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Carbon material (cone-shaped graphitic whisker) generated in plant cell which works as microtube reactor

Research Project

Project/Area Number 15H04525
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Wood science
Research InstitutionThe University of Tokyo

Principal Investigator

Saito Yukie  東京大学, 大学院農学生命科学研究科(農学部), 准教授 (30301120)

Co-Investigator(Kenkyū-buntansha) 齋藤 継之  東京大学, 大学院農学生命科学研究科(農学部), 准教授 (90533993)
Co-Investigator(Renkei-kenkyūsha) HAMANE Daisuke  東京大学, 物性研究所, 特任専門職員 (20579073)
Research Collaborator MATSUMOTO Rika  東京工芸大学, 工学部, 教授
YAMADA Hajime  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2015: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Keywords木質バイオマス / カーボン材料 / 木質科学 / バイオマス / 構造・機能材料
Outline of Final Research Achievements

Cone-shaped graphitic whiskers (CGW) are easily produced by carbonization of woody plants, via heat treatment at >2000°C together with SiC, which works as nuclei for a stable growth of CGWs. Our crystallographic study with transmission microscopy characterized CGWs as super-helical cone stack of graphene. The intercalation behavior and contract-expand mobile behavior of CGW were revealed and the mechanisms were clarified. The density gradient centrifugation method was used to successfully separate CGWs from impurities. This can be further applied for sample preparations for measurements of their unrevealed unique properties. Plant-cell-mimic "microreactor" was synthesized with biopolymer and the generation mechanism of CGWs in plant cell cavity was discussed.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (17 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (3 results) Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results) Funded Workshop (1 results)

  • [Int'l Joint Research] IS2M-CNRS(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] IS2M-CNRS(フランス)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] IS2M-CNRS(フランス)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Helical superstructure of continuum graphene cone uncovered by TEM analysis of herringbone-striped pattern in graphitic whiskers2016

    • Author(s)
      Yukie Saito, Daisuke Nishio-Hamane
    • Journal Title

      J Crystal Growth

      Volume: 451 Pages: 27-32

    • DOI

      10.1016/j.jcrysgro.2016.06.037

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] キトサンモノリス構造体による円錐黒鉛ウイスカの製造2018

    • Author(s)
      山田肇、齋藤継之、斎藤幸恵
    • Organizer
      第68回日本木材学会大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] SEPARATION OF CONE-SHAPED GRAPHITIC WHISKERS BY DENSITY GRADIENT CENTRIFUGATION2017

    • Author(s)
      Yuko Goto, Yukie Saito
    • Organizer
      Carbon 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] PRODUCTION OF GRAPHITIC-WHISKER IN SCROLLED NATURAL POLYMER FILM AS MICROREACTOR2017

    • Author(s)
      Yukie Saito, Valeriy Luchnikov
    • Organizer
      Carbon 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] JOULE HEATED HOLLOW-CORE CARBON MICROTUBE REACTOR2017

    • Author(s)
      Luchnikov, V, Saito, Y, Ghimbeu, C
    • Organizer
      Carbon 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イネ科ケイ酸体を核とした円錐黒鉛ウイスカー形成2017

    • Author(s)
      斎藤幸恵、吉川正晃、藤本宏之
    • Organizer
      第67回日本木材学会大会
    • Place of Presentation
      九州大学(福岡県博多市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 木材粉炭を原料として製造した円錐黒鉛ウイスカーの密度勾配遠心法による分離精製2017

    • Author(s)
      後藤優子、斎藤幸恵
    • Organizer
      第67回日本木材学会大会
    • Place of Presentation
      九州大学(福岡県博多市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 木質の構成成分による黒鉛質化構造の差異2016

    • Author(s)
      斎藤幸恵、若林久人、吉川正晃、藤本宏之
    • Organizer
      第66回日本木材学会大会
    • Place of Presentation
      名古屋大学(愛知県、名古屋市)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Growth mechanism of helicaly stacked cone structure of graphene ribbon2016

    • Author(s)
      Yukie Saito, Masaaki Yoshikawa, Hiroyuki Fujimoto
    • Organizer
      Carbon2016
    • Place of Presentation
      ペンステート(アメリカ)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Carbonization of "Ijuk", leaf-sheath of sugar palm2015

    • Author(s)
      Yukie Saito
    • Organizer
      The Innovatiove Utilization of Tropical Woods
    • Place of Presentation
      Kangwon(韓国)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly Ordered Helical Turbostratic Carbon of Screw-Stacked Cone and its Intercalation Behavior2015

    • Author(s)
      Yukie Saito, Daisuke Hamane
    • Organizer
      Carbon 2015
    • Place of Presentation
      ドレスデン(、ドイツ)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 木材セルロースを由来とするナノカーボンエアロゲルの調製と特性解析2015

    • Author(s)
      安井皓章、酒井紅、齋藤継之、斎藤幸恵、磯貝明
    • Organizer
      セルロース学会第22回年次大会
    • Place of Presentation
      北海道大学学術交流会館(北海道、札幌市)
    • Related Report
      2015 Annual Research Report
  • [Presentation] 前処理の異なる木質原料の炭素質化と硫酸インターカレーション2015

    • Author(s)
      若林久人・斎藤幸恵・吉川正晃・藤本宏之
    • Organizer
      第42回炭素材料学会
    • Place of Presentation
      関西大学(大阪府、吹田市)
    • Related Report
      2015 Annual Research Report
  • [Funded Workshop] Carbon20152015

    • Place of Presentation
      ドレスデン国際会議場
    • Year and Date
      2015-07-10
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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