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Farbrication of polar superstructures to develop new photovoltaic materials

Research Project

Project/Area Number 15H05426
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Nakamura Masao  国立研究開発法人理化学研究所, 創発物性科学研究センター, 上級研究員 (50525780)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
Fiscal Year 2016: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2015: ¥20,410,000 (Direct Cost: ¥15,700,000、Indirect Cost: ¥4,710,000)
Keywords酸化物ヘテロ界面 / 自発分極 / バルク光起電力効果 / 太陽電池 / 酸化物ヘテロ接合 / 有機電荷移動錯体 / シフト電流 / 高効率太陽光発電材料 / 強相関エレクトロニクス / 表面・界面物性 / 酸化物界面
Outline of Final Research Achievements

The bulk photovoltaic effect observed in polar materials has a potential to be a photon-to-electron conversion mechanism to realize novel high efficiency solar cells. In this study, I investigated photovoltaic properties of heterojunctions composed of LaFeO3 and SrTiO3. Due to the polar discontinuity at the interface, the originally nonpolar insulator LaFeO3 becomes polar. The junctions exhibit anomalous photovoltaic properties driven by the induced polarization, such as the reversal of the sign of photocurrent depending on the thickness and interfacial termination layer. The photovoltaic efficiency of the LaFeO3 junctions exhibits large improvement compared to other Mott insulator junctions due to the bulk photovoltaic effect associated with the induced polarization.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • Research Products

    (13 results)

All 2017 2016 2015 Other

All Journal Article (7 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 7 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (5 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Nonlinear electron-phonon coupling in doped manganites2017

    • Author(s)
      V. Esposito, R. Mankowsky, M. Fechner, H. Lemke, M. Chollet, J.M. Glownia, M. Nakamura, M. Kawasaki, Y. Tokura, U. Staub, P. Beaud, and M. Forst
    • Journal Title

      Phys. Rev. Lett.

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Spontaneous Polarization and Bulk Photovoltaic Effect Driven by Polar Discontinuity in LaFeO3/SrTiO3 Heterojunctions2016

    • Author(s)
      M. Nakamura, F. Kagawa, T.Tanigaki, H. S. Park, T. Matsuda, D. Shindo, Y. Tokura, and M. Kawasaki
    • Journal Title

      PHYSICAL REVIEW LETTERS

      Volume: in press Issue: 15

    • DOI

      10.1103/physrevlett.116.156801

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Surface Ordering of Orbitals at Higher Temperature in LaCoO3 Thin Film2016

    • Author(s)
      Y. Yamasaki, J. Fujioka, H. Nakao, J. Okamoto, T. Sudayama, Y. Murakami, M. Nakamura, M. Kawasaki, T. Arima, and Y. Tokura
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 85 Issue: 2 Pages: 023704-023704

    • DOI

      10.7566/jpsj.85.023704

    • NAID

      210000133819

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Band alignment and photovoltaic effect of epitaxial α-PbO thin films2015

    • Author(s)
      E. Majima, Y. Kozuka, M. Uchida, M. Nakamura, M. Kawasaki
    • Journal Title

      Applied Physics Express

      Volume: 8 Issue: 7 Pages: 074001-074001

    • DOI

      10.7567/apex.8.074001

    • NAID

      210000137593

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Strain-sensitive spin-state ordering in thin films of perovskite LaCoO32015

    • Author(s)
      J. Fujioka, Y. Yamasaki, A. Doi, H. Nakao, R. Kumai,Y. Murakami, M. Nakamura, M. Kawasaki, T. Arima, Y. Tokura
    • Journal Title

      Physical Review B

      Volume: 92 Issue: 19 Pages: 072103-072103

    • DOI

      10.1103/physrevb.92.195115

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct Imaging of Dynamic Glassy Behavior in a Strained Manganite Film2015

    • Author(s)
      W. Kundhikanjana, Z. Sheng, Y. Yang, K. Lai, E. Ma, Y. Cui, M. Kelly, M. Nakamura, M. Kawasaki, Y. Tokura, Q. Tang, K. Zhang, X. Li, Z. Shen
    • Journal Title

      Physical Review Letters

      Volume: 115 Issue: 26 Pages: 265701-265701

    • DOI

      10.1103/physrevlett.115.265701

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermal generation of spin current in an antiferromagnet2015

    • Author(s)
      S. Seki, T. Ideue, M. Kubota, Y. Kozuka, R. Takagi, M. Nakamura, Y.Kaneko, M. Kawasaki, Y. Tokura
    • Journal Title

      Physical Review Letters

      Volume: 115 Issue: 26 Pages: 266601-266601

    • DOI

      10.1103/physrevlett.115.266601

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] Shift current photovoltaic effect in a quasi-one-dimensianl ferroelectric compound2017

    • Author(s)
      M. Nakamura, S. Horiuchi, S. Ishibashi, N. Ogawa, T. Kurumaji, F. Kagawa, Y. Tokura, and M. Kawasaki
    • Organizer
      CEMS-QPEC Symposium on Emergent Quantum Materials
    • Place of Presentation
      理化学研究所、和光
    • Year and Date
      2017-01-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Spontaneous polarization and anomalous photovoltaic effect induced in oxide heterointerfaces2017

    • Author(s)
      Masao Nakamura
    • Organizer
      2016 MRS Spring meeting
    • Place of Presentation
      Phoenix, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spontaneous polarization and bulk photovoltaic effect induced in designed interface of oxide heterojunctions2015

    • Author(s)
      M. Nakamura
    • Organizer
      CEMS Topical Meeting on Oxide Interface
    • Place of Presentation
      理化学研究所(埼玉県和光市)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Skyrmion formation in an epitaxial film of perovskite manganite with controlled magnetic anisotropy2015

    • Author(s)
      M. Nakamura, D. Morikawa, X. Z. Yu, F. Kagawa, T. Arima, M. Kawasaki, and Y. Tokura
    • Organizer
      Workshop on “Topological Magnets”
    • Place of Presentation
      理研理化学研究所(埼玉県和光市)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化物ヘテロ接合における界面誘起の自発分極2015

    • Author(s)
      中村優男、賀川史敬、谷垣俊明、松田強、進藤大輔、十倉好紀、川﨑雅司
    • Organizer
      応用物理学会2015秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(愛知県名古屋市)
    • Related Report
      2015 Annual Research Report
  • [Remarks] 理化学研究所 創発物性科学研究センター

    • URL

      http://www.cems.riken.jp/jp/

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report

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Published: 2015-04-16   Modified: 2018-03-22  

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