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Development of composite nanoparticles for negative electrode of next generation lithium ion batteries

Research Project

Project/Area Number 15H04152
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionThe University of Tokyo

Principal Investigator

Kambara Makoto  東京大学, 大学院工学系研究科(工学部), 准教授 (80359661)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2017: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywordsリチウムイオン電池 / ナノ粒子 / プラズマスプレー / プラズマプロセス / シリコンナノ粒子 / 材料加工・処理 / ナノ材料 / プラズマ加工 / シリコン
Outline of Final Research Achievements

This project aims at the simultaneous attainment of increased capacity and enhanced cyclability of lithium-ion batteries by using the best of the characteristic composite nanoparticles designed by plasma spray PVD. As the major achievements, we have demonstrated significantly high capacity maintained after longer cycles with the active-material-network in the anode by using the best of the characteristic structure of Si:Sn nanoparticle produced by PS-PVD. The higher cycle capacities with SiO nanoparticles is also attained by the effective reduction during PS-PVD of SiO, along with the new finding that the disproportionation reaction can be accelerated in nanosized SiO. Furthermore, we have also achieved Si nanoparticle production as high as 1 kg/hr. The effect of throughput on the co-condensation process in PS-PVD is clarified and the optimal conditions to produce the optimal composite particles at greater throughputs are proposed.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (36 results)

All 2018 2017 2016 2015

All Journal Article (6 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (28 results) (of which Int'l Joint Research: 10 results,  Invited: 17 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Effect of PS-PVD production throughput on Si nanoparticles for negative electrode of lithium ion batteries2018

    • Author(s)
      R. Ohta, K. Fukada, T. Tashiro, M. Dougakiuchi, M. Kambara
    • Journal Title

      J. Phys. D: Appl. Phys.

      Volume: 51 Issue: 10 Pages: 105501-105501

    • DOI

      10.1088/1361-6463/aaab37

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Cycle Capacity of Lithium Ion Batteries with Nanocomposite Si Anodes Produced By Rapid Co-Condensation in Plasma Spray PVD2017

    • Author(s)
      K. Fukada, R. Ohta, M. Kambara
    • Journal Title

      ECS Trans.

      Volume: 77 Issue: 3 Pages: 41-47

    • DOI

      10.1149/07703.0041ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Instantaneous formation of SiOx nanocomposite for high capacity lithium ion batteries by enhanced disproportionation reaction during plasma spray physical vapor deposition2016

    • Author(s)
      T. Tashiro, M. Dogakiuchi, M. Kambara
    • Journal Title

      Sci. Technol. Adv. Mater.

      Volume: 17 Issue: 1 Pages: 744-752

    • DOI

      10.1080/14686996.2016.1240574

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] シリコンのナノクラスター支援メゾプラズマ高速エピタキシ-2016

    • Author(s)
      神原淳
    • Journal Title

      日本学術振興会第131委員会 第279回研究会紀要

      Volume: 279 Pages: 1-6

    • Related Report
      2016 Annual Research Report
  • [Journal Article] プラズマスプレーPVDによる次世代高密度リチウム2次電池向けSi系ナノ複合負極開発2016

    • Author(s)
      神原淳
    • Journal Title

      日本学術振興会第153委員会 第129回研究会紀要

      Volume: 129 Pages: 1-6

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Plasma Spray PVD: High throughput production of nanoparticles2016

    • Author(s)
      M. Kambara, T. Hideshima, M. Kaga, T. Yoshida
    • Journal Title

      Encyclopedia Plasma Process

      Volume: 印刷中

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 高スループットPS-PVDによるSiナノ粒子の構造変調とLiイオン電池特性2018

    • Author(s)
      太田遼至,道垣内将司,神原淳
    • Organizer
      第65回 応用物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] PS-PVDナノSi:Sn粒子を用いた負極複合化によるLiB特性向上2018

