Elucidating key factors of coherent conduction in polymer semiconductors and modeling of the conduction mechanisms

• Project/Area Number: 15H05455
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Condensed matter physics II
• Research Institution: Yamagata University (2016-2017); The University of Tokyo (2015)
• Principal Investigator: Matsui Hiroyuki 山形大学, 大学院有機材料システム研究科, 准教授 (80707357)
• Project Period (FY): 2015-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000); Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000); Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2015: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
• Keywords: 有機電界効果トランジスタ / ポリマー半導体 / バンド伝導 / OFETs / OTFTs / polymer semiconductors / band transport / 有機半導体 / 高分子半導体 / ホール効果 / バンド計算 / 有効質量 / 電子スピン共鳴 / 高配向性薄膜 / イオン液体 / 高移動度

Outline of Final Research Achievements

Polymer semiconductor, in which conjugated organic molecules are polymerized, is an electronic material excellent in solubility, homogeneous film formation by solution processes, low temperature processability, and mechanical flexibility. However, having many structural disorders and defects, polymer semiconductor had been believed to follow hopping transport model, where the maximum mobility is at most several cm2/Vs. In this study, we have clarified that band transport can be realized in some polymer semiconductors by the measurements of mobility exceeding 10 cm2/Vs, its temperature dependence and Hall effect. The relationship between structure and band conduction was also analyzed in detail.

