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Preparation of zeolite membranes in a fluoride containing medium

Research Project

Project/Area Number 15H04174
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionYamaguchi University

Principal Investigator

KITA Hidetoshi  山口大学, 大学院創成科学研究科, 教授(特命) (10177826)

Co-Investigator(Kenkyū-buntansha) 熊切 泉  山口大学, 大学院創成科学研究科, 准教授 (20618805)
田中 一宏  山口大学, 大学院創成科学研究科, 准教授 (30188289)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2015: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsゼオライト膜 / 水熱合成 / 気体分離 / 浸透気化分離 / 化学工学 / 触媒・化学プロセス / 膜分離
Outline of Final Research Achievements

In this study, we prepared zeolite membranes such as MFI(ZSM-5), MOR, RHO and AEI using F-containing gels by a single hydrothermal synthesis. The role and location of F ion were also clarified. The membrane prepared from F-containing gel had a high flux and a high separation factor for a gas separation of CO2/CH4 or for a water/ethanol mixture. Especially the membranes showed good acidic durability and dehydration performance. The membrane prepared from the fluoride-containing precursor gel had a better acid stability and reproducibility than the membrane prepared from non fluoride-containing precursor gel. Long-term acid-stable zeolite membranes for the dehydration process will certainly advance the acceptance of zeolite membranes in industrial processes.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (8 results)

All 2018 2017 2016

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (5 results)

  • [Journal Article] Synthesis and Gas Permeation Properties of AEI Zeolite Membranes by DIPEA as a Template2018

    • Author(s)
      Ting Wu , Kazuhiro Tanaka, Xiangshu Chen , Izumi Kumakiri , Hidetoshi Kita
    • Journal Title

      膜

      Volume: 43 Pages: 67-73

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Seed Crystal Size on the Properties of Silicalite-1 Membranes Synthesized in a Fluoride Containing Medium2017

    • Author(s)
      L. Qiu, I. Kumakiri, K. Tanaka, X. Chen, H. Kita
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: 41(5) Pages: 1-6

    • NAID

      130006837137

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Rho Zeolite Membranes on Tubular Supports2016

    • Author(s)
      Bo Liu, Izumi Kumakiri, Kazuhiro Tanaka, Xiangshu Chen, Hidetoshi Kita
    • Journal Title

      Membrane

      Volume: 41 Pages: 81-86

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Preparation and permeation properties of AlPO-18 membrane2018

    • Author(s)
      Ting Wu,熊切泉,田中一宏,喜多英敏
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] RHOゼオライト膜の製膜と透過物性(II)2017

    • Author(s)
      柳波,熊切泉,田中一宏,喜多英敏
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工大(東京都江東区)
    • Year and Date
      2017-03-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] CHA、AEIなどの小細孔ゼオライト膜の製膜と透過物性2017

    • Author(s)
      喜多英敏、Ting Wu、柳 波、陳祥樹、熊切 泉、田中一宏
    • Organizer
      膜シンポジウム2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] Fイオン存在下に水熱合成したゼオライト膜の透過物性2016

    • Author(s)
      山本智貴, 山本琢也, 喜多英敏, 熊切泉, 田中一宏
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県徳島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] Preparation and Permeation Properties of Rho Zeolite Membrane2016

    • Author(s)
      Bo Liu, Izumi Kumakiri, Kazuhiro Tanaka, Hidetoshi Kita
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪府吹田市)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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