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Development of Hybrid Anvil Cell for polarized and unpolarized neutron diffraction experiment

Research Project

Project/Area Number 15H05433
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Quantum beam science
Research InstitutionNational Institute for Materials Science

Principal Investigator

Terada Noriki  国立研究開発法人物質・材料研究機構, 先端材料解析研究拠点, 主任研究員 (60442993)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥22,880,000 (Direct Cost: ¥17,600,000、Indirect Cost: ¥5,280,000)
Fiscal Year 2017: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
Keywordsマルチフェロイクス / 中性子回折 / 高圧力 / 中性子回折実験 / 強相関電子系 / 磁性 / 誘電体物性
Outline of Final Research Achievements

By developing the Hybrid-Anvil-Cell(HAC) for polarized and unpolarized neutron diffraction experiment, we have studied the pressure-induced ferroelectric properties in some multiferroic materials. By multi-exstream condition (5 GPa, 5 T, 1.5 K) neutron diffraction experiment for multiferroic TbMnO3 on the cold neutron time-of-flight diffractometer WISH in ISIS, we found that the gigantic ferroelectric polarization induced by high pressure in TbMnO3 is induced by the collinear magnetic ordering through the exchange striction mechanism. We also have developed the complete nonmagnetic HAC with nonmagnetic sapphire and diamond composite (or WC) anvils for Spherical-Neutron-Polarimetry (SNP) analysis experiment. By using the cell, we have succeeded in the first SNP analysis for the multiferroic CuFeO2 at Institut Laue Langevin, and determined the complex noncollinear magnetic structures in the pressure-induced ferroelectric phases.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (53 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (7 results) Journal Article (16 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 16 results,  Open Access: 1 results,  Acknowledgement Compliant: 6 results) Presentation (26 results) (of which Int'l Joint Research: 12 results,  Invited: 7 results) Remarks (4 results)

  • [Int'l Joint Research] Rutherford Appleton Laboratory/University of Oxford(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Institut Laue Langevin(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] モスクワ大学(ロシア連邦)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Rutherford Appleton Laboratory(英国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Institute of Laue Langevin(フランス)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Rutherford Appleton Laboratory(英国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] モスクワ大学(ロシア連邦)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] High-Pressure Synthesis, Structures, and Properties of Trivalent A-Site-Ordered Quadruple Perovskites RMn7O12 (R = Sm, Eu, Gd, and Tb)2018

    • Author(s)
      L. Zhang, N. Terada, R. D. Johnson, D. Khalyavin, P. Manuel, Y. Katsuya, M. Tanaka, K. Yamaura, A. A. Belik
    • Journal Title

      Inorganic Chemestry

      Volume: 印刷中

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Magnetic Bragg dip and Bragg edge in neutron transmission spectra of typical spin superstructures2017

    • Author(s)
      Mamiya Hiroaki、Oba Yojiro、Terada Noriki、Watanabe Norimichi、Hiroi Kosuke、Shinohara Takenao、Oikawa Kenichi
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 15516-15516

    • DOI

      10.1038/s41598-017-15850-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Magneto-orbital ordering in the divalent A-site quadruple perovskite manganites AMn7O12 (A=Sr, Cd, and Pb)2017

    • Author(s)
      Johnson R. D.、Khalyavin D. D.、Manuel P.、Radaelli P. G.、Glazkova I. S.、Terada N.、Belik A. A.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 5 Pages: 054448-054448

    • DOI

      10.1103/physrevb.96.054448

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Rich magnetoelectric phase diagrams of multiferroic single-crystal α-NaFeO22017

    • Author(s)
      Terada Noriki、Ikedo Yuta、Sato Hirohiko、Khalyavin Dmitry D.、Manuel Pascal、Miyake Atsushi、Matsuo Akira、Tokunaga Masashi、Kindo Koichi
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 3 Pages: 035128-035128

    • DOI

      10.1103/physrevb.96.035128

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evidence of Charge Transfer and Orbital Magnetic Moment in Multiferroic CuFeO22016

    • Author(s)
      Yasuo Narumi, Tetsuya Nakamura, Hidekazu Ikeno, Noriki Terada, Takayuki Morioka, Kota Saito, Hideaki Kitazawa, Koichi Kindo, and Hiroyuki Nojiri
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 85 Issue: 11 Pages: 114705-114705

    • DOI

      10.7566/jpsj.85.114705

    • NAID

      210000134153

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic ordering in pressure-induced phases with giant spin-driven ferroelectricity in multiferroic TbMnO32016

    • Author(s)
      N. Terada, D. D. Khalyavin, P. Manuel, T. Osakabe, A. Kikkawa, H. Kitazawa
    • Journal Title

