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Fabrication of ultra-hightemperature boride ceramics with novel properties

Research Project

Project/Area Number 15H04163
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/Microstructural control engineering
Research InstitutionNational Institute for Materials Science

Principal Investigator

Sakka Yoshio  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 特命研究員 (00354217)

Co-Investigator(Kenkyū-buntansha) VASYLKIV Oleg  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主任研究員 (00469785)
Co-Investigator(Renkei-kenkyūsha) SUZUKI Toru  (国研)物質・材料研究機構, 機能性材料研究拠点, グループリーダー (50267407)
NISHIMURA Toshiyuki  (国研)物質・材料研究機構, 構造材料研究拠点, グループリーダー (50354428)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Keywordsホウ化物セラミックス / 複合材料 / 配向体 / 共晶組織 / 力学特性 / ホウカ物セラミックス / ホウ化物系セラミックス
Outline of Final Research Achievements

The emphasis is on the processing approaches, especially colloidal processing in a strong magnetic field and SPS of transition metal diboride (MB2)-based composites, and SPS consolidation of eutectic composites of transition metal borides (MeB2:Me=Ti, Zr, Ta, Nb, V) and B4C. Considering the success of Si3N4 ceramics in the field of structural ceramics, the potential MB2-based ceramic composites with abundant elongated MB2 grains and textured structures have succeeded to possess improved fracture toughness and reliable high-temperature strength. Consolidation of in situ synthesized B4C–MeB2 eutectic composites by SPS has been successfully conducted for fabricating multicomponent eutectic composites. The composites show both good strength and good fracture toughness and the relationship among the microstructure and mechanical properties have been systematically examined.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (46 results)

All 2017 2016 2015 Other

All Journal Article (16 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 16 results,  Acknowledgement Compliant: 8 results,  Open Access: 3 results) Presentation (27 results) (of which Int'l Joint Research: 18 results,  Invited: 17 results) Remarks (3 results)

  • [Journal Article] High-temperature strength and plastic deformation behavior of niobium diboride consolidated by spark plasma sintering2017

    • Author(s)
      Demirskyi, D, Solodkyi, I., Nishimura, T., Sakka, Y, Vasylkiv, O.
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 100 Issue: 11 Pages: 5295-5305

    • DOI

      10.1111/jace.15048

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultra-high elevated temperature strength of TiB2-based ceramics consolidated by spark plasma sintering2017

    • Author(s)
      Demirskyi, D., Borodianska, H., Sakka, Y., Vasylkiv, O.
    • Journal Title

      Journal of the European Ceramic Society

      Volume: 37 Issue: 1 Pages: 393-397

    • DOI

      10.1016/j.jeurceramsoc.2016.08.009

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Flexural strength behavior of a ZrB2-TaB2 composite consolidated by non-reactive spark plasma sintering at 2300 °C2017

    • Author(s)
      Demirskyi, D., Vasylkiv, O.
    • Journal Title

      International Journal of Refractory Metals and Hard Materials

      Volume: 66 Pages: 31-35

    • DOI

      10.1016/j.ijrmhm.2017.02.003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spark plasma sintering and high-temperature strength of B6O-TaB22017

    • Author(s)
      Demirskyi, D., Vasylkiv, O.
    • Journal Title

      Journal of the European Ceramic Society

      Volume: 37 Issue: 8 Pages: 3009-3014

    • DOI

      10.1016/j.jeurceramsoc.2017.02.052

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Analysis of the high-temperature flexural strength behavior of B4C-TaB2eutectic composites produced by in situ spark plasma sintering2017

    • Author(s)
      Demirskyi, D., Vasylkiv, O.
    • Journal Title

      Materials Science and Engineering A

      Volume: 697 Pages: 71-78

    • DOI

      10.1016/j.msea.2017.04.093

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inherent anisotropy in transition metal diborides and microstructure/property tailoring in ultra-high temperature ceramics-A review2017

    • Author(s)
      Zhang, G.-J. Ni, D.-W, Zou, J., Liu, H.-T, Wu, W.-W., Liu, J.-X., Suzuki, T.S., Sakka, Y.
    • Journal Title

