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Study of structure modification of boron nitride films by plasma exposure - the effect of ion energy distribution function

Research Project

Project/Area Number 15H04159
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionKyoto University

Principal Investigator

Eriguchi Koji  京都大学, 工学研究科, 教授 (70419448)

Co-Investigator(Kenkyū-buntansha) 長谷川 繁彦  大阪大学, 産業科学研究所, 准教授 (50189528)
斧 高一  京都大学, 工学(系)研究科(研究院), 教授 (30311731)
Research Collaborator NOMA MASAO  神港精機株式会社, 主任
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2017: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywordsプラズマ / 結晶・組成制御 / ナノ材料 / 材料加工・処理
Outline of Final Research Achievements

Boron nitride films have attracted much attention recently due to the unique structures such as sp2- and sp3-bonded phases. In this study, the structure modification induced by plasma exposure was investigated in detail. It was found that the change in the indentation hardness strongly depends on the energy of incident ions from plasma. Molecular dynamics simulations predicted that the transition from sp3-bonded to sp2-bonded phases was observed in the surface region of the prepared structures. Moreover, the observed phase change was confirmed to be a function of the energy of incident ions. The present findings imply that the ion-energy control during plasma exposure was key to the structure optimization of BN films in future.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (17 results)

All 2017 2016 2015 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Remarks (3 results)

  • [Journal Article] Optical model for spectroscopic ellipsometry analysis of plasma-induced damage to SiOC films2017

    • Author(s)
      Kentaro Nishida, Kouichi Ono, and Koji Eriguchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 6S2 Pages: 06HD01-06HD01

    • DOI

      10.7567/jjap.56.06hd01

    • NAID

      210000147960

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Time-dependent dielectric breakdown characterizations of interlayer dielectric damage induced during plasma processing2017

    • Author(s)
      Kengo Shinohara, Kentaro Nishida, Kouichi Ono, and Koji Eriguchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 6S2 Pages: 06HD03-06HD03

    • DOI

      10.7567/jjap.56.06hd03

    • NAID

      210000147962

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modeling of defect generation during plasma etching and its impact on electronic device performance-plasma-induced damage2017

    • Author(s)
      Koji Eriguchi
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 50 Issue: 33 Pages: 333001-333001

    • DOI

      10.1088/1361-6463/aa7523

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defect generation in electronic devices under plasma exposure: Plasma-induced damage2017

    • Author(s)
      Koji Eriguchi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 6S2 Pages: 06HA01-06HA01

    • DOI

      10.7567/jjap.56.06ha01

    • NAID

      210000147946

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrical characterization of carrier trapping behavior of defects created by plasma exposures2017

    • Author(s)
      Koji Eriguchi and Yukimasa Okada
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 50 Issue: 26 Pages: 26LT01-26LT01

    • DOI

      10.1088/1361-6463/aa731a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] プラズマ曝露による窒化ホウ素膜機械特性変化のナノインデンテーション法による解析2017

    • Author(s)
      樋口智哉, 野間正男, 山下満, 長谷川繁彦, 江利口 浩二
    • Organizer
      第54回日本航空宇宙学会 関西・中部支部合同秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 反応性プラズマ支援コーティング(RePAC/MEP-IP)法による高機能窒化ホウ素薄膜の形成2017

    • Author(s)
      野間正男, 山下満, 江利口浩二, 長谷川繁彦
    • Organizer
      2017年真空・表面科学合同講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 反応性プラズマ支援成膜法により形成したBN膜の構造変化と密着性2016

    • Author(s)
      野間正男、山下満、江利口浩二、長谷川繁彦
    • Organizer
      2016年 第63回応用物理学会春季学術講演会
    • Place of Presentation
      東工大 大岡山キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Coatings of Boron Nitride Films for Vacuum Tribology by Reactive Plasma Assisted Coating (RePAC) Technology - Friction coefficient lowering under vacuum -2016

    • Author(s)
      M. Noma, K. Eriguchi, M. Yamashita, S. Hasegawa
    • Organizer
      The 7th Tsukuba International Coating Symposium (TICS7)
    • Place of Presentation
      Tsukuba, Japan
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Friction Coefficient Lowering in High-hardness Boron Nitride Films Under Ultra-high Vacuum2016

    • Author(s)
      M. Noma, K. Eriguchi, M. Yamashita, S. Hasegawa
    • Organizer
      AVS 63rd International Symposium & Exhibition
    • Place of Presentation
      Nashville, TN, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of superhard c-BN films on the body and edge of cutting tools by reactive plasma-assisted coating (RePAC)2016

    • Author(s)
      M. Noma, M. Yamashita, K. Eriguchi, S. Hasegawa
    • Organizer
      The 16th International Conference on Precision Engineering
    • Place of Presentation
      Hamamatsu, Japan
    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] RePAC法を用いたプラズマ窒化によるc-BN膜密着性の改善2016

    • Author(s)
      野間正男,山下満,江利口浩二,長谷川繁彦
    • Organizer
      第77 回 応用物理学秋季学術講演会
    • Place of Presentation
      新潟
    • Related Report
      2016 Annual Research Report
  • [Presentation] Characterization of polymorphism in boron nitride films prepared by Reactive Plasma-Assisted Coating2015

    • Author(s)
      S. Hasegawa, M. Noma, M. Yamashita, K.Eriguchi
    • Organizer
      The 19th SANKEN Int. Symp. / The 11th HANDAI Nanosci. Nanotechnol. Int. Symp.
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 反応性プラズマ支援成膜法により形成したBN 膜の構造と化学結合状態分析2015

    • Author(s)
      長谷川繁彦、野間正男、山下満、江利口浩二
    • Organizer
      2015年 第76 回応用物理学会秋季学術講演
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Remarks] 京都大学 航空宇宙工学専攻 推進工学分野 (江利口研)

    • URL

      http://www.propulsion.kuaero.kyoto-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 京都大学 航空宇宙工学専攻 推進工学分野 (斧・江利口研)

    • URL

      http://www.propulsion.kuaero.kyoto-u.ac.jp/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 大阪大学 産業科学研究所 量子システム創成研究分野

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/qse/index.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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