    • Author(s)
      東原智秋,太田遼至,道垣内将司,神原淳
    • Organizer
      第65回 応用物理学会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 熱プラズマスプレーPVDによるLiイオン電池負極向けSi系ナノ複合粒子開発2017

    • Author(s)
      神原淳,田代亘
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学,大阪
    • Year and Date
      2017-03-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] Enhancement in capacity of lithium ion batteries with composite Si:Sn nanoparticulate anode produced through co-condensation in PS-PVD2017

    • Author(s)
      Makoto Kambara, Tomoaki Tohara, Ryoshi Ohta
    • Organizer
      MRS-J
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] メゾプラズマナノクラスターを利用したエピタキシャルブリッジング2017

    • Author(s)
      神原淳
    • Organizer
      Plasma conference 2018
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Enhanced cyclability with plasma sprayed Si-M nanocomposite anodes for lithium ion batteries2017

    • Author(s)
      M. Kambara, T. Tohara, R. Ohta
    • Organizer
      AEPSE2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新たな材料プロセッシングに向けた熱プラズマスプレーの挑戦2017

    • Author(s)
      神原淳
    • Organizer
      日本学術振興会 第153委員会 30周年記念講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Enhanced cycle capacity of lithium ion batteries with nanocomposite Si anodes produced by rapid co-condensation in plasma spray PVD2017

    • Author(s)
      M. Kambara, K. Fukada, R. Ohta, T. Tohara, N. Gerile
    • Organizer
      ECS2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanocomposite Si particle production by plasma spray PVD for next generation high energy density lithium ion batteries2017

    • Author(s)
      M. Kambara
    • Organizer
      The 22nd Korea-Japan Workshop
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanocluster assited mesoplasma epitaxial bridging2017

    • Author(s)
      M. Kambara, R. Yamada, S. Wu
    • Organizer
      ICMCTF2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enhanced cycle capacity of lithium ion batteries with Ni-epitaxially-attached Si nanoparticles as anode produced by plasma spray physical vapor deposition2016

    • Author(s)
      M. Kambara
    • Organizer
      26th MRS-J
    • Place of Presentation
      Yokohama Port Opening Plaza, Kanagawa
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Production of SiO nanoparticles with reduced oxygen content by pulse-modulated plasma spray PVD for an increase in capacity of LiBS2016

    • Author(s)
      S. Hamazaki, N. Kodama, K. Kita, Y Ishisaka, Y. Tanaka,M. Kambara
    • Organizer
      26th MRS-J
    • Place of Presentation
      Yokohama Port Opening Plaza, Kanagawa
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] Plasma spray PVD for nanocparticulate Si composite anodes of high density lithium ion batteries2016

    • Author(s)
      M. Kambara
    • Organizer
      NTI-UTokyo Joint Conference
    • Place of Presentation
      National Taiwan University, Taipei, Taiwan
    • Year and Date
      2016-11-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Lateral epitaxial overgrowth of silicon thick films during nanocluster assisted mesoplasma CVD2016

    • Author(s)
      M. Kambara, T. Koyano, Y. Imamura, T. Yoshida
    • Organizer
      69th Annual Gaseous Electronics
    • Place of Presentation
      Ruhr University Bochum, Bochum, Germany
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プラズマスプレーPVDによるLiイオン二次電池用Si-Ni複合ナノ負極の特性向上2016

    • Author(s)
      深田航平,太田遼至,神原淳
    • Organizer
      第77回応用物理学会秋期学術講演会
    • Place of Presentation
      朱鷺メッセ,新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Nanocomposite Si-M particles produced by plasma spray PVD for high-density lithium ion batteries2016

    • Author(s)
      M. Kambara, Naren Gerile, M. Kaga
    • Organizer
      ICMCTF 2016
    • Place of Presentation
      San Diego, USA
    • Year and Date
      2016-04-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プラズマスプレーPVDによるリチウム2次電池負極向けSi系ナノ粒子の高速複合化2016