      Journal of the European Ceramic Society

      Volume: 38 Issue: 2 Pages: 371-389

    • DOI

      10.1016/j.jeurceramsoc.2017.09.012

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hardness and toughness control of brittle boron suboxide ceramics by consolidation of star-shaped particles by spark plasma sintering2016

    • Author(s)
      I. Solodkyi, Dmytro Demirskyi, Y. Sakka, O. Vasylkiv
    • Journal Title

      Ceramic International

      Volume: 42 Issue: 2 Pages: 3525-3530

    • DOI

      10.1016/j.ceramint.2015.10.157

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High-Strength B4CーTaB2 Eutectic Composites Obtained via in situ by Spark Plasma Sintering2016

    • Author(s)
      Demirskyi Dmytro, Y. Sakka, O. Vasylkiv
    • Journal Title

      J. Am. Ceram. Soc.

      Volume: 99 Issue: 7 Pages: 2436-2441

    • DOI

      10.1111/jace.14235

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of iron oxide nanoparticles with different morphologies by precipitation method with and without chitosan addition2016

    • Author(s)
      O. Vasylkiv, O. BEZDOROZHEV, Y. Sakka
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 124 Issue: 4 Pages: 489-494

    • DOI

      10.2109/jcersj2.15288

    • NAID

      130005142408

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Room and high temperature flexural failure of spark plasma sintered boron carbide2016

    • Author(s)
      O. Vasylkiv, D. Demirskyi, P Badica, T. Nishimura, A. I.Y.Tok, Y. Sakka, H Borodianska
    • Journal Title

      Ceramic International

      Volume: 42 Issue: 6 Pages: 7001-7013

    • DOI

      10.1016/j.ceramint.2016.01.088

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] High-Temperature Strength of Boron Suboxide Ceramic Consolidated by Spark Plasma Sintering2016

    • Author(s)
      D. Demirskyi, I. Solodkyi, Y. Sakka, O. Vasylkiv
    • Journal Title

      J. Am. Ceram. Soc.

      Volume: 99 Issue: 8 Pages: 2769-2777

    • DOI

      10.1111/jace.14308

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] High-strength TiB2-TaC ceramic composites prepared using reactive spark plasma consolidation2016

    • Author(s)
      D. Demirskyi, T. Nishimura, Y. Sakka, O. Vasylkiv
    • Journal Title

      Ceram. Int.

      Volume: 42 Issue: 1 Pages: 1298-1306

    • DOI

      10.1016/j.ceramint.2015.09.065

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] High-temperature reactive spark plasma consolidation of TiB2-NbC ceramic composites2015

    • Author(s)
      D. Demirskyi, Y. Sakka, O. Vasylkiv
    • Journal Title

      Ceram. Int.

      Volume: 41 Issue: 9 Pages: 10828-10834

    • DOI

      10.1016/j.ceramint.2015.05.022

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Densification microstructure evolution and mechanical properties of WC doped HfB2-SiC ceramics2015

    • Author(s)
      Liu J. X., Zhang G. J., Xu F. F., W. Wenwen, Hai-Tao Liu, Y. Sakka, T. Nishimura, T. Suzuki, D. Ni, Zou J.
    • Journal Title

      J. European Ceram. Soc.

      Volume: 95 Issue: 10 Pages: 2707-2714

    • DOI

      10.1016/j.jeurceramsoc.2015.04.009

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Consolidation of B4C-TaB2 eutectic ceramics composites by spark plasma sintering2015

    • Author(s)
      D. Demirskyi, Y. Sakka, O. Vasylkiv
    • Journal Title

      JOURNAL OF ASIAN CERAMIC SOCIETIES

      Volume: 3 Issue: 4 Pages: 369-372

    • DOI

      10.1016/j.jascer.2015.08.001

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Consolidation of B<sub>4</sub>C&ndash;VB<sub>2</sub> eutectic ceramics by spark plasma sintering2015

