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Establishment of analysis of single nanowire by atom probe tomography in combination with transmission electron microscopy

Research Project

Project/Area Number 15H05413
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Shimizu Yasuo  東北大学, 金属材料研究所, 助教 (40581963)

Research Collaborator FUKATA Naoki  物質・材料研究機構, 主任研究員 (90302207)
INOUE Koji  東北大学, 金属材料研究所, 准教授 (50344718)
NAGAI Yasuyoshi  東北大学, 金属材料研究所, 教授 (10302209)
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Fiscal Year 2017: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Keywords3次元アトムプローブ / 透過電子顕微鏡 / ナノワイヤ / 量子構造 / 半導体
Outline of Final Research Achievements

A study of nanowire has been attracting much interest as a future gate-all-around quantum device in the state-of-the-art research. In order to understand the influence of crystal defects induced during growth on electrical property, the relationship between the dopants and defects needs to be clarified. In this study, atom probe tomography combined with transmission electron microscopy for obtaining dopant and defect distributions, respectively, in real space in a core-shall nanowire composed of silicon and germanium, was utilized. We have established an effective pick-up method of an arbitrary single nanowire by using a manipulator equipped in focused ion beam apparatus, and mounting on micropost prior to atom probe measurements at a high successful rate. Our experimental strategy can reveal defect distribution and elemental mapping in nanowires, and lead to clear understanding their relationship.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (42 results)

All 2018 2017 2016 2015 Other

All Journal Article (16 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 16 results,  Open Access: 3 results,  Acknowledgement Compliant: 2 results) Presentation (24 results) (of which Int'l Joint Research: 12 results,  Invited: 9 results) Remarks (2 results)

  • [Journal Article] Blocking of deuterium diffusion in poly-Si/Al2O3/HfxSi1?xO2/SiO2 high-k stacks as evidenced by atom probe tomography2018

    • Author(s)
      Tu Y.、Han B.、Shimizu Y.、Kunimune Y.、Shimada Y.、Katayama T.、Ide T.、Inoue M.、Yano F.、Inoue K.、Nagai Y.
    • Journal Title

      Appl. Phys. Lett.

      Volume: 112 Issue: 3 Pages: 032902-032902

    • DOI

      10.1063/1.5010256

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Composition evolution of gamma prime nanoparticles in the Ti-doped CoFeCrNi high entropy alloy2018

    • Author(s)
      Han Bin、Wei Jie、Tong Yang、Chen Da、Zhao Yilu、Wang Jing、He Feng、Yang Tao、Zhao Can、Shimizu Yasuo、Inoue Koji、Nagai Yasuyoshi、Hu Alice、Liu Chain Tsuan、Kai Ji Jung
    • Journal Title

      Scripta Materialia

      Volume: 148 Pages: 42-46

    • DOI

      10.1016/j.scriptamat.2018.01.025

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Industrial application of atom probe tomography to semiconductor devices2018

    • Author(s)
      A. D. Giddings, S. Koelling, Y. Shimizu, R. Estivill, K. Inoue, W. Vandervorst, and W. K. Yeoh
    • Journal Title

      Scripta Materialia

      Volume: 148 Pages: 82-90

    • DOI

      10.1016/j.scriptamat.2017.09.004

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Room-temperature 1.54 um photoluminescence from Er:Ox centers at extremely low concentration in silicon2017

    • Author(s)
      M. Celebrano, L. Ghirardini, M. Finazzi, Y. Shimizu, Y. Tu, K. Inoue, Y. Nagai, T. Shinada, Y. Chiba, A. Abderghafar, M. Yano, T. Tanii, E. Prati
    • Journal Title

      Opt. Lett. 42 (2017) 3311

      Volume: 42 Issue: 17 Pages: 3311-3314

    • DOI

      10.1364/ol.42.003311

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atom probe tomographic assessment of the distribution of germanium atoms implanted in a silicon matrix through nano-apertures2017

    • Author(s)
      Tu Y、Han B、Shimizu Y、Inoue K、Fukui Y、Yano M、Tanii T、Shinada T、Nagai Y
    • Journal Title

      Nanotechnology

      Volume: 28 Issue: 38 Pages: 385301-385301

    • DOI

      10.1088/1361-6528/aa7f49

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanoscopic analysis of oxygen segregation at tilt boundaries in silicon ingots using atom probe tomography combined with TEM and ab initio calculations2017