      Physical Review B (Rapid Communications)

      Volume: 93 Issue: 8 Pages: 081104-081104

    • DOI

      10.1103/physrevb.93.081104

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Spin-Driven Multiferroic Properties of PbMn7O12 Perovskite2016

    • Author(s)
      A. A. Belik, Y. S. Glazkova, N. Terada, Y. Matsushita, A. V. Sobolev, I. A. Presniakov, N. Tsujii, S. Nimori, K. Takehana, and Y. Imanaka
    • Journal Title

      Inorganic chemistry

      Volume: 55 Issue: 12 Pages: 6169-6169

    • DOI

      10.1021/acs.inorgchem.6b00774

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Differentiation between Ferroelectricity and Thermally Stimulated Current in Pyrocurrent Measurements of Multiferroic MMn7O12 (M = Ca, Sr, Cd, Pb)2016

    • Author(s)
      N. Terada, Y. S. Glazkova, and A. A. Belik
    • Journal Title

      Physical Review B

      Volume: 93 Issue: 15 Pages: 155127-155127

    • DOI

      10.1103/physrevb.93.155127

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Activation of frozen ferroelectric domain wall by magnetic field sweeping in multiferroic CuFeO22016

    • Author(s)
      H. Tamatsukuri, S. Mitsuda, T. Nakajima, K. Shibata, C. Kaneko, K. Takehana, Y. Imanaka, N. Terada, H. Kitazawa, K. Prokes, S. Matas, K. Kiefer, S. Paeckel, A. Sokolowski, B. Klemke, and S. Gerischer
    • Journal Title

      PHYSICAL REVIEW B

      Volume: 93 Issue: 17 Pages: 174101-174101

    • DOI

      10.1103/physrevb.93.174101

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] 冷中性子TOF回折計WISHにおけるHybrid-Anvil-Cellを用いた高圧力中性子回折実験:マルチフェロイクスへの応用2016

    • Author(s)
      寺田典樹
    • Journal Title

      日本中性子科学会誌 「波紋」

      Volume: 26 Pages: 91-91

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 冷中性子TOF回折計WISHにおけるHybrid-Anvil-Cellを用いた 高圧力下中性子回折実験:マルチフェロイクスへの応用2016

    • Author(s)
      寺田典樹
    • Journal Title

      中性子科学会誌 波紋

      Volume: 5月号

    • NAID

      130007510633

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetic structure of the frustrated antiferromagnetic spin-1/2 chain substance Cu3Mo2O9: appearance of a partial disordered state2015

    • Author(s)
      M. Hase, H. Kuroe, V. Y. Pomjakushin, L. Leller, R. Tamura, N. Terada, Y. Matsushita, A. Doenni, and T. Sekine
    • Journal Title

      Physical Review B

      Volume: 92 Issue: 5

    • DOI

      10.1103/physrevb.92.054425

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] High-Pressure Synthesis, Crystal Structures, and Properties of CdMn7O12 and SrMn7O12 Perovskites2015

    • Author(s)
      Y. S. Glazkova, N. Terada, Y. Matsushita, Y. Katsuya, M. Tanaka, I. A. Presniakov, A. V. Sobolev, and A. A. Belik
    • Journal Title

      Inorganic Chemistry

      Volume: 54 Issue: 18 Pages: 9081-9091

    • DOI

      10.1021/acs.inorgchem.5b01472

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Multistage ordering and critical singularities in Co1-xZnxAl2O4 (0<x<1): Dilution and pressure effects in a magnetically frustrated2015

    • Author(s)
      T. Naka, K. Sato, Y. Matsushita, N. Terada, S. Ishii, T. Nakane, M. Taguchi, M. Nakayama, S. Ohara, S. Takami, A. Matsushita
    • Journal Title

      Physical Review B

      Volume: 91 Issue: 22 Pages: 1-10

    • DOI

      10.1103/physrevb.91.224412

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic ordering and ferroelectricity in multiferroic 2H-AgFeO2: Comparison between hexagonal and rhombohedral polytypes2015

    • Author(s)
      N. Terada, D. D. Khalyavin, P. Manuel, Y. Tsujimoto, and A. A. Belik
    • Journal Title

      Physical Review B

      Volume: 91 Issue: 9

    • DOI

      10.1103/physrevb.91.094434

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ferroelectricity induced by ferriaxial crystal rotation and spin helicity in a B-site-ordered double-perovskite multiferroic In2NiMnO62015

    • Author(s)
      Noriki Terada, Dmitry D. Khalyavin, Pascal Manuel, Wei Yi, Hiroyuki S. Suzuki, Naohito Tsujii, Yasutaka Imanaka, and Alexei A. Belik
    • Journal Title

