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Functionality and applications of biomass-derived novel porous structures with toughness and transparency

Research Project

Project/Area Number 15H04524
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Wood science
Research InstitutionThe University of Tokyo

Principal Investigator

Saito Tsuguyuki  東京大学, 大学院農学生命科学研究科(農学部), 准教授 (90533993)

Co-Investigator(Kenkyū-buntansha) 斎藤 幸恵  東京大学, 大学院農学生命科学研究科(農学部), 准教授 (30301120)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2017: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Keywordsセルロースナノファイバー / セルロース / エアロゲル / キセロゲル / 断熱材 / ナノカーボン / 発泡体 / 断熱性
Outline of Final Research Achievements

We compared the heat transfer properties of novel foams and aerogels consisting of cellulose nanofibers (CNFs). The foams feature rather closed, microscale pores formed with a thin film-like solid phase, whereas the aerogels feature nanoscale open pores formed with a nanofibrous network-like solid skeleton. Unlike the aerogel samples, the thermal diffusivity of the foam decreases considerably with a slight increase in the solid fraction. The results indicate that for suppressing the thermal diffusion of air within high porosity solids, creating microscale spaces with distinct partitions is more effective than directly blocking the free path of air molecules at the nanoscale. Other investigations include the preparation of porous CNF structures by ambient-pressure drying and also the formation of CNF-derived nanocarbon structures.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (47 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 3 results,  Open Access: 1 results) Presentation (33 results) (of which Int'l Joint Research: 5 results,  Invited: 32 results) Book (3 results)

  • [Int'l Joint Research] KTH(Sweden)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] CERMAV(France)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Nematic structuring of transparent and multifunctional nanocellulose papers2018

    • Author(s)
      Zhao, M.; Ansari, F.; Takeuchi, M.; Shimizu, M.; Saito, T.; Berglund, L. A.; Isogai, A.
    • Journal Title

      Nanoscale Horiz.

      Volume: 3 Issue: 1 Pages: 28-34

    • DOI

      10.1039/c7nh00104e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ensemble evaluation of polydisperse nanocellulose dimensions: rheology, electron microscopy, X-ray scattering and turbidimetry2017

    • Author(s)
      Tanaka, R.; Kuribayashi, T.; Ogawa, Y.; Saito, T.; Isogai, A.; Nishiyama, Y.
    • Journal Title

      Cellulose

      Volume: 24 Issue: 8 Pages: 3231-3242

    • DOI

      10.1007/s10570-017-1334-6

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamic Viscoelastic Functions of Liquid-Crystalline Chitin Nanofibril Dispersions2017

    • Author(s)
      Yokoi, M.; Tanaka, R.; Saito, T.; Isogai, A.
    • Journal Title

      Biomacromolecules

      Volume: 18 Issue: 8 Pages: 2564-2570

    • DOI

      10.1021/acs.biomac.7b00690

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Estimating The Strength of Single Chitin Nanofibrils via Sonication-Induced Fragmentation2017

    • Author(s)
      Bamba, Y.; Ogawa, Y.; Saito, T.; Berglund, L. A.; Isogai, T.
    • Journal Title

      Biomacromolecules

      Volume: 18 Issue: 12 Pages: 4405-4410

    • DOI

      10.1021/acs.biomac.7b01467

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Optimization of Preparation of Thermally Stable Cellulose Nanofibrils via Heat-Induced Conversion of Ionic Bonds to Amide Bonds2017

    • Author(s)
      Lavoine, N.; Bras, J.; Saito, T.; Isogai, A.
    • Journal Title

      J. Polym. Sci. A Polym. Chem.

      Volume: 55 Issue: 10 Pages: 1750-1756

    • DOI

      10.1002/pola.28541

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] セルロースナノファイバー2017

    • Author(s)
      齋藤継之
    • Journal Title

      応用物理

      Volume: 86 Pages: 144-147

    • Related Report
      2016 Annual Research Report
  • [Journal Article] 強靭なエアロゲル2017

    • Author(s)
      齋藤継之
    • Journal Title

      化学と工業

      Volume: 70 Pages: 110-112

    • Related Report
      2016 Annual Research Report
  • [Journal Article] mprovement of the Thermal Stability of TEMPO-Oxidized Cellulose Nanofibrils by Heat-Induced Conversion of Ionic Bonds to Amide Bonds2016

    • Author(s)
      Lavoine, N.; Bras, J.; Saito, T.; Isogai, A.
    • Journal Title

      Macromol. Rapid Commun.