    • Author(s)
      OHNO Y.、INOUE K.、FUJIWARA K.、KUTSUKAKE K.、DEURA M.、YONENAGA I.、EBISAWA N.、SHIMIZU Y.、INOUE K.、NAGAI Y.、YOSHIDA H.、TAKEDA S.、TANAKA S.、KOHYAMA M.
    • Journal Title

      Microscopy

      Volume: 268 Issue: 3 Pages: 230-238

    • DOI

      10.1111/jmi.12602

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of laser power on atom probe tomographic analysis of boron distribution in silicon2017

    • Author(s)
      Y. Tu, H. Takamizawa, B. Han, Y. Shimizu, K. Inoue, T. Toyama, F. Yano, A. Nishida, Y. Nagai
    • Journal Title

      Ultramicroscopy

      Volume: 173 Pages: 58-63

    • DOI

      10.1016/j.ultramic.2016.11.023

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact of local atomic stress on oxygen segregation at tilt boundaries silicon2017

    • Author(s)
      Y. Ohno, K. Inoue, K. Fujiwara, K. Kutsukake, M. Deura, I. Yonenaga, N. Ebisawa, Y. Shimizu, K. Inoue, Y. Nagai, H. Yoshida, S. Takeda, S. Tanaka, M. Kohyama
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 6

    • DOI

      10.1063/1.4975814

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Weak-beam scanning transmission electron microscopy for quantitative dislocation density measurement in steels2017

    • Author(s)
      K. Yoshida, M. Shimodaira, T. Toyama, Y. Shimizu, K. Inoue, T. Yoshiie, K. J. Milan, R. Gerard, Y. Nagai
    • Journal Title

      Microscopy

      Volume: 66 Pages: 120-130

    • DOI

      10.1093/jmicro/dfw111

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Quantitative analysis of hydrogen in SiO2/SiN/SiO2 stacks using atom probe tomography2016

    • Author(s)
      Y. Kunimune, Y. Shimada, Y. Sakurai, M. Inoue, A. Nishida, B. Han, Y. Tu, H. Takamizawa, Y. Shimizu, K. Inoue, F. Yano, Y. Nagai, T. Katayama, and T. Ide
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 4

    • DOI

      10.1063/1.4948558

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Predoping effects of boron and phosphorous on arsenic diffusion along grain boundaries in polycrystalline silicon investigated by atom probe tomography2016

    • Author(s)
      H. Takamizawa, Y. Shimizu, K. Inoue, Y. Nozawa, T. Toyama, F. Yano, M. Inoue, A. Nishida, Y. Nagai
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 10 Pages: 253-256

    • DOI

      10.7567/apex.9.106601

    • NAID

      210000138076

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recombination activity of nickel, copper, and oxygen atoms segregating at grain boundaries in mono-like silicon crystals2016

    • Author(s)
      Y. Ohno, K. Kutsukake, M. Deura, I. Yonenaga, Y. Shimizu, N. Ebisawa, K. Inoue, Y. Nagai, H. Yoshida, S. Takeda
    • Journal Title

      Applied Physics Letters

      Volume: 109 Issue: 14

    • DOI

      10.1063/1.4964440

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boron distributions in individual core-shell Ge/Si and Si/Ge heterostructured nanowires2016

    • Author(s)
      B. Han, Y. Shimizu, J. Wipakorn, K. Nishibe, Y. Tu, K. Inoue, N. Fukata, Y. Nagai
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 47 Pages: 19811-19815

    • DOI

      10.1039/c6nr04384d

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Impact of carbon co-implantation on boron distribution and activation in silicon studied by atom probe tomography and spreading resistance measurements2016

    • Author(s)
      Y. Shimizu, H. Takamizawa, K. Inoue, F. Yano, S. Kudo, A. Nishida, T. Toyama, and Y. Nagai
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 2 Pages: 026501-026501

    • DOI

      10.7567/jjap.55.026501

    • NAID

      210000146038

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of shape, size, and areal density of a single plane of Si nanocrystals embedded in SiO2 matrix studied by atom probe tomography2016

    • Author(s)
      B. Han, Y. Shimizu, G. Seguini, E. Arduca, C. Castro, G. Ben Assayag, K. Inoue, Y. Nagai, S. Schamm-Chardon, and M. Perego
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 5 Pages: 3617-3622