    • Author(s)
      神原淳
    • Organizer
      第158回日本金属学会
    • Place of Presentation
      東京理科大学,東京都葛飾区
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] プラズマスプレーPVDによるLiイオン二次電池用Si-Ni複合ナノ負極の特性向上2016

    • Author(s)
      深田航平,太田遼至,神原淳
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学,東京都目黒区
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] プラズマスプレーPVDによるリチウム2次電池負極用Si系ナノ複合粒子開発2016

    • Author(s)
      神原淳
    • Organizer
      神奈川大オープンラボ第17回講演会
    • Place of Presentation
      神奈川大学,神奈川県横浜市
    • Year and Date
      2016-01-21
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] シリコンのメゾプラズマ超高速エピタキシー2016

    • Author(s)
      神原淳
    • Organizer
      日本学術振興会 薄膜第131委員会・第279回研究会
    • Place of Presentation
      東京都立産業技術研究センター,東京
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] プラズマスプレー技術による高速・高品質ナノ粒子製造2016

    • Author(s)
      神原淳
    • Organizer
      ナノ粒子製造システム研究会
    • Place of Presentation
      島根県産業技術センター,松江,島根
    • Related Report
      2016 Annual Research Report
  • [Presentation] ナノクラスター支援メゾプラズマ高速沿面エピタキシャルオーバー成長2016

    • Author(s)
      神原淳
    • Organizer
      第74回マテリアルズテーラリング研究会
    • Place of Presentation
      加藤山崎教育基金 軽井沢研修所,長野
    • Related Report
      2016 Annual Research Report
  • [Presentation] プラズマスプレーPVDによる次世代高密度リチウム2次電池向けSi系ナノ複合負極開発2016

    • Author(s)
      神原淳
    • Organizer
      日本学術振興会 プラズマ材料科学第153委員会・第129回研究会
    • Place of Presentation
      島根県産業技術センター,松江,島根
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Nanocomposite Si/SiOx particle formation through enhanced disproportionation reaction during plasma spray PVD2015

    • Author(s)
      T. Tashiro, M. Kambara
    • Organizer
      MRS-J
    • Place of Presentation
      横浜開港記念会館,神奈川県横浜市
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] プラズマスプレーPVDによるリチウムイオン電池向けSi系複合ナノ粒子の開発2015

    • Author(s)
      神原淳
    • Organizer
      技術情報協会セミナー
    • Place of Presentation
      東京日幸五反田ビル,東京都品川区
    • Year and Date
      2015-12-04
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] プラズマスプレーPVDによるリチウムイオン電池向けSi系複合ナノ粒子製造2015

    • Author(s)
      神原淳
    • Organizer
      次世代マイクロ化学チップ第33回研究会
    • Place of Presentation
      東京大学,東京都文京区
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Production of composite Si nano particles by plasma spray PVD and CH4 annealing for negative electrodes of lithium ion batteries2015

    • Author(s)
      R. Ohta, R. Yutaro, T. Tashiro, M. Kambara
    • Organizer
      68tjGEC/ICRP-9
    • Place of Presentation
      Hawaii Convention Center, Honolulu, USA
    • Year and Date
      2015-10-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プラズマスプレーPVDによるリチウムイオン電池用SiO系ナノ複合負極創製2015

    • Author(s)
      本間啓一郎,神原淳
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場,愛知県名古屋市
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Book] Encyclopedia of Plasma Technology: Powders: Plasma Spray PVD for High-Throughput Production2017

    • Author(s)
      M. Kambara, T. Hideshima, M. Kaga, T. Yoshida
    • Publisher
      Taylor and Francis
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] リチウムイオン二次電池用負極の製造方法、負極、及び負極活物質2017

    • Inventor(s)
      神原淳,東原智秋,太田遼至
    • Industrial Property Rights Holder
      神原淳,東原智秋,太田遼至
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-106031
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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