      Volume: 13 Issue: 13 Pages: 1033-1039

    • DOI

      10.1002/marc.201600186

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Partitioned airs at microscale and nanoscale: thermal diffusivity in ultrahigh porosity solids of nanocellulose2016

    • Author(s)
      Koh Sakai, Yuri Kobayashi, Tsuguyuki Saito, Akira Isogai
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 20434-20434

    • DOI

      10.1038/srep20434

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] セルロースナノファイバーの構造化と特性相関2018

    • Author(s)
      齋藤 継之
    • Organizer
      ナノテク展2018
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Nematic structuring of transparent and multifunctional nanocellulose papers2018

    • Author(s)
      Tsuguyuki Saito
    • Organizer
      255th ACS National Meeting & Exposition, Anselme Payen Award Symposium
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] CNF生産における化学改質の意義,TEMPO酸化法の発見と展開2017

    • Author(s)
      齋藤継之
    • Organizer
      日本化学会第97回春季年会
    • Place of Presentation
      慶応大学日吉キャンパス(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーって何?2017

    • Author(s)
      齋藤継之
    • Organizer
      第3回安藤塾
    • Place of Presentation
      東京大学弥生講堂一条ホール(東京都文京区)
    • Year and Date
      2017-03-03
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバー入門2017

    • Author(s)
      齋藤継之
    • Organizer
      グリーンサーキット
    • Place of Presentation
      東京大学向ヶ丘ファカルティハウス(東京都文京区)
    • Year and Date
      2017-01-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバー: TEMPO酸化法の発見と展開2017

    • Author(s)
      齋藤 継之
    • Organizer
      第57回澱粉研究懇談会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーの基本特性2017

    • Author(s)
      齋藤 継之
    • Organizer
      日本セラミックス協会 第54回東海若手セラミスト懇話会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバー生産における化学改質の意義,TEMPO酸化法の特徴と展開2017

    • Author(s)
      齋藤 継之
    • Organizer
      日本学術振興会 先端ナノデバイス・材料テクノロジー151委員会 平成29年度第3回研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバー入門-軽量高強度材から化粧品まで- 3.学会等名2017

    • Author(s)
      齋藤 継之
    • Organizer
      栃木航空宇宙懇話会 第96回月例研修会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] TEMPO酸化CNFの特徴と活用2017

    • Author(s)
      齋藤 継之
    • Organizer
      第5回高機能素材Week
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高分散性セルロースナノファイバーのキャラクタリゼーション2016

    • Author(s)
      齋藤継之
    • Organizer
      ナノセルロースフォーラム地域分科会第4回技術研修会
    • Place of Presentation
      JEF京浜ビル(神奈川県川崎市)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Thermal Diffusivity in Ultrahigh Porosity Solids of Nanocellulose2016

    • Author(s)
      Saito, T.
    • Organizer
      Nanocellulose Seminar at Royal Institute of Technology
    • Place of Presentation
      Stockholm(Sweden)
    • Year and Date
      2016-12-01
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] セルロースナノファイバーの基礎と応用展開2016

    • Author(s)
      齋藤継之
    • Organizer
      平成28年度繊維学会ナノファイバー技術戦略研究委員会勉強会
    • Place of Presentation
      東京工業大学南8号館(東京都目黒区)
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] TEMPO酸化セルロースナノファイバーの基本特性と応用展開2016

    • Author(s)
      齋藤継之
    • Organizer
      一般財団法人四国産業技術振興センター第二回CNF技術セミナー
    • Place of Presentation
      ホテルグランフォーレ(愛媛県四国中央市)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Cellulose Nanofiber: Fundamentals and Potential of the Emerging Bio-based Material2016

    • Author(s)
      Saito, T.
    • Organizer
      The Pan Pacific Conference 2016
    • Place of Presentation
      Seoul(Korea)
    • Year and Date
      2016-10-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 農学のすすめ2016

    • Author(s)
      齋藤継之
    • Organizer
      埼玉県立大宮高校創立90周年記念行事“大高人から大高生へ”
    • Place of Presentation
      埼玉県立大宮高校(埼玉県さいたま市)
    • Year and Date
      2016-10-13
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 新素材セルロースナノファイバーの基本特性と応用事例2016

    • Author(s)
      齋藤継之
    • Organizer
      化学工学会超臨界流体部会第15回サマースクール
    • Place of Presentation
      クロスウェーブ船橋(千葉県船橋市)
    • Year and Date
      2016-08-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ナノセルロース多孔質体の熱拡散性2016

    • Author(s)
      酒井紅; 小林ゆり; 齋藤継之; 磯貝明
    • Organizer
      セルロース学会第23回年次大会
    • Place of Presentation
      つくばカピオ(茨城県つくば市)
    • Year and Date
      2016-07-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 表面改質セルロースナノファイバーの基礎と応用2016