    • DOI

      10.1039/c5ra26710b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Suppression of segregation of the phosphorus δ-doping layer in germanium by incorporation of carbon2016

    • Author(s)
      M. Yamada, K. Sawano, M. Uematsu, Y. Shimizu, K. Inoue, Y. Nagai, and K. M. Itoh
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 3 Pages: 031304-031304

    • DOI

      10.7567/jjap.55.031304

    • NAID

      210000146129

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] シリコン中に形成されたエルビウム不均一分布の3次元アトムプローブ評価2017

    • Author(s)
      清水康雄, Yuan Tu, アブデルガファ愛満, 矢野真麻, 鈴木雄大, 谷井孝至, 品田高宏, Enrico Prati, 井上耕治, 永井康介
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜、横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Atom probe tomographic study on implanted deuterium in Al2O3/HfxSi1-xO2/SiO2 stacks2017

    • Author(s)
      Y. Tu, B. Han, Y. Shimizu, Y. Kunimune, Y. Shimada, M. Inoue, K. Inoue, S. Nagata, and Y. Nagai
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜、横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Dopant detection in silicon nanostructures by atom probe tomography2017

    • Author(s)
      Y. Shimizu and K. Inoue
    • Organizer
      4th Bilateral Italy-Japan Seminar: Innovative Solutions for Single Atom Applications in Photonics and Nanoelectronics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Atom probe study of erbium and oxygen co-implanted silicon2017

    • Author(s)
      Y. Shimizu, Y. Tu, A. Abdelghafar, M. Yano, Y. Suzuki, T. Tanii, T. Shinada, E. Prati, M. Celebrano, M. Finazzi, L. Ghirardini, K. Inoue, and Y. Nagai
    • Organizer
      2017 Silicon Nanoelectronics Workshop
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atom probe study of semiconductor-based nanostructure2017

    • Author(s)
      Y. Shimizu
    • Organizer
      15th International Conference on Advanced Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of carbon on boron clustering and diffusion in silicon studied by atom probe tomography2017

    • Author(s)
      Y. Tu, Y. Shimizu, M. Inoue, Y. Kunimune, Y. Shimada, T. Katayama, T. Ide, K. Inoue, and Y. Nagai
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] シリコン中に共注入した酸素がエルビウム分布に与える影響2017

    • Author(s)
      清水康雄, Yuan Tu, アブデルガファ愛満, 鈴木雄大, 魏啓楠, 谷井孝至, 品田高宏, Enrico Prati, Michele Celebrano, Marco Finazzi, Lavinia Ghirardini, 井上耕治, 永井康介
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Direct observation of trapping of implanted deuterium in poly-Si/Al2O3/HfxSi1-xO2/SiO2 high-k stacks2017

    • Author(s)
      Y. Tu, B. Han, Y. Shimizu, M. Inoue, Y. Kunimune, Y. Shimada, T. Katayama, T. Ide, S. Nagata, K. Inoue, and Y. Nagai
    • Organizer
      2017 Materials Research Society Fall Meeting & Exhibit
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dopant distribution analysis core-shell nanowires by atom probe tomography2017

    • Author(s)
      Y. Shimizu, B. Han, W. Jevasuwan, K. Nishibe, Y. Tu, K. Inoue, N. Fukata, and Y. Nagai
    • Organizer
      2017 Materials Research Society Fall Meeting & Exhibit
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 3次元アトムプローブ法を用いた材料解析:原理と応用2017

    • Author(s)
      清水康雄
    • Organizer
      日本学術振興会 結晶加工と評価技術 第145委員会第156回研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 半導体・酸化物材料の3次元アトムプローブ分析2016

    • Author(s)
      清水康雄
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      産業貿易センタービル、横浜
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Hydrogen distribution analysis in Al2O3 films by atom probe tomography2016

    • Author(s)
      Y. Shimizu, B. Han, Y. Tu, K. Inoue, F. Yano, M. Inoue, Y. Kunimune, Y. Shimada, T. Katayama, T. Ide, and Y. Nagai
    • Organizer
      2016 Materials Research Society Fall Meeting & Exhibit
    • Place of Presentation
      ボストン、米国
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Direct observation of single ion implanted dopants distribution in silicon by atom probe tomography2016