Research Products

• [Journal Article] One step facile synthesis of a novel anthanthrone dye-based, dopant-free hole transporting material for efficient and stable perovskite solar cells (2018)
  • Author(s): H. D. Pham, K. Hayasake, J. Kim, T. T. Do, H. Matsui, S. Manzhos, K. Feron, S. Tokito, T. Watson, W. C. Tsoi, N. Motta, J. R. Durrant, S. M. Jain, P. Sonar
  • Journal Title: J. Mater. Chem. C Volume: 6 Issue: 14 Pages: 3699-3708
  • DOI: 10.1039/c7tc05238c
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] A Printed Organic Amplification System for Wearable Potentiometric Electrochemical Sensors (2018)
  • Author(s): R. Shiwaku, H. Matsui, K. Nagamine, M. Uematsu, T. Mano, Y. Maruyama, A. Nomura, K. Tsuchiya, K. Hayasaka, Y. Takeda, T. Fukuda, D. Kumaki, S. Tokito
  • Journal Title: Sci. Rep. Volume: 8 Issue: 1 Pages: 3822-3822
  • DOI: 10.1038/s41598-018-22265-1
  • Peer Reviewed / Open Access
• [Journal Article] Switching Time in Ferroelectric Organic Field-Effect Transistors (2018)
  • Author(s): R. Sugano, T. Tashiro, T. Sekine, H. Matsui, D. Kumaki, F. D. D. Santos, A. Miyabo, S. Tokito
  • Journal Title: Physica Status Solidi (a) Volume: 印刷中 Issue: 11
  • DOI: 10.1002/pssa.201701059
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Fully Printed Wearable Vital Sensor for Human Pulse Rate Monitoring using Ferroelectric Polymer (2018)
  • Author(s): T. Sekine, R. Sugano, T. Tashiro, J. Sato, Y. Takeda, H. Matsui, D. Kumaki, F. D. D. Santos, A. Miyabo, S. Tokito
  • Journal Title: Sci. Rep. Volume: 8 Issue: 1 Pages: 4442-4442
  • DOI: 10.1038/s41598-018-22746-3
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] A Printed Organic Circuit System for Wearable Amperometric Electrochemical Sensors (2018)
  • Author(s): R. Shiwaku, H. Matsui, K. Nagamine, M. Uematsu, T. Mano, Y. Maruyama, A. Nomura, K. Tsuchiya, K. Hayasaka, Y. Takeda, T. Fukuda, D. Kumaki, S. Tokito
  • Journal Title: Sci. Rep. Volume: 8 Issue: 1 Pages: 6368-6368
  • DOI: 10.1038/s41598-018-24744-x
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Painting Integrated Complementary Logic Circuits for Single-Crystal Organic Transistors: A Demonstration of a Digital Wireless Communication Sensing Tag (2017)
  • Author(s): A. Yamamura, H. Matsui, M. Uno, N. Isahaya, Y. Tanaka, M. Kudo, M. Ito, C. Mitsui, T. Okamoto, J. Takeya
  • Journal Title: Adv. Electron. Mater. Volume: 3 Issue: 7 Pages: 1600456-1600456
  • DOI: 10.1002/aelm.201600456
  • Peer Reviewed
• [Journal Article] Control of molecular doping in conjugated polymers by thermal annealing (2017)
  • Author(s): R. Fujimoto, S. Watanabe, Y. Yamashita, J. Tsurumi, H. Matsui, T. Kushida, C. Mitsui, H. T. Yi, V. Podzorov, J. Takeya
  • Journal Title: Org. Electron. Volume: 47 Pages: 139-146
  • DOI: 10.1016/j.orgel.2017.05.019
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Coexistence of ultra-long spin relaxation time and coherent charge transport in organic single-crystal semiconductors (2017)
  • Author(s): Junto Tsurumi, Hiroyuki Matsui, Takayoshi Kubo, Roger Hausermann, Chikahiko Mitsui, Toshihiro Okamoto, Shun Watanabe, and Jun Takeya,
  • Journal Title: Nature Physics Volume: 13 Issue: 10 Pages: 994-998
  • DOI: 10.1038/nphys4217
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Boron-Stabilized Planar Neutral π-Radicals with Well-Balanced Ambipolar Charge-Transport Properties (2017)
  • Author(s): Kushida Tomokatsu、Shirai Shusuke、Ando Naoki、Okamoto Toshihiro、Ishii Hiroyuki、Matsui Hiroyuki、Yamagishi Masakazu、Uemura Takafumi、Tsurumi Junto、Watanabe Shun、Takeya Jun、Yamaguchi Shigehiro
  • Journal Title: J. Am. Chem. Soc. Volume: 139 Issue: 41 Pages: 14336-14339
  • DOI: 10.1021/jacs.7b05471
  • Peer Reviewed
• [Journal Article] Compactly Designed Organic Complementary D-Type Flip-Flop Circuits Fabricated with Inkjet Printing (2017)
  • Author(s): K. Hayasaka, H. Matsui, Y. Takeda, R. Shiwaku, Y. Tanaka, T. Shiba, D. Kumaki, S. Tokito
  • Journal Title: Adv. Electron. Mater. Volume: 3 Issue: 9 Pages: 1700208-1700208
  • DOI: 10.1002/aelm.201700208
  • Peer Reviewed
• [Journal Article] Organic Complementary Inverter Circuits Fabricated with Reverse Offset Printing (2017)
  • Author(s): Y. Takeda, Y. Yoshimura, R. Shiwaku, K. Hayasaka, T. Sekine, T. Okamoto, H. Matsui, D. Kumaki, Y. Katayama, S. Tokito
  • Journal Title: Adv. Electron. Mater. Volume: 4 Issue: 1 Pages: 1700313-1700313
  • DOI: 10.1002/aelm.201700313
  • Peer Reviewed
• [Journal Article] Uniform, high performance, solution processed organic thin-film transistors integrated in 1 MHz frequency ring oscillators (2017)
  • Author(s): S. D. Ogier, H. Matsui, LinrunFengaMikeSimmsa, M. Mashayekhi, J. Carrabina, L. Teres, S. Tokito
  • Journal Title: Org. Electron. Volume: 54 Pages: 40-47