    • Author(s)
      D. Demirskyi, Y. Sakka, O. Vasylkiv
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 123 Issue: 1443 Pages: 1051-1054

    • DOI

      10.2109/jcersj2.123.1051

    • NAID

      130005106916

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Development of Electric current activated/assisted sintering (ECAS)2017

    • Author(s)
      Y. Sakka
    • Organizer
      WAIM2016
    • Place of Presentation
      Liston Hotel (上海、中国)
    • Year and Date
      2017-10-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Water-dispersible Carbon Nanostructures to Fabricate Advanced Composite Materials2017

    • Author(s)
      M. Estili, Y. Sakka
    • Organizer
      WAIM2016
    • Place of Presentation
      Liston Hotel (上海、中国)
    • Year and Date
      2017-10-16
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Electric current activated/assisted sintering (ECAS)2017

    • Author(s)
      SAKKA, Y.
    • Organizer
      PACRIM2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pulsed electro-discharged pressure sintering and Flash sintering.2017

    • Author(s)
      SAKKA, Y.
    • Organizer
      Workshop on Advanced Inorganic Materials (WAIM 2017)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Dispersion and reinforcing mechanisms of multi-walled carbon nanotubes in a ceramic material . 41st International Conference and Expo on Advanced Ceramics. 20172017

    • Author(s)
      ESTILI, Mehdi, SAKKA, Yoshio.
    • Organizer
      Dispersion and reinforcing mechanisms of multi-walled carbon nanotubes in a ceramic material . 41st International Conference and Expo on Advanced Ceramics. 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Processing and characterization of multi-walled carbon nanotube - ZrB2 ceramic matrix composite.2017

    • Author(s)
      ESTILI, Mehdi, SAKKA, Yoshio.
    • Organizer
      JSPM International Conference on Powder and Powder Metallurgy. 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Tailoring the microstructure in SiC by magnetic field2017

    • Author(s)
      SUZUKI, Tohru, KOBAYASHI, Kiyoshi, NISHIMURA, Toshiyuki, UCHIKOSHI, Tetsuo, SAKKA, Yoshio.
    • Organizer
      ISNT2017&ISSNOX5. 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of highly structure-controlled ceramics by advanced powder processing2017

    • Author(s)
      SAKKA Y.
    • Organizer
      CICC-10.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] セラミックスの高機能化と製造プロセスの革新を目指して2017

    • Author(s)
      目 義雄
    • Organizer
      2017年度 産学連携シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] セラミックスの高機能と製造プロセスの革新2017

    • Author(s)
      目 義雄
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Preparation of highly Carbon Nanotube (CNT) dispersed ZrB2 and textured Zr(Hf)B2-based UHT ceramics by SPS2017

    • Author(s)
      SAKKA Y. ESTILI, Mehdi,Zhang, G.-J
    • Organizer
      J-K International Ceramic Seminar-34.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Highly Textured Hydroxyapatite Ceramics by Colloidal Processing in a High Magnetic Field and Sintering2017

    • Author(s)
      SAKKA, Yoshio, Kazuya Takahashi, SUZUKI, Tohru, UCHIKOSHI, Tetsuo.
    • Organizer
      PACRIM2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Texturing and mechanical properties of MAX phase ceramics and Zr(Hf)B2-base ultra-high temperature ceramics.2017

    • Author(s)
      SAKKA, Y
    • Organizer
      International Conference of European Ceramic Society 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] FABRICATION AND SOME PROPERTIES OF MAX PHASE CRAMICS2017

    • Author(s)
      SAKKA, Yoshio, UCHIDA, Yuichi, MORITA, Koji, SUZUKI, Tohru, Guo-Jun Zhang.
    • Organizer
      5th International Symposium on SiAlONs and Non-oxides
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ECAS(SPS)による先端セラミックスの作製2016

    • Author(s)
      目義雄
    • Organizer
      第21回通電焼結研究会
    • Place of Presentation
      東北大学、金研
    • Year and Date
      2016-12-01
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Uniform Dispersion and Structural Evolution of Multi-Walled Carbon Nanotubes in ZrB2 Matrix2016

