| Budget Amount *help |
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2017: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2016: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2015: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
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| Outline of Final Research Achievements |
Design of simple reaction pathway toward fine chemicals and functionalized products are desired due to the efficient usefulness of chemical resources and energy. Development of novel catalysts and catalytic reaction enables such simple reaction pathways through the activation of inert chemical bonds, such as C-H and C-O bonds, and transformation of stable molecules, such as CO2.
In this research, we focus on “concerted catalysis on surface” for the efficient transformation reactions. Metal complex and organic functionalities immobilized on same solid surface enabled several organic reactions. In addition, simple fluoride salts were found to be active catalysts for hydrosilylation of CO2. Detailed structure of catalysts and catalytic reaction mechanism were investigated by spectroscopic techniques, such as XAFS, NMR, and XPS.
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