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Elucidating key factors of coherent conduction in polymer semiconductors and modeling of the conduction mechanisms

Research Project

Project/Area Number 15H05455
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Condensed matter physics II
Research InstitutionYamagata University (2016-2017)
The University of Tokyo (2015)

Principal Investigator

Matsui Hiroyuki  山形大学, 大学院有機材料システム研究科, 准教授 (80707357)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords有機電界効果トランジスタ / ポリマー半導体 / バンド伝導 / OFETs / OTFTs / polymer semiconductors / band transport / 有機半導体 / 高分子半導体 / ホール効果 / バンド計算 / 有効質量 / 電子スピン共鳴 / 高配向性薄膜 / イオン液体 / 高移動度
Outline of Final Research Achievements

Polymer semiconductor, in which conjugated organic molecules are polymerized, is an electronic material excellent in solubility, homogeneous film formation by solution processes, low temperature processability, and mechanical flexibility. However, having many structural disorders and defects, polymer semiconductor had been believed to follow hopping transport model, where the maximum mobility is at most several cm2/Vs. In this study, we have clarified that band transport can be realized in some polymer semiconductors by the measurements of mobility exceeding 10 cm2/Vs, its temperature dependence and Hall effect. The relationship between structure and band conduction was also analyzed in detail.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (38 results)

All 2018 2017 2016 2015 Other

All Journal Article (19 results) (of which Int'l Joint Research: 12 results,  Peer Reviewed: 19 results,  Open Access: 8 results,  Acknowledgement Compliant: 2 results) Presentation (17 results) (of which Int'l Joint Research: 6 results,  Invited: 6 results) Remarks (2 results)

  • [Journal Article] One step facile synthesis of a novel anthanthrone dye-based, dopant-free hole transporting material for efficient and stable perovskite solar cells2018

    • Author(s)
      H. D. Pham, K. Hayasake, J. Kim, T. T. Do, H. Matsui, S. Manzhos, K. Feron, S. Tokito, T. Watson, W. C. Tsoi, N. Motta, J. R. Durrant, S. M. Jain, P. Sonar
    • Journal Title

      J. Mater. Chem. C

      Volume: 6 Issue: 14 Pages: 3699-3708

    • DOI

      10.1039/c7tc05238c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Printed Organic Amplification System for Wearable Potentiometric Electrochemical Sensors2018

    • Author(s)
      R. Shiwaku, H. Matsui, K. Nagamine, M. Uematsu, T. Mano, Y. Maruyama, A. Nomura, K. Tsuchiya, K. Hayasaka, Y. Takeda, T. Fukuda, D. Kumaki, S. Tokito
    • Journal Title

      Sci. Rep.

      Volume: 8 Issue: 1 Pages: 3822-3822

    • DOI

      10.1038/s41598-018-22265-1

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Switching Time in Ferroelectric Organic Field-Effect Transistors2018

    • Author(s)
      R. Sugano, T. Tashiro, T. Sekine, H. Matsui, D. Kumaki, F. D. D. Santos, A. Miyabo, S. Tokito
    • Journal Title

      Physica Status Solidi (a)

      Volume: 印刷中 Issue: 11

    • DOI

      10.1002/pssa.201701059

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fully Printed Wearable Vital Sensor for Human Pulse Rate Monitoring using Ferroelectric Polymer2018

    • Author(s)
      T. Sekine, R. Sugano, T. Tashiro, J. Sato, Y. Takeda, H. Matsui, D. Kumaki, F. D. D. Santos, A. Miyabo, S. Tokito
    • Journal Title

      Sci. Rep.

      Volume: 8 Issue: 1 Pages: 4442-4442

    • DOI

      10.1038/s41598-018-22746-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A Printed Organic Circuit System for Wearable Amperometric Electrochemical Sensors2018

    • Author(s)
      R. Shiwaku, H. Matsui, K. Nagamine, M. Uematsu, T. Mano, Y. Maruyama, A. Nomura, K. Tsuchiya, K. Hayasaka, Y. Takeda, T. Fukuda, D. Kumaki, S. Tokito
    • Journal Title

      Sci. Rep.

      Volume: 8 Issue: 1 Pages: 6368-6368

    • DOI

      10.1038/s41598-018-24744-x

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Painting Integrated Complementary Logic Circuits for Single-Crystal Organic Transistors: A Demonstration of a Digital Wireless Communication Sensing Tag2017

    • Author(s)
      A. Yamamura, H. Matsui, M. Uno, N. Isahaya, Y. Tanaka, M. Kudo, M. Ito, C. Mitsui, T. Okamoto, J. Takeya
    • Journal Title

      Adv. Electron. Mater.

      Volume: 3 Issue: 7 Pages: 1600456-1600456

    • DOI

      10.1002/aelm.201600456

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of molecular doping in conjugated polymers by thermal annealing2017

    • Author(s)
      R. Fujimoto, S. Watanabe, Y. Yamashita, J. Tsurumi, H. Matsui, T. Kushida, C. Mitsui, H. T. Yi, V. Podzorov, J. Takeya
    • Journal Title

      Org. Electron.

