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Investigation of radiation-induced reaction process of supercritical water for fundamentals of water chemistry in the next generation water-cooled reactor

Research Project

Project/Area Number 15H04243
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionOsaka University

Principal Investigator

Muroya Yusa  大阪大学, 産業科学研究所, 准教授 (40334320)

Co-Investigator(Renkei-kenkyūsha) YAMASHITA Shinichi  東京大学, 大学院・工学系研究科, 准教授 (20511489)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2016: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2015: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywords超臨界水 / 放射線分解反応過程 / 高時間分解分光 / スパー拡散反応計算 / 高温高圧水 / 放射線分解反応初期過程 / 原子力エネルギー / 量子ビーム / ピコ秒・ナノ秒時間分解分光 / 放射線分解
Outline of Final Research Achievements

It is of great importance to understand and control chemical environment of cooling water for long-term sustainability of water-cooled reactors. In radiation field, water is decomposed to form oxidative products which initiate undesirable effects on the structural materials such as SCC, transportation of radioactivity. Therefore, to understand the fundamental process of the radiolysis of water is indispensable on the support to water chemistry. Nevertheless, radiation chemistry of water at high temperature / high pressure condition (HTHP), or even supercritical regime are not established yet. In this project, it was developed a new HTHP ultrafast transient absorption spectroscopy system, which enables to measure radiation-induced fast process in supercritical condition. Accordingly, numerical reaction kinetic simulation codes were also developed. By using both approaching methods, the reaction mechanism involving important element reactions was investigated.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (28 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (8 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 7 results,  Open Access: 2 results) Presentation (17 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results)

  • [Int'l Joint Research] Univ. Paris-sud(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Univ. Sherbrooke(カナダ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Univ. Paris-sud(France)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] An improved method for modelling coolant radiolysis in ITER2018

    • Author(s)
      Zhong Fang, Xuewu Cao, Lili Tong, Yusa Muroya, Giles Whitaker, Mojtaba Momeni, Mingzhang Lin
    • Journal Title

      Fusion Eng. Des.

      Volume: 127 Pages: 91-98

    • DOI

      10.1016/j.fusengdes.2017.12.031

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Rate constant for the H + H2O -> OH + H2 reaction at elevated temperatures measured by pulse radiolysis2017

    • Author(s)
      Y. Muroya, S. Yamashita, P. Lertnaisat, S. Sanguanmith, J. Meesungnoen, J.-P. Jay-Gerin and Y. Katsumura
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 45 Pages: 30834-30841

    • DOI

      10.1039/c7cp06010f

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of the solvation state of electron in dissociative electron attachment reaction in aqueous solutions2017

    • Author(s)
      Furong Wang, Pierre Archirel, Yusa Muroya Shinichi Yamashita, Pascal Pernot, Chengying Yin, Abdel Karim El Omar, Uli Schmidhammer, Jean-Marie Teuler and Mehran Mostafavi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 34 Pages: 23068-23077

    • DOI

      10.1039/c7cp03997b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 5 Radiation Chemistry of Water and Aqueous Solutions2017

    • Author(s)
      室屋裕佐
    • Journal Title

      RADIOISOTOPES

      Volume: 66 Issue: 10 Pages: 425-435

    • DOI

      10.3769/radioisotopes.66.425

    • NAID

      130006770767

    • ISSN
      0033-8303, 1884-4111
    • Related Report
      2017 Annual Research Report
  • [Journal Article] Local density augmentation of supercritical water probed by 4,40-bpyH radical: A pulse radiolysis study2016

    • Author(s)
      Zhe Liu, Zhong Fang, Yusa Muroya, Haiying Fu, Yu Yan, Yosuke Katsumura, Mingzhang Lin
    • Journal Title

      Chem. Phys. Lett.

      Volume: 657 Pages: 78-82

    • DOI

      10.1016/j.cplett.2016.05.059

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ab initio spur size calculation in liquid water at room temperature2016

    • Author(s)
      Yusa Muroya, Asokendu Mozumder
    • Journal Title

      Chem. Phys. Lett.

      Volume: 657 Pages: 102-106

    • DOI

      10.1016/j.cplett.2016.05.021

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quick measurement of continuous absorption spectrum in ion beam pulse radiolysis: Application of optical multi-channel detector into transient species observation2016

    • Author(s)
      K. Iwamatsu, Y. Muroya, S. Yamashita, A. Kimura, M. Taguchi, Y. Katsumura
    • Journal Title

      Radiat. Phys. Chem.

