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Mechanism of hydrogen embrittlement in martensitic steels

Research Project

Project/Area Number 15H04158
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionKyoto University

Principal Investigator

Shibata Akinobu  京都大学, 工学研究科, 准教授 (60451994)

Research Collaborator MOMOTANI yuji  
YONEMURA takashi  
TAKEDA yasunari  
OKADA kazuho  
Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2015: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Keywords水素脆性 / マルテンサイト鋼 / 構造材料 / 材料組織
Outline of Final Research Achievements

The present project investigated hydrogen-related fracture behavior of martensitic steels by microstructure analysis, three-dimensional fracture surface topography analysis, and hydrogen micro-print technique. The main obtained results are (i) formation site of hydrogen-related cracks is around prior austenite grain boundary in martensite structure, (ii) fracture mechanism changes from plastic strain-controlled to stress-controlled with increasing hydrogen content, (iii) with the proceeding of fracture, the fracture mode changes from intergranular to quasi-cleavage, (iv) hydrogen tends to accumulate around prior austenite grain boundary by tensile deformation at a slow strain rate, (v) hydrogen transportation by dislocation motion is a main mechanism for hydrogen accumulation.

Academic Significance and Societal Importance of the Research Achievements

水素脆性破壊の素過程に関しては,古くから多くの研究がなされてきているが,その破壊メカニズムの解明には至っていないのが現状であった.本研究では,典型的な高強度鉄鋼材料であるマルテンサイト鋼を研究対象とし,マルテンサイト鋼における水素脆性破壊の「破壊起点」,「破壊伝播経路」,「破壊過程における水素集積挙動」を系統的に調べることによって,破壊メカニズムを明らかにした.本研究で得られた結果は水素脆性破壊の理解を大きく進めるものであるだけでなく,水素脆性を抑制するための材料組織制御法に繋がるため,耐水素脆性に優れた材料開発を通して,安全・安心な社会を構成するための社会基盤の構築に貢献しうるものである.

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (42 results)

All 2019 2018 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (12 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 5 results) Presentation (28 results) (of which Int'l Joint Research: 15 results,  Invited: 5 results)

  • [Int'l Joint Research] Mines ParisTech(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Mines ParisTech(France)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Crystallographic feature of hydrogen-related fracture in 2Mn-0.1C ferritic steel2018

    • Author(s)
      K. Okada, Y. Takeda, A. Shibata, N. Tsuji
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 43 Issue: 24 Pages: 11298-11306

    • DOI

      10.1016/j.ijhydene.2018.05.011

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between applied stress and hydrogen-related fracture behavior in martensitic steel2018

    • Author(s)
      Y. Takeda, T. Yonemura, Y. Momotani, A. Shibata, N. Tsuji
    • Journal Title

      Proceedings of the International Conference on Martensitic Transformation: Chicago, The Minerals, Metals & Materials Series

      Volume: - Pages: 227-231

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural and crystallographic features of hydrogen-related fracture in lath martensitic steels2017

    • Author(s)
      Akinobu Shibata, Yuji Momotani, Tamotsu Murata, Takahiro Matsuoka, Mizuki Tsuboi, Nobuhiro Tsuji
    • Journal Title

      Materials Science and Technology

      Volume: 印刷中 Issue: 13 Pages: 1524-1532

    • DOI

      10.1080/02670836.2017.1312210

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Role of Different Kinds of Boundaries against Cleavage Crack Propagation in Low Temperature Embrittlement of Low-Carbon Martensitic Steel2017

    • Author(s)
      Mizuki Tsuboi, Akinobu Shibata, Daisuke Terada, Nobuhiro Tsuji
    • Journal Title

      Metallurgical and Materials Transactions A

      Volume: 印刷中 Issue: 7 Pages: 3261-3268

    • DOI

      10.1007/s11661-017-4107-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrogen-Related Fracture Behavior Under Stress Concentration in Low Carbon Martensitic Steel2017

    • Author(s)
      T. Yonemura, Y. Momotani, A. Shibata, S. Takagi, and N. Tsuji
    • Journal Title

      Proceedings of the 2016 International Hydrogen Conference

      Volume: - Pages: 90-96

    • DOI

      10.1115/1.861387_ch8

    • ISBN
      9780791861387
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Deformation Temperature on Hydrogen Embrittlement in Low-Carbon Martensitic Steel2017

    • Author(s)
      Y. Momotani, A. Shibata, and N. Tsuji
    • Journal Title

      Proceedings of the 2016 International Hydrogen Conference

      Volume: - Pages: 97-104

    • DOI

      10.1115/1.861387_ch9

    • ISBN
      9780791861387
    • Related Report
      2017 Annual Research Report
  • [Journal Article] Fracture surface topography analysis of the hydrogen-related fracture propagation process in martensitic steel2017