      Physical Review B

      Volume: 91 Issue: 10

    • DOI

      10.1103/physrevb.91.104413

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 単結晶を用いた菱面体晶および六方晶AgFeO2の磁気秩序と誘電分極の探査2018

    • Author(s)
      寺田典樹, D D. Khalyavin, P. Manuel, F. Orlandi, 池戸優太, 佐藤博彦
    • Organizer
      2018年日本物理学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 中性子透過スペクトルに現れるスピン秩序由来の磁気ブラッグエッジ・ブラッグディップとその利用2018

    • Author(s)
      間宮広明, 大場洋次郎, 寺田典樹, 渡邉騎通, 廣井孝介, 篠原武尚, 及川健一
    • Organizer
      2018年日本物理学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高圧力下3次元偏極解析に向けた非磁性ハイブリッドアンビルセルの開発2017

    • Author(s)
      寺田典樹, Laurent Chapon, 長壁豊隆
    • Organizer
      2017年日本物理学会年次大会
    • Place of Presentation
      大阪大学(大阪府豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] スピン誘導型強誘電体CuFeO2の一軸圧力下における磁場誘起新奇強誘電相の探査2017

    • Author(s)
      玉造博夢, 清水崇宏, 満田節生, 廣浦晃, 山崎祐希, 竹端寛治, 今中康貴, 寺田典樹, 北澤英明
    • Organizer
      2017年日本物理学会年次大会
    • Place of Presentation
      大阪大学(大阪府豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Spherical neutron polarimetry analysis under pressure for delafossite CuFeO22017

    • Author(s)
      N. Terada, N. Qureshi, L. C. Chapon and T. Osakabe
    • Organizer
      The 9th Asia Pacific Center for Theoretical Physics Workshop on Multiferroics, University of Tokyo, Kashiwa Nov 9-11, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] New perovskites in R2O3-Mn2O3 systems (R = rare-earths)2017

    • Author(s)
      A. A. Belik, L. Zhang, Y. Matsushita, N. Terada, Y. Katsuya, M. Tanaka, and K. Yamaura
    • Organizer
      AIRAPT-26, China National Convention Center,Beijing,China Aug 19-24, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Research2017

    • Author(s)
      N. Terada
    • Organizer
      The 15th International Conference on Advanced Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高圧・高磁場下における中性子回折実験によるマルチフェロイクスの研究2017

    • Author(s)
      寺田典樹
    • Organizer
      強磁場コラボラトリーが拓く未踏計測領域への挑戦と物質・材料科学の最先端
    • Related Report
      2017 Annual Research Report
  • [Presentation] 中性子散乱でできること2017

    • Author(s)
      寺田典樹
    • Organizer
      第60回化合部新磁性材料研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高圧力下中性子3次元偏極解析によるマルチフェロイクスCuFeO2の圧力誘起強誘電相の磁気構造決定2017

    • Author(s)
      寺田典樹, Navid Qureshi, Laurent Chapon, 長壁豊隆
    • Organizer
      2017年日本物理学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Research2016

    • Author(s)
      寺田典樹
    • Organizer
      第26回 日本MRS年次大会
    • Place of Presentation
      マツ・ムラホール(神奈川県横浜市中区住吉町)
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Research2016

    • Author(s)
      Noriki Terada
    • Organizer
      The 8th Asia Pacific Center for Theoretical Physics Workshop
    • Place of Presentation
      上海大学(中国)
    • Year and Date
      2016-10-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マルチフェロイクスMM7O12における焦電流の再検証2016

    • Author(s)
      寺田典樹, Y. S. Glazkova, and A. A. Belik
    • Organizer
      2016年日本物理学会年会
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] マルチフェロイック物質 CuFeO2 の価数状態2016

    • Author(s)
      鳴海康雄,中村哲也,池野豪一, 寺田典樹,北澤英明, 金道浩一, 野尻浩之
    • Organizer
      2016年日本物理学会年会
    • Place of Presentation
      東北学院大学
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高圧下中性子回折によるマルチフェロイクスの研究2015

    • Author(s)
      寺田典樹
    • Organizer
      第5回 応用セラミックス研究所 材料構造講演会
    • Place of Presentation
      東工大
    • Year and Date
      2015-10-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] High-Pressure Neutron Diffraction with Hybrid-Anvil-Cell for Multiferroic Materials2015

    • Author(s)
      N. Terada, D. D. Khalyavin, P. Manuel, T. Osakabe, A. Kikkawa, P. G. Radaelli and H. Kitazawa
    • Organizer
      NIMS conference 2015
    • Place of Presentation
      つくば
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Magnetic ordering and ferroelectricity in multiferroic 2H-AgFeO2: Comparison between hexagonal and rhombohedral polytypes2015

