Preparation of zeolite membranes in a fluoride containing medium
Project/Area Number |
15H04174
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Properties in chemical engineering process/Transfer operation/Unit operation
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Research Institution | Yamaguchi University |
Principal Investigator |
KITA Hidetoshi 山口大学, 大学院創成科学研究科, 教授(特命) (10177826)
|
Co-Investigator(Kenkyū-buntansha) |
熊切 泉 山口大学, 大学院創成科学研究科, 准教授 (20618805)
田中 一宏 山口大学, 大学院創成科学研究科, 准教授 (30188289)
|
Project Period (FY) |
2015-04-01 – 2018-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2015: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
|
Keywords | ゼオライト膜 / 水熱合成 / 気体分離 / 浸透気化分離 / 化学工学 / 触媒・化学プロセス / 膜分離 |
Outline of Final Research Achievements |
In this study, we prepared zeolite membranes such as MFI(ZSM-5), MOR, RHO and AEI using F-containing gels by a single hydrothermal synthesis. The role and location of F ion were also clarified. The membrane prepared from F-containing gel had a high flux and a high separation factor for a gas separation of CO2/CH4 or for a water/ethanol mixture. Especially the membranes showed good acidic durability and dehydration performance. The membrane prepared from the fluoride-containing precursor gel had a better acid stability and reproducibility than the membrane prepared from non fluoride-containing precursor gel. Long-term acid-stable zeolite membranes for the dehydration process will certainly advance the acceptance of zeolite membranes in industrial processes.
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Report
(4 results)
Research Products
(8 results)