-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Artificial Fabrication and Electrical Conduction Property of Charged Domain-walls in Ferroelectric Oxide2015

    • Author(s)
      A. Nakamura, Y. Sato, E. Tochigi, T. Mizoguchi, N. Shibata, Y. Ikuhara, K. Toyoura, K. Matsunaga
    • Organizer
      Materials Science & Technology 2015 (MS&T15)
    • Place of Presentation
      Columbus, USA
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化物双結晶を用いた転位の構造解析と物性評価2015

    • Author(s)
      中村篤智
    • Organizer
      日本金属学会 2015年秋期(第157回)講演大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 強誘電体中の小角粒界における転位構造と物性2015

    • Author(s)
      中村篤智, 古嶋佑帆,栃木栄太,幾原雄一, 豊浦和明, 松永克志
    • Organizer
      日本機械学会 2015年度年次大会
    • Place of Presentation
      北海道大学 工学部
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Yield drop phenomena in alumina single crystals deformed for basal slip2015

    • Author(s)
      A. Nakamura, E. Tochigi, N. Shibata, K. Toyoura, K. Matsunaga, P. Lagerlof, Y. Ikuhara
    • Organizer
      17th International Conference on the Strength of Materials (ICSMA-17)
    • Place of Presentation
      Brno, Czech Republic
    • Year and Date
      2015-08-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bicrystal study on atomic structures and electric properties of low - angle tilt grain boundaries in lithium niobate2015

    • Author(s)
      Y. Furushima, A. Nakamura, K. Toyoura, K. Matsunaga
    • Organizer
      17th International Conference on the Strength of Materials (ICSMA-17)
    • Place of Presentation
      Brno, Czech Republic
    • Year and Date
      2015-08-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Theoretical investigations on atomic-scale conduction mechanism of interstitial oxygen ions in apatite-type fast ionic conductors2015

    • Author(s)
      K. Matsunaga, K. Imaizumi, S. Ishimoto, K. Toyoura, A. Nakamura
    • Organizer
      11th International Conference on Ceramic Materials and Components for Energy and Environmental Applications
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2015-06-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 名古屋大学大学院工学研究科物質科学専攻 材料設計工学研究グループ

    • URL

      http://www.numse.nagoya-u.ac.jp/matsunaga/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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