  • DOI: 10.1016/j.orgel.2017.12.005
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Printed Organic Inverter Circuits with Ultralow Operating Voltages (2017)
  • Author(s): Rei Shiwaku, Hiroyuki Matsui,* Kazuma Hayasaka, Yasunori Takeda, Takashi Fukuda, Daisuke Kumaki, and Shizuo Tokito*
  • Journal Title: Advanced Electronic Materials Volume: - Issue: 5
  • DOI: 10.1002/aelm.201600557
  • Peer Reviewed
• [Journal Article] Strain-Modulated Charge Transport in Flexible PbS Nanocrystal Field-Effect Transistors (2017)
  • Author(s): M. I. Nugraha, H. Matsui, S. Watanabe, T. Kubo, R. Häusermann, S. Z. Bisri, M. Sytnyk, W. Heiss, M. A. Loi, and J. Takeya
  • Journal Title: Adv. Electron. Mater Volume: 3 Issue: 1 Pages: 1600360-1600360
  • DOI: 10.1002/aelm.201600360
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Tunable doping in PbS nanocrystal field-effect transistors using surface molecular dipoles (2016)
  • Author(s): M. I. Nugraha, H. Matsui, S. Z. Bisri, M. Sytnyk, W. Heiss, M. A. Loi, J. Takeya
  • Journal Title: APL Materials Volume: 4 Issue: 11 Pages: 116105-116105
  • DOI: 10.1063/1.4966208
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Printed 2 V-operating organic inverter arrays employing a small-molecule/polymer blend (2016)
  • Author(s): R. Shiwaku, Y. Takeda, T. Fukuda, K. Fukuda, H. Matsui, D. Kumaki, S. Tokito
  • Journal Title: Scientific Reports Volume: 6 Issue: 1 Pages: 34723-34723
  • DOI: 10.1038/srep34723
  • Peer Reviewed
• [Journal Article] Suppressing molecular vibrations in organic semiconductors by inducing strain (2016)
  • Author(s): T. Kubo, R. Haeusermann, J. Tsurumi, J. Soeda, Y. Okada, Y. Yamashita, N. Akamatsu, A. Shishido, C. Mitsui, T. Okamoto, S. Yanagisawa, H. Matsui, and J. Takeya
  • Journal Title: Nature Communications Volume: 7 Issue: 1 Pages: 11156-11156
  • DOI: 10.1038/ncomms11156
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Emergence of charge coherence in soft molecular organic semiconductors by suppressing thermal fluctuations (2016)
  • Author(s): K. Sakai, Y. Okada, T. Uemura, J. Tsurumi, R. Hausermann, H. Matsui, T. Fukami, H. Ishii, N. Kobayashi, K. Hirose and J. Takeya
  • Journal Title: NPG Asia Materials Volume: 8 Issue: 3 Pages: 252-252
  • DOI: 10.1038/am.2016.30
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Mobility Exceeding 10 cm2/(Vs) in Donor–Acceptor Polymer Transistors with Band-like Charge Transport (2015)
  • Author(s): Yu Yamashita, Felix Hinkel, Tomasz Marszalek, Wojciech Zajaczkowski, Wojciech Pisula, Martin Baumgarten, Hiroyuki Matsui, Klaus Mullen, and Jun Takeya
  • Journal Title: Chemistry of Materials Volume: 28 Issue: 2 Pages: 420-424
  • DOI: 10.1021/acs.chemmater.5b04567
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Presentation] ギャップ内準位による有機トランジスタのターンオン電圧制御 (2018)
  • Author(s): 松井 弘之, 時任 静士
  • Organizer: 第65回応用物理学会春季学術講演会
• [Presentation] Systematic Study ofBand Calculations and Experimentsfor High-MobilityOrganic Semiconductor Materials (2018)
  • Author(s): Hiroyuki Matsui
  • Organizer: Bridging the Scales in Soft Matter Simulations
  • Int'l Joint Research / Invited
• [Presentation] 印刷法による有機トランジスタの集積回路応用 (2017)
  • Author(s): 松井 弘之, 塩飽 黎, 時任 静士
  • Organizer: 新化学技術推進協会電子情報技術部会・次世代エレクトロニクス分科会講演会
  • Invited
• [Presentation] パルス幅変調を用いた有機非接触IC タグの設計と実現可能性の検証 (2017)
  • Author(s): 松井 弘之, 竹田 泰典, 早坂 和将, 横澤 晃二, 田中 康裕, 芝 健夫, 熊木 大介, 時任 静士
  • Organizer: 第78回応用物理学会秋季学術講演会
• [Presentation] ウェアラブルデバイスに向けた省電力有機トランジスタ回路 (2017)
  • Author(s): 松井 弘之
  • Organizer: 2017有機エレクトロニクス講習会
  • Invited
• [Presentation] 印刷型有機TFTと集積回路応用 (2017)
  • Author(s): 松井 弘之
  • Organizer: 第4回フレキシブル有機エレクトロニクス研究会
  • Invited
• [Presentation] 有機エレクトロニクスの誕生から近年の応用事例まで (2017)
  • Author(s): 松井 弘之
  • Organizer: アース研究会
  • Invited
• [Presentation] インクジェット印刷電極を用いた5 V駆動有機オペアンプの開発 (2017)
  • Author(s): 松井弘之, 早坂和将, 竹田泰典, 塩飽黎,Kwon Jimin, Jung Sungjune, 田中康裕, 時任静士
  • Organizer: 第64回応用物理学会春季学術講演会
  • Place of Presentation: パシフィコ横浜（神奈川県、横浜市）
• [Presentation] 印刷技術で作製した超低電圧駆動有機インバータ回路 (2017)
  • Author(s): 塩飽黎, 松井弘之, 早坂和将, 竹田泰典, 福田貴, 熊木大介, 時任静士
  • Organizer: 第64回応用物理学会春季学術講演会
  • Place of Presentation: パシフィコ横浜（神奈川県、横浜市）
• [Presentation] 凸版反転印刷電極による有機トランジスタの作製と相補型集積回路応用 (2017)
  • Author(s): 竹田泰典, 早坂和将, 塩飽黎, 吉村悠大, 岡本朋子, 田中康裕, 松井弘之, 熊木大介, 片山嘉則, 時任静士
  • Organizer: 第64回応用物理学会春季学術講演会
  • Place of Presentation: パシフィコ横浜（神奈川県、横浜市）
• [Presentation] 印刷型有機Dフリップフロップの動的特性解析とその回路応用 (2017)
  • Author(s): 早坂和将, 松井弘之, 竹田泰典, 塩飽黎, 田中康裕, 芝健夫, 熊木大介, 時任静士
  • Organizer: 第64回応用物理学会春季学術講演会
  • Place of Presentation: パシフィコ横浜（神奈川県、横浜市）
• [Presentation] 分子性ドーピングによる導電性ポリマーのバンド伝導性の評価 (2016)
  • Author(s): 藤本亮
  • Organizer: 日本物理学会第71回年次大会
  • Place of Presentation: 仙台
  • Year and Date: 2016-03