    • Author(s)
      A. Shibata, T. Matsuoka, A. Ueno, N. Tsuji
    • Journal Title

      International Journal of Fracture

      Volume: 205 Issue: 1 Pages: 73-82

    • DOI

      10.1007/s10704-017-0182-6

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of strain rate on hydrogen embrittlement in low-carbon martensitic steel2017

    • Author(s)
      Y. Momotani, A. Shibata, D. Terada, N. Tsuji
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 42 Pages: 3371-3379

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Relationship between Bain unit size and low-temperature toughness in low-carbon bainitic steel2016

    • Author(s)
      M. Tsuboi, Y. Kobuchi, A. Shibata, N. Tsuji
    • Journal Title

      Proceedings of the 9th Pacific Rim International Conference on Advanced Materials and Processing

      Volume: - Pages: 237-238

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Deformation Condition on Hydrogen Embrittlement Behavior in Low-carbon Martensitic Steel2016

    • Author(s)
      Y. Momotani, A. Shibata, N. Tsuji
    • Journal Title

      Proceedings of the 9th Pacific Rim International Conference on Advanced Materials and Processing

      Volume: - Pages: 459-461

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of the stress concentration on the hydrogen embrittlement in Fe-0.2C martensitic steels2016

    • Author(s)
      T. Yonemura, Y. Momotani, A. Shibata, S. Takagi, N. Tsuji
    • Journal Title

      Proceedings of the 9th Pacific Rim International Conference on Advanced Materials and Processing

      Volume: - Pages: 589-591

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of hydrogen-related fracture behavior in as-quenched low carbon martensitic steel and tempered medium carbon martensitic steel2015

    • Author(s)
      A. Shibata, T. Murata, H. Takahashi, T. Matsuoka, N. Tsuji
    • Journal Title

      Metallurgical and Materials Transactions A

      Volume: 46A Issue: 12 Pages: 5685-5696

    • DOI

      10.1007/s11661-015-3176-x

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Mechanical and microstructural analysis on hydrogen-related fracture behavior of martensitic steels2019

    • Author(s)
      A. Shibata, K. Okada, Y. Madi, J. Besson, N. Tsuji
    • Organizer
      7th ESISM Workshops in Kyoto
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マルテンサイト鋼の水素脆性破壊と微視組織の関係2019

    • Author(s)
      柴田曉伸,桃谷裕二,米村天志,岡田和歩,白玉,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2Mn-0.1Cフェライト鋼の変形組織におよぼす水素の影響2019

    • Author(s)
      岡田和歩,柴田曉伸,Wu Gong,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] マルテンサイト鋼における水素脆性破壊の力学的・組織学的解析2019

    • Author(s)
      柴田曉伸,岡田和歩,Yazid Madi, Jacques Besson, 辻伸泰
    • Organizer
      日本金属学会春期講演大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Hydrogen-related fracture behavior in a ferritic steel2018

    • Author(s)
      K. Okada, A. Shibata, N. Tsuji
    • Organizer
      International Conference on Processing & Manufacturing of Advanced Materials (THERMEC 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mechanical and microstructural analysis on hydrogen-related fracture behavior of martensitic steels2018

    • Author(s)
      A. Shibata, K. Okada, Y. Madi, J. Besson, N. Tsuji
    • Organizer
      The 2nd International Symposium on Advanced Structural Materials; Design, Characterization and Processing
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effects of hydrogen on deformed microstructure in 2Mn-0.1C ferritic steel2018

    • Author(s)
      K. Okada, A. Shibata, W. Gong, N. Tsuji
    • Organizer
      6th International Conference on Advanced Steels
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 2Mn-0.1C鋼フェライト組織における水素脆性破壊の結晶学的特徴2018

    • Author(s)
      岡田和歩,柴田曉伸,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Hydrogen-related fracture behavior of martensitic steels2018

    • Author(s)
      A. Shibata, Y. Momotani, T. Yonemura, K. Okada, Y. Madi, J. Besson, N. Tsuji
    • Organizer
      Polycrystals: Microstructure and Effective Properties Workshop
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 低炭素マルテンサイト鋼における水素脆性破壊特性と水素集積挙動の関係2017

    • Author(s)
      桃谷裕二,柴田曉伸,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Place of Presentation
      首都大学東京 (東京都・八王子市)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 8Ni-0.1C 鋼マルテンサイトの水素脆性における破壊様式と負荷応力の関係2017

    • Author(s)
      竹田泰成,柴田曉伸,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Place of Presentation
      首都大学東京 (東京都・八王子市)
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Hydrogen-related fracture behavior of martensitic steel under different deformation conditions2017