      Volume: 47 Pages: 139-146

    • DOI

      10.1016/j.orgel.2017.05.019

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Coexistence of ultra-long spin relaxation time and coherent charge transport in organic single-crystal semiconductors2017

    • Author(s)
      Junto Tsurumi, Hiroyuki Matsui, Takayoshi Kubo, Roger Hausermann, Chikahiko Mitsui, Toshihiro Okamoto, Shun Watanabe, and Jun Takeya,
    • Journal Title

      Nature Physics

      Volume: 13 Issue: 10 Pages: 994-998

    • DOI

      10.1038/nphys4217

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Boron-Stabilized Planar Neutral π-Radicals with Well-Balanced Ambipolar Charge-Transport Properties2017

    • Author(s)
      Kushida Tomokatsu、Shirai Shusuke、Ando Naoki、Okamoto Toshihiro、Ishii Hiroyuki、Matsui Hiroyuki、Yamagishi Masakazu、Uemura Takafumi、Tsurumi Junto、Watanabe Shun、Takeya Jun、Yamaguchi Shigehiro
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 41 Pages: 14336-14339

    • DOI

      10.1021/jacs.7b05471

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Compactly Designed Organic Complementary D-Type Flip-Flop Circuits Fabricated with Inkjet Printing2017

    • Author(s)
      K. Hayasaka, H. Matsui, Y. Takeda, R. Shiwaku, Y. Tanaka, T. Shiba, D. Kumaki, S. Tokito
    • Journal Title

      Adv. Electron. Mater.

      Volume: 3 Issue: 9 Pages: 1700208-1700208

    • DOI

      10.1002/aelm.201700208

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic Complementary Inverter Circuits Fabricated with Reverse Offset Printing2017

    • Author(s)
      Y. Takeda, Y. Yoshimura, R. Shiwaku, K. Hayasaka, T. Sekine, T. Okamoto, H. Matsui, D. Kumaki, Y. Katayama, S. Tokito
    • Journal Title

      Adv. Electron. Mater.

      Volume: 4 Issue: 1 Pages: 1700313-1700313

    • DOI

      10.1002/aelm.201700313

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uniform, high performance, solution processed organic thin-film transistors integrated in 1 MHz frequency ring oscillators2017

    • Author(s)
      S. D. Ogier, H. Matsui, LinrunFengaMikeSimmsa, M. Mashayekhi, J. Carrabina, L. Teres, S. Tokito
    • Journal Title

      Org. Electron.

      Volume: 54 Pages: 40-47

    • DOI

      10.1016/j.orgel.2017.12.005

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Printed Organic Inverter Circuits with Ultralow Operating Voltages2017

    • Author(s)
      Rei Shiwaku, Hiroyuki Matsui,* Kazuma Hayasaka, Yasunori Takeda, Takashi Fukuda, Daisuke Kumaki, and Shizuo Tokito*
    • Journal Title

      Advanced Electronic Materials

      Volume: - Issue: 5

    • DOI

      10.1002/aelm.201600557

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strain-Modulated Charge Transport in Flexible PbS Nanocrystal Field-Effect Transistors2017

    • Author(s)
      M. I. Nugraha, H. Matsui, S. Watanabe, T. Kubo, R. Häusermann, S. Z. Bisri, M. Sytnyk, W. Heiss, M. A. Loi, and J. Takeya
    • Journal Title

      Adv. Electron. Mater

      Volume: 3 Issue: 1 Pages: 1600360-1600360

    • DOI

      10.1002/aelm.201600360

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Tunable doping in PbS nanocrystal field-effect transistors using surface molecular dipoles2016

    • Author(s)
      M. I. Nugraha, H. Matsui, S. Z. Bisri, M. Sytnyk, W. Heiss, M. A. Loi, J. Takeya
    • Journal Title

      APL Materials

      Volume: 4 Issue: 11 Pages: 116105-116105

    • DOI

      10.1063/1.4966208

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Printed 2 V-operating organic inverter arrays employing a small-molecule/polymer blend2016

    • Author(s)
      R. Shiwaku, Y. Takeda, T. Fukuda, K. Fukuda, H. Matsui, D. Kumaki, S. Tokito
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 34723-34723

    • DOI

      10.1038/srep34723

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Suppressing molecular vibrations in organic semiconductors by inducing strain2016

    • Author(s)
      T. Kubo, R. Haeusermann, J. Tsurumi, J. Soeda, Y. Okada, Y. Yamashita, N. Akamatsu, A. Shishido, C. Mitsui, T. Okamoto, S. Yanagisawa, H. Matsui, and J. Takeya
    • Journal Title

      Nature Communications

      Volume: 7 Issue: 1 Pages: 11156-11156

    • DOI

      10.1038/ncomms11156

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Emergence of charge coherence in soft molecular organic semiconductors by suppressing thermal fluctuations2016

    • Author(s)
      K. Sakai, Y. Okada, T. Uemura, J. Tsurumi, R. Hausermann, H. Matsui, T. Fukami, H. Ishii, N. Kobayashi, K. Hirose and J. Takeya
    • Journal Title