    • Author(s)
      ESTILIMehdi, Wen-wen Wu, Guo-Jun ZHANG, 目義雄
    • Organizer
      粉体粉末冶金協会秋季大会
    • Place of Presentation
      東北大学
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabrication Textured Non-oxide Si-based ceramics and their Properties2016

    • Author(s)
      目義雄
    • Organizer
      ISASC2016
    • Place of Presentation
      釜山、韓国
    • Year and Date
      2016-09-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 微粉体プロセスの高度化による先端セラミックスの創製2016

    • Author(s)
      目義雄
    • Organizer
      日本セラミックス協会秋季シンポジウム
    • Place of Presentation
      広島大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Carbon Nanotube Ceramic Matrix Composites: Processing and Characterizations2016

    • Author(s)
      M. Estili, Y. Sakka
    • Organizer
      HTCMC 9
    • Place of Presentation
      トロント、カナダ
    • Year and Date
      2016-06-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] SPS Processing to Fabricate Defect-Free Carbon Nanostructure-Dispersed Ceramic Matrix Composites2016

    • Author(s)
      ESTILIMehdi, 目義雄
    • Organizer
      粉体粉末冶金協会春季大会
    • Place of Presentation
      京都大学
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Boron Carbide Based Bulk Composites by Reactive Spark Plasma Sintering2016

    • Author(s)
      OlegVASYLKIV, 目義雄, Demirskyi D
    • Organizer
      粉体粉末冶金協会春季大会
    • Place of Presentation
      京都大学
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Texture developing and some properties of feeble magnetic ceramics2016

    • Author(s)
      Y. Sakka, T. Suzuki, T. Uchikoshi
    • Organizer
      ICCPS-13
    • Place of Presentation
      東大寺ホール、奈良
    • Year and Date
      2016-05-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Engineering of lightweight ceramic composites by spark plasma sintering2016

    • Author(s)
      O. Vasylkiv, H. Borodianska, Y. Sakka, Demirskyi Dmytro
    • Organizer
      Electric Field Assisted Sintering and Related Phenomena Far From From Equilibrium
    • Place of Presentation
      Tomar, Portugal
    • Year and Date
      2016-03-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] O. Vasylkiv, H. Borodianska, Y. Sakka, Demirskyi Dmytro : “Growing larger: Scaling up during spark plasma sintering of high temperature ceramics2016

    • Author(s)
      O. Vasylkiv, H. Borodianska, Y. Sakka, Demirskyi Dmytro
    • Organizer
      O. Vasylkiv, H. Borodianska, Y. Sakka, Demirskyi Dmytro : “Growing larger: Scaling up during spark plasma sintering of high temperature ceramics
    • Place of Presentation
      Tomar, Portugal
    • Year and Date
      2016-03-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of electric current activated/assisted sintering2015

    • Author(s)
      Y. Sakka, G. Salvatore
    • Organizer
      PACRIM 11
    • Place of Presentation
      済州島、韓国
    • Year and Date
      2015-08-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] SPSによるZrB2基超高温セラミックスの作製と力学特性2015

    • Author(s)
      目義雄, WUWenwen, ESTILIMehdi, 西村聡之, 鈴木達
    • Organizer
      粉体粉末冶金協会春季大会
    • Place of Presentation
      早稲田大学、東京
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fabrication of advanced ceramics by electric current activated/assisted sintering2015

    • Author(s)
      Y. Sakka, M. Estili, C. Hu, K. Sato, G. Salvatore
    • Organizer
      Engineering Ceramics 2015
    • Place of Presentation
      The Castle of Smolence, Slovakia
    • Year and Date
      2015-05-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] NIMS研究者情報データベースSAMURAI

    • URL

      http://samurai.nims.go.jp/SAKKA_Yoshio-j.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] samurai

    • URL

      http://samurai.nims.go.jp/SAKKA_Yoshio-j.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] NIMSの研究者情報データベース「SAMURAI

    • URL

      http://samurai.nims.go.jp/SAKKA_Yoshio-j.html

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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