    • Author(s)
      A. Shibata, Y. Momotani, T. Yonemura, N. Tsuji
    • Organizer
      5th ESISM International Workshop
    • Place of Presentation
      京都大学 (京都府・京都市)
    • Year and Date
      2017-01-31
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Relationship between applied stress amd hydrogen-related fracture behavior in martensitic steel2017

    • Author(s)
      Y. Takeda, T. Yonemura, Y. Momotani, A. Shibata, N. Tsuji
    • Organizer
      International Conference on Martensitic Transformations (ICOMAT) 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 8Ni-0.1C マルテンサイト鋼の水素脆性における破壊様式と負荷応力の関係2017

    • Author(s)
      竹田泰成,柴田曉伸,辻伸泰
    • Organizer
      日本鉄鋼協会秋季講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 低炭素マルテンサイト鋼の応力集中下における水素脆化破壊挙動2016

    • Author(s)
      米村天志,柴田曉伸,高木周作,辻伸泰
    • Organizer
      日本鉄鋼協会秋季講演大会
    • Place of Presentation
      大阪大学 (大阪府・豊中市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 極低炭素マルテンサイト鋼の水素集積挙動におよぼす転位密度の影響2016

    • Author(s)
      桃谷裕二,柴田曉伸,辻伸泰
    • Organizer
      日本鉄鋼協会秋季講演大会
    • Place of Presentation
      大阪大学 (大阪府・豊中市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Hydrogen-related fracture behavior under stress concentration in low carbon martensitic steel2016

    • Author(s)
      T. Yonemura, Y. Momotani, A. Shibata, N. Tsuji
    • Organizer
      International Hydrogen Conference
    • Place of Presentation
      Moran, USA
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of deformation temperature on hydrogen embrittlement in low-carbon martensitic steel2016

    • Author(s)
      Y. Momotani, A. Shibata, N. Tsuji
    • Organizer
      International Hydrogen Conference
    • Place of Presentation
      Moran, USA
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen-related fracture under deformation at various strain rates in low-carbon martensitic steel2016

    • Author(s)
      A. Shibata, Y. Momotani, T. Yonemura, N. Tsuji
    • Organizer
      International Hydrogen Conference
    • Place of Presentation
      Moran, USA
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Deformation Condition on Hydrogen Embrittlement Behavior in Low-Carbon Martensitic Steel2016

    • Author(s)
      Y. Momotani, A. Shibata, N. Tsuji
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing (PRICM9)
    • Place of Presentation
      国立京都国際会館 (京都府・京都市)
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Stress Concentration on Hydrogen Embrittlement in Low-Carbon Martensitic Steel2016

    • Author(s)
      T. Yonemura, Y. Momotani, A. Shibata, S. Takagi, N. Tsuji
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing (PRICM9)
    • Place of Presentation
      国立京都国際会館 (京都府・京都市)
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relationship between Bain Unit Size and Low-Temperature Toughness in Low-Carbon Bainitic Steel2016

    • Author(s)
      M. Tsuboi, A. Shibata, N. Tsuji
    • Organizer
      The 9th Pacific Rim International Conference on Advanced Materials and Processing (PRICM9)
    • Place of Presentation
      国立京都国際会館 (京都府・京都市)
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 低炭素マルテンサイト鋼における水素脆性クラックの伝播挙動2016

    • Author(s)
      柴田曉伸,桃谷裕二,米村天志,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低炭素マルテンサイト鋼の水素脆化における応力集中の影響2016

    • Author(s)
      米村天志,柴田曉伸,辻伸泰
    • Organizer
      日本鉄鋼協会春季講演大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hydrogen-related fracture behavior in martensitic steel analyzed by FRASTA method2015

    • Author(s)
      A. Shibata, T. Matsuoka, A. Ueno, N. Tsuji
    • Organizer
      European Congress and Exhibition on Advanced Materials and Processes 2015
    • Place of Presentation
      Warsaw
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen-related fracture behaviors at various strain rates in a low carbon martensitic steel2015

    • Author(s)
      Y. Momotani, A. Shibata, N. Tsuji
    • Organizer
      European Congress and Exhibition on Advanced Materials and Processes 2015
    • Place of Presentation
      Warsaw
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マルテンサイト鋼における水素脆性破壊の結晶学的解析2015

    • Author(s)
      柴田曉伸,村田 有,松岡雄大,桃谷裕二,辻 伸泰
    • Organizer
      日本鉄鋼協会秋季講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低炭素マルテンサイト鋼の水素脆性におよぼす変形温度の影響2015

    • Author(s)
      桃谷裕二,柴田曉伸,辻 伸泰
    • Organizer
      日本鉄鋼協会秋季講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2020-03-30  

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