      NPG Asia Materials

      Volume: 8 Issue: 3 Pages: 252-252

    • DOI

      10.1038/am.2016.30

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mobility Exceeding 10 cm2/(Vs) in Donor–Acceptor Polymer Transistors with Band-like Charge Transport2015

    • Author(s)
      Yu Yamashita, Felix Hinkel, Tomasz Marszalek, Wojciech Zajaczkowski, Wojciech Pisula, Martin Baumgarten, Hiroyuki Matsui, Klaus Mullen, and Jun Takeya
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 2 Pages: 420-424

    • DOI

      10.1021/acs.chemmater.5b04567

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] ギャップ内準位による有機トランジスタのターンオン電圧制御2018

    • Author(s)
      松井 弘之, 時任 静士
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Systematic Study ofBand Calculations and Experimentsfor High-MobilityOrganic Semiconductor Materials2018

    • Author(s)
      Hiroyuki Matsui
    • Organizer
      Bridging the Scales in Soft Matter Simulations
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 印刷法による有機トランジスタの集積回路応用2017

    • Author(s)
      松井 弘之, 塩飽 黎, 時任 静士
    • Organizer
      新化学技術推進協会電子情報技術部会・次世代エレクトロニクス分科会講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] パルス幅変調を用いた有機非接触IC タグの設計と実現可能性の検証2017

    • Author(s)
      松井 弘之, 竹田 泰典, 早坂 和将, 横澤 晃二, 田中 康裕, 芝 健夫, 熊木 大介, 時任 静士
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ウェアラブルデバイスに向けた省電力有機トランジスタ回路2017

    • Author(s)
      松井 弘之
    • Organizer
      2017有機エレクトロニクス講習会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 印刷型有機TFTと集積回路応用2017

    • Author(s)
      松井 弘之
    • Organizer
      第4回フレキシブル有機エレクトロニクス研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 有機エレクトロニクスの誕生から近年の応用事例まで2017

    • Author(s)
      松井 弘之
    • Organizer
      アース研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] インクジェット印刷電極を用いた5 V駆動有機オペアンプの開発2017

    • Author(s)
      松井弘之, 早坂和将, 竹田泰典, 塩飽黎,Kwon Jimin, Jung Sungjune, 田中康裕, 時任静士
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県、横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 印刷技術で作製した超低電圧駆動有機インバータ回路2017

    • Author(s)
      塩飽黎, 松井弘之, 早坂和将, 竹田泰典, 福田貴, 熊木大介, 時任静士
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県、横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 凸版反転印刷電極による有機トランジスタの作製と相補型集積回路応用2017

    • Author(s)
      竹田泰典, 早坂和将, 塩飽黎, 吉村悠大, 岡本朋子, 田中康裕, 松井弘之, 熊木大介, 片山嘉則, 時任静士
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県、横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 印刷型有機Dフリップフロップの動的特性解析とその回路応用2017

    • Author(s)
      早坂和将, 松井弘之, 竹田泰典, 塩飽黎, 田中康裕, 芝健夫, 熊木大介, 時任静士
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県、横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分子性ドーピングによる導電性ポリマーのバンド伝導性の評価2016

    • Author(s)
      藤本亮
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      仙台
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Hall effect and band-like carrier transport in high mobility polymer transistors2016

    • Author(s)
      Yu Yamashita
    • Organizer
      APS March Meeting 2016
    • Place of Presentation
      Baltimore, USA
    • Year and Date
      2016-03-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Fully-printed Organic Thin-film Transistors using Donor/acceptor Type Polymer Semiconductor2016

    • Author(s)
      Tomohide Murase, Noriyuki Kida, Rei Shiwaku, Hiroyuki Matsui, Daisuke Kumaki, and Shizuo Tokito
    • Organizer
      ICFPE 2016
    • Place of Presentation
      山形大学(山形県、米沢市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Printed Organic D-Flipflops with Compact Design2016

    • Author(s)
      Kazuma Hayasaka, Hiroyuki Matsui, Yasunori Takeda, Rei Shiwaku, Yasuhiro Tanaka, Takeo Shiba, Daisuke Kumaki, Shizuo Tokito
    • Organizer
      ICFPE 2016
    • Place of Presentation
      山形大学(山形県、米沢市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hybrid Complementary D-Flipflops of Carbon Nanotubes and Organic Semiconductors2016

    • Author(s)
      Hiroyuki Matsui, Vladimir Derenskyi, Jorge Mario Salazar-Rios, Artem Shulga, Widianta Gomulya, Shinji Kishimura, Jun Takeya, Maria Antonietta Loi
    • Organizer
      ICFPE 2016
    • Place of Presentation
      山形大学(山形県、米沢市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Overview of Organic Transistors: From Device Physics to Applications2015

    • Author(s)
      Hiroyuki Matsui
    • Organizer
      IEEE/ACM Workshop on Variability Modeling and Characterization (VMC) 2015
    • Place of Presentation
      Austin, USA
    • Year and Date
      2015-11-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 松井研究室

    • URL

      http://matsui-lab.yz.yamagata-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://matsui-lab.yz.yamagata-u.ac.jp/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2020-05-15  

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