Mechanochemically assisted Synthesis of (M-Al)MFI-type zeolite and their catalytic properties

• Project/Area Number: 15H04181
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Catalyst/Resource chemical process
• Research Institution: Tohoku University
• Principal Investigator: Muramatsu Atsushi 東北大学, 多元物質科学研究所, 教授 (40210059)
• Co-Investigator(Kenkyū-buntansha): 蟹江 澄志 東北大学, 多元物質科学研究所, 准教授 (60302767) ; 中谷 昌史 東北大学, 多元物質科学研究所, 助教 (80451681)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000); Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2015: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
• Keywords: メカノケミカル反応 / ゼオライト / 骨格導入 / オレフィン合成 / 触媒 / メカノケミカル / 骨格内導入 / 触媒・化学プロセス / ナノ材料 / ジメチルエーテル / 低級オレフィン合成

Outline of Final Research Achievements

For the purpose of acidity control for MFI zeolite with the substation of Fe from a part of Al in the flame, the present study has been focused on the synthesis of MFI nanoparticles by the mechanochemical and the successive hydrothermal procedure. As a result, the precursor with Si-O-Fe structure has been formed and then the zeolite was finally obtained with the substitutional hetero-structure.

Research Products

• [Journal Article] Preparation of Nickel Carbide Nanoparticles and Their Electrode Catalytic Activity on Oxygen Reduction Reaction (2017)
  • Author(s): Changgyu An, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
  • Journal Title: Nanoscience and Nanotechnology Letters Volume: 9 Issue: 10 Pages: 1592-1595
  • DOI: 10.1166/nnl.2017.2502
  • Peer Reviewed
• [Journal Article] Size-Controlled Hydrothermal Synthesis of Monodispersed BaZrO3 Sphere Particles by Seeding (2017)
  • Author(s): Kiyoshi Kanie, Yuki Seino, Masaki Matsubara, Atsushi Muramatsu
  • Journal Title: Advanced Powder Technology Volume: 28 Issue: 1 Pages: 55-60
  • DOI: 10.1016/j.apt.2016.07.020
  • Peer Reviewed / Open Access
• [Journal Article] Direct Hydrothermal Synthesis of Size-Controlled Co₃O₄ Nanocubes under Highly Condensed Conditions (2017)
  • Author(s): Kiyoshi Kanie, Yusuke Tsujikawa, Atsushi Muramatsu
  • Journal Title: MATERIALS TRANSACTIONS Volume: 58 Issue: 7 Pages: 1014-1019
  • DOI: 10.2320/matertrans.M2017090
  • NAID: 130006777003
  • ISSN: 1345-9678, 1347-5320
  • Peer Reviewed / Open Access
• [Presentation] Controlled Substitution of Al in MFI by Mechanochemical and Hydrothermal Synthesis Method (2017)
  • Author(s): Atsushi Muramatsu, Kiyoshi Kanie, Masafumi Nakaya
  • Organizer: EMN on Mesoporous Materials 2017
  • Place of Presentation: Kaohsiung City, Taiwan
  • Year and Date: 2017-03-13
  • Int'l Joint Research / Invited
• [Presentation] Controlled Substitution of Al in MFI by Mechanochemical and HydrothermalSynthesis Method (2017)
  • Author(s): Atsushi Muramatsu
  • Organizer: EMN Meeting on Mesoporous Materials
  • Int'l Joint Research / Invited
• [Presentation] Photocatalytic activity of TiO2 and SrTiO3 nanoparticles precisely controlled in size and shape (2017)
  • Author(s): Atsushi Muramatsu, Takeshi Kimijima, Masafumi Nakaya, Kiyoshi Kanie
  • Organizer: PACRIM12
  • Int'l Joint Research / Invited
• [Presentation] メカノケミカル効果を利用したSn置換多孔質シリケートの合成と Sn含有率の制御 (2016)
  • Author(s): 坂口萌, 小林裕季, 中谷昌史, 蟹江澄志, 村松淳司
  • Organizer: 第118回触媒討論会
  • Place of Presentation: 岩手大学（岩手県・盛岡市）
  • Year and Date: 2016-09-21
• [Presentation] メカノケミカル反応を経由した水熱合成によるSn置換シリケート の調製 (2016)
  • Author(s): 坂口萌, 小林裕季, 中谷昌史, 蟹江澄志, 村松淳司
  • Organizer: ナノ学会第14回大会
  • Place of Presentation: 北九州国際会議場（福岡県・北九州市）
  • Year and Date: 2016-06-14
• [Presentation] Mechanochemical effect for hydrothermal synthesis of Sn substituted MFI-type silicates (2015)
  • Author(s): Moe Sakaguchi, Hiroki Kobayashi, Masafumi Nakaya, Atsushi Muramatsu
  • Organizer: The International Chemical Congress of Pacific Basin Societies 2015
  • Place of Presentation: USA, Hawaii
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] メカノケミカル法によるSn-MFIの合成とSn含有量制御 (2015)
  • Author(s): 坂口萌, 小林裕季, 中谷昌史, 村松淳司
  • Organizer: 第45回石油・石油化学討論会
  • Place of Presentation: 名古屋（ウインクあいち）
  • Year and Date: 2015-11-05
• [Presentation] Fe-substituted MFI zeolites with different acidic properties for DTO reaction (2015)
  • Author(s): Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
  • Organizer: International Symposium on Zeolite and Microporous Crystals 2015
  • Place of Presentation: 札幌（札幌コンベンションセンター）
  • Year and Date: 2015-06-28
  • Int'l Joint Research
• [Presentation] Conversion of dimethyl ether to light olefins over FeZSM-5 catalysts (2015)
  • Author(s): Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
  • Organizer: The 15th Korea-Japan Symposium on Catalysis
  • Place of Presentation: Korea, Busan
  • Year and Date: 2015-05-26
  • Int'l Joint Research
• [Presentation] Synthesis of MFI-type Sn substituted silicates via mechanochemical route (2015)
  • Author(s): Moe Sakaguchi, Hiroki Kobayashi, Masafumi Nakaya, Kiyoshi Kanie, Atsushi Muramatsu
  • Organizer: The 15th Korea-Japan Symposium on Catalysis
  • Place of Presentation: Korea, Busan
  • Year and Date: 2015-05-26
  • Int'l Joint Research