    • Author(s)
      Y. Tu, B. Han, Y. Shimizu, K. Inoue, M. Yano, Y. Chiba, T. Tanii, T. Shinada, and Y. Nagai
    • Organizer
      2016 Materials Research Society Fall Meeting & Exhibit
    • Place of Presentation
      ボストン、米国
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of Si nanocrystals embedded in SiO2 matrix by atom probe tomography2016

    • Author(s)
      B. Han, Y. Shimizu, G. Seguini, E. Arduca, C. Castro, G. Ben Assayag, K. Inoue, Y. Nagai, S. Schamm-Chardon, and M. Perego
    • Organizer
      Energy Materials and Nanotechnology (EMN) Meeting on Nanocrystals
    • Place of Presentation
      西安、中国
    • Year and Date
      2016-10-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Three-dimensional analysis of phosphorus-doped Si nanocrystals embedded in SiO2 matrix by atom probe tomography2016

    • Author(s)
      Y. Shimizu, B. Han, G. Seguini, E. Arduca, C. Castro, G. Ben Assayag, K. Inoue, Y. Nagai, S. Schamm-Chardon, and M. Perego
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ、新潟
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Influence of high power laser on B distribution in Si obtained by atom probe tomography2016

    • Author(s)
      Y. Tu, H. Takamizawa, Y. Shimizu, K. Inoue, T. Toyama, F. Yano, A. Nishida, and Y. Nagai
    • Organizer
      Atom Probe Tomography & Microscopy 2016
    • Place of Presentation
      慶州、韓国
    • Year and Date
      2016-06-12
    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atom probe study of structural characteristics of Si nanocrystals embedded in SiO2 matrix2016

    • Author(s)
      B. Han, Y. Shimizu, G. Seguini, E. Arduca, C. Castro, G. Ben Assayag, K. Inoue, Y. Nagai, S. Schamm-Chardon, and M. Perego
    • Organizer
      Atom Probe Tomography & Microscopy 2016
    • Place of Presentation
      慶州、韓国
    • Year and Date
      2016-06-12
    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of boron doping in individual Ge/Si core-shell nanowires investigated by atom probe tomography2016

    • Author(s)
      B. Han, Y. Shimizu, K. Inoue, W. Jevasuwan, N. Fukata, and Y. Nagai
    • Organizer
      2016 Materials Research Society Spring Meeting
    • Place of Presentation
      Phoenix, Arizona, USA
    • Year and Date
      2016-03-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of dopant in individual Si/Ge core-shell nanowires investigated by atom probe tomography2016

    • Author(s)
      B. Han, Y. Shimizu, W. Jevasuwan, K. Nishibe, K. Inoue, N. Fukata, and Y. Nagai
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 3次元アトムプローブ法の半導体応用の現状と最近の話題2016

    • Author(s)
      清水康雄
    • Organizer
      日本学術振興会 ナノプローブテクノロジー 第167委員会 第81回研究会
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2016-01-12
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 先端ナノエレクトロニクス材料の元素分布分析2016

    • Author(s)
      清水康雄
    • Organizer
      第106回総研セミナー
    • Place of Presentation
      東京都市大学総合研究所
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 先端デバイス開発のための3次元アトムプローブ分析技術の応用例2016

    • Author(s)
      清水康雄
    • Organizer
      カメカテクニカルセミナー2016
    • Place of Presentation
      くるまプラザ貸会議室、東京
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Boron distribution in individual Ge/Si core-shell nanowires investigated by atom probe tomography2015

    • Author(s)
      B. Han, Y. Shimizu, K. Inoue, W. Jevasuwan, N. Fukata, and Y. Nagai
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Elemental distributions in semiconductor-based device structures analyzed by atom probe tomography2015

    • Author(s)
      Y. Shimizu, B. Han, Y. Tu, K. Inoue, and Y. Nagai
    • Organizer
      2015 International Symposium for Advanced Materials Research
    • Place of Presentation
      日月潭、台湾
    • Year and Date
      2015-08-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 永井研究室(清水康雄)

    • URL

      http://wani.imr.tohoku.ac.jp/yshimizu.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report 2015 Annual Research Report
  • [Remarks] 東北大学研究者紹介(清水康雄)

    • URL

      http://db.tohoku.ac.jp/whois/detail/bdade9d3e1da0c7a19d6872a59445e4e.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report 2015 Annual Research Report

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Published: 2015-04-16   Modified: 2019-03-29  

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