    • Author(s)
      齋藤継之
    • Organizer
      日本真空学会関西支部/日本表面科学会合同セミナー2016
    • Place of Presentation
      京都大学桂ホール(京都府京都市)
    • Year and Date
      2016-07-04
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーの構造解析と特性評価2016

    • Author(s)
      齋藤継之
    • Organizer
      JFEテクノリサーチ研究講演会
    • Place of Presentation
      JEF京浜ビル(神奈川県川崎市)
    • Year and Date
      2016-06-28
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 環境にやさしいセルロースナノファイバーの科学2016

    • Author(s)
      齋藤継之
    • Organizer
      第50回東京大学農学部公開セミナー
    • Place of Presentation
      東京大学弥生講堂一条ホール(東京都文京区)
    • Year and Date
      2016-06-18
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーの調製と新規材料への展開2016

    • Author(s)
      齋藤継之
    • Organizer
      有機エレクトロニクス材料研究会第217回研究会
    • Place of Presentation
      新宿NSビル(東京都新宿区)
    • Year and Date
      2016-06-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーの基本特性と応用事例2016

    • Author(s)
      齋藤継之
    • Organizer
      プラスチック成形加工学会第27回年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] TEMPO酸化セルロースナノファイバーの基本特性と応用事例2016

    • Author(s)
      齋藤継之
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2016-06-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Cellulose Nanofiber: Structures and Fundamental Properties2016

    • Author(s)
      Saito, T.
    • Organizer
      Nordic Polymer Days 2016
    • Place of Presentation
      Helsinki(Finland)
    • Year and Date
      2016-05-31
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新素材セルロースナノファイバーの可能性2016

    • Author(s)
      齋藤継之
    • Organizer
      ジャパンライフサイエンスウィーク2016
    • Place of Presentation
      東京ビックサイト(東京都江東区)
    • Year and Date
      2016-04-22
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Thermal diffusivity in ultrahigh porosity solids of nanocellulose2016

    • Author(s)
      Tsuguyuki Saito
    • Organizer
      251st ACS National Meeting & Exposition, Anselme Payen Award Symposium
    • Place of Presentation
      California, USA
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] セルロースナノファイバーの基礎と応用事例2016

    • Author(s)
      齋藤継之
    • Organizer
      ふじのくにCNFフォーラム第1回技術講演会
    • Place of Presentation
      静岡県, 富士市産業交流展示場
    • Year and Date
      2016-01-12
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] TEMPO-Oxidized Cellulose Nanofiber: Fundamentals and Applications2015

    • Author(s)
      Tsuguyuki Saito
    • Organizer
      2015 MRS Fall Meeting & Exhibit, Nanocellulose Materials and Beyond I
    • Place of Presentation
      Hynes Convention Center, Massachusetts, US
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] セルロースナノファイバーが拓く未来 ‐木材活用による高度部材イノベーション‐2015

    • Author(s)
      齋藤継之
    • Organizer
      みえCNF協議会キックオフセミナー(みえリーディング産業展2015)
    • Place of Presentation
      三重県, 四日市ドーム
    • Year and Date
      2015-11-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーの構造と基礎特性2015

    • Author(s)
      齋藤継之
    • Organizer
      第46回ナノ構造ポリマー研究会
    • Place of Presentation
      東京都, 味覚糖UHA館
    • Year and Date
      2015-11-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 天然セルロースのTEMPO触媒酸化2015

    • Author(s)
      齋藤継之
    • Organizer
      ナノセルロースフォーラム第5回技術セミナー
    • Place of Presentation
      東京都, 木材会館
    • Year and Date
      2015-07-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーの基礎特性と応用展開2015

    • Author(s)
      齋藤継之
    • Organizer
      ナノファイバー学会第6回年次大会
    • Place of Presentation
      東京都, 東京大学弥生講堂一条ホール
    • Year and Date
      2015-07-06
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Book] 機能紙最前線~次世代機能紙とその垂直連携に向けて~2017

    • Author(s)
      齋藤継之(分担執筆);機能紙研究会編
    • Total Pages
      350
    • Publisher
      (株)加工技術研究会
    • Related Report
      2016 Annual Research Report
  • [Book] ナノセルロースの製造技術と応用2016

    • Author(s)
      齋藤継之(分担執筆);ナノセルロースフォーラム編
    • Total Pages
      245
    • Publisher
      S&T出版
    • Related Report
      2016 Annual Research Report
  • [Book] 図解よくわかるナノセルロース2015

    • Author(s)
      齋藤継之(分担執筆); ナノセルロースフォーラム編
    • Total Pages
      208
    • Publisher
      日刊工業新聞社
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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