    • Author(s)
      N. Terada, D. D. Khalyavin, P. Manuel, Y. Tsujimoto and A. A. Belik
    • Organizer
      NIMS conference 2015
    • Place of Presentation
      つくば
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高圧下中性子回折によるTbMnO3の圧力磁場誘起巨大強誘電相の磁気秩序の解明2015

    • Author(s)
      寺田典樹, Dmitry Khalyavin, Pascal Manuel, 長壁豊隆, 吉川明子, 北澤英明
    • Organizer
      2015年日本物理学会秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] マルチフェロイック三角格子反強磁性体3R-AgFeO2とα-NaFeO2の単結晶作成と強磁場物性2015

    • Author(s)
      池戸優太, 佐藤博彦, 金道浩一, 松尾晶, 徳永将史, 三宅厚志, 寺田典樹
    • Organizer
      2015年日本物理学会秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] スピネル型CoAl2O4系の置換および圧力効果2015

    • Author(s)
      名嘉節, 佐藤康一, 寺田典樹, 石井聡, 高見誠一, 田口実, 中根茂行, 中山美奈子, 松下能孝, 松下明行
    • Organizer
      2015年日本物理学会秋季大会
    • Place of Presentation
      関西大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Crystal Chemistry and Physics of Perovskites with Small Cations at the A Site2015

    • Author(s)
      A. A. Belik, Y. Wei, Y. Matsushita, M. Tanaka, N. Terada, H. S. Suzuki, N. Tsujii, Y. Imanaka, D. D. Khalyavin, P. Manuel, A. V. Sobolev and I. A. Presnyakov
    • Organizer
      15th EUROPEAN CONFERENCE ON SOLID STATE CHEMISTRY
    • Place of Presentation
      Vienna
    • Year and Date
      2015-08-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystal Chemistry and Physics of Perovskites with Small Cations at the A Site2015

    • Author(s)
      A. A. Belik, Y. Wei, Y. Matsushita, M. Tanaka, N. Terada, H. S. Suzuki, N. Tsujii, Y. Imanaka, D. D. Khalyavin, P. Manuel, A. V. Sobolev and I. A. Presnyakov
    • Organizer
      12th International Conference on Materials Chemistry
    • Place of Presentation
      Univ. of York, UK
    • Year and Date
      2015-07-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Field induced phenomena in magnetically frustrated systems Co1-xMxAl2O4 (M = Mg, Zn)2015

    • Author(s)
      T. Naka, K. Sato, S. Ishii, T. Nakane. N. Terada, M. Taguchi, M. Nakayama, Y. Matsushita, A. Matsushita and S. Takami
    • Organizer
      International conference on magnetism 2015
    • Place of Presentation
      Barcelona
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic structure of quasi-one-dimensional frustrated antiferromagnet Cu3Mo2O92015

    • Author(s)
      M. Hase, H. Kuroe, V. Y. Pomjakushin, L. Keller, R. Tamura, N. Terada, Y. Matsushita, S Dnni, and T. Sekine
    • Organizer
      International conference on magnetism 2015
    • Place of Presentation
      Barcelona
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Single-crystal growth and magnetic properties of multiferroic triangular- lattice antiferromagnet AgFeO2 and alpha-NaFeO22015

    • Author(s)
      Y. Ikedo, H. Sato, K. Kindo, A. Matsuo, M. Tokunaga, A. Miyake and N. Terada
    • Organizer
      International conference on magnetism 2015
    • Place of Presentation
      Barcelona
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A comparison in multiferroic coupling between triangular lattice polytypes of hexagonal and rhombohedral AgFeO22015

    • Author(s)
      N. Terada, D. D. Khalyavin. P. Manuel, Y. Tsujimoto. A. A. Belik
    • Organizer
      International conference on magnetism 2015
    • Place of Presentation
      Barcelona
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Remarks] Terada homepage

    • URL

      http://www.nims.go.jp/nsg/terada/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] SAMURAI NIMS Researchers Directory Service

    • URL

      https://samurai.nims.go.jp/profiles/terada_noriki

    • Related Report
      2017 Annual Research Report
  • [Remarks] 物質・材料研究機構のSAMURAIシステム

    • URL

      http://samurai.nims.go.jp/TERADA_Noriki-j.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 寺田典樹のホームページ

    • URL

      http://www.nims.go.jp/nsg/terada/index.html

    • Related Report
      2016 Annual Research Report

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Published: 2015-04-16   Modified: 2022-09-01  

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