      Volume: 119 Pages: 213-217

    • DOI

      10.1016/j.radphyschem.2015.10.024

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Deciphering the reaction between a hydrated electron and a hydronium ion at elevated temperatures2015

    • Author(s)
      J. Ma, S. Yamashita, Y. Muroya, Y. Katsumura, M. Mostafavi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 35 Pages: 22934-22939

    • DOI

      10.1039/c5cp04293c

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] パルスラジオリシス法による高温下の水素原子と水分子との反応(H + H2O → H2 + OH)に関する研究2018

    • Author(s)
      室屋裕佐、金森航、山下真一、Phantira Lertnaisat、Sunuchakan Sanguanmith、Jintana Meesungnoen、Jean-Paul Jay-Gerin、勝村庸介
    • Organizer
      日本原子力学会2018年春の大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ピコ秒パルスラジオリシス法による高温水中の電子溶媒和過程の研究2017

    • Author(s)
      室屋裕佐, 金森 航, 勝村庸介,山下真一, 古澤孝弘
    • Organizer
      日本原子力学会2017年春の大会
    • Place of Presentation
      東海大学(湘南)
    • Year and Date
      2017-03-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ps and ns pulse radiolysis study on electron solvation and spur reaction processes in polar liquids at high temperature and high pressure condition2017

    • Author(s)
      Yusa Muroya, Wataru Kanamori, Shinichi Yamashita, Yosuke Katsumura, Takahiro Kozawa
    • Organizer
      The 30th Miller Conference on Radiation Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高温高圧ピコ秒パルスラジオリシス法による高温水中の電子溶媒和過程の研究2017

    • Author(s)
      室屋裕佐、金森航、勝村庸介、山下真一、古澤孝弘
    • Organizer
      第60回放射線化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Electron solvation and spur reaction processes in polar liquids at high temperature condition2016

    • Author(s)
      Yusa Muroya, Tetsuro Yoshida, Yosuke Katsumura, Shinichi Yamashita, Takahiro Kozawa
    • Organizer
      International Conference on Ionizing Processes (ICIP 2016)
    • Place of Presentation
      NY, US
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Radiolysis of water at high temperature and high pressure conditions studied by a picosecond time-resolved electron pulse radiolysis2016

    • Author(s)
      Yusa Muroya, Wataru Kanamori, Yosuke Katsumura, Shinichi Yamashita, Takahiro Kozawa
    • Organizer
      20th International Nuclear Plant Chemistry Conference (NPC2016)
    • Place of Presentation
      Brighton, UK
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ピコ秒パルスラジオリシスおよびスパー拡散モデル計算による高温水のスパー拡散反応過程研究2016

    • Author(s)
      室屋裕佐, 金森 航, 勝村庸介,山下真一, 古澤孝弘
    • Organizer
      第59回放射線化学討論会
    • Place of Presentation
      高崎
    • Year and Date
      2016-09-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] ピコ秒パルスラジオリシスによる高温プロパノール中の電子溶媒和過程の研究2016

    • Author(s)
      室屋裕佐, 吉田哲郎, 金森 航, 勝村庸介, 山下真一, 古澤孝弘
    • Organizer
      日本原子力学会2016年秋の大会
    • Place of Presentation
      久留米市
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] ピコ秒パルスラジオリシスおよびスパー拡散モデル計算による高温水のスパー拡散反応過程研究2016

    • Author(s)
      室屋裕佐, 金森 航, 吉田哲郎, 勝村庸介, 山下真一, 古澤孝弘
    • Organizer
      第53回アイソトープ・放射線研究発表会
    • Place of Presentation
      東京大学
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electron solvation process, spur reaction process at high temperature2016

    • Author(s)
      Yusa Muroya, Tetsuro Yoshida, Wataru Kanamori, Yosuke Katsumura, Shinichi Yamashita, Takahiro Kozawa
    • Organizer
      3rd International Workshop on Radiation Effects in Nuclear Technology (RENT3)
    • Place of Presentation
      Hefei, China
    • Year and Date
      2016-06-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高温水のピコ秒パルスラジオリシス:スパー拡散過程における素反応2016

    • Author(s)
      室屋裕佐
    • Organizer
      日本原子力学会2016年春の大会
    • Place of Presentation
      宮城
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] ピコ秒パルスプローブによる高温高圧流体の放射線誘起高速反応研究2015

    • Author(s)
      室屋裕佐
    • Organizer
      先端放射線化学シンポジウム
    • Place of Presentation
      静岡
    • Year and Date
      2015-09-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高温水および超臨界水の放射線分解反応初期過程2015

    • Author(s)
      室屋裕佐
    • Organizer
      第59回放射化学討論会
    • Place of Presentation
      宮城
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高温水および超臨界水のピコ秒放射線分解反応2015

    • Author(s)
      室屋裕佐
    • Organizer
      日本原子力学会2015年秋の大会
    • Place of Presentation
      静岡
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Radiolysis of water at high temperature and pressure conditions:: A picosecond pulse radiolysis experiment and numerical simulations2015

    • Author(s)
      Yusa Muroya
    • Organizer
      Symposium on Water Chemistry and Corrosion in Nuclear Power Plants in Asia 2015
    • Place of Presentation
      Kalpakkam, India
    • Year and Date
      2015-09-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超臨界水のピコ秒パルスラジオリシスとモンテカルロ計算2015

    • Author(s)
      室屋裕佐
    • Organizer
      第52回アイソトープ・放射線研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Observation of solvated electron at elevated temperatures up to supercritical condition by the newly improved ps pulse-probe system2015

    • Author(s)
      Yusa Muroya
    • Organizer
      15th International Congress of Radiation Research
    • Place of Presentation
      Kyoto
    • Year and Date
      2015-05-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research

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Published: 2015-04-16   Modified: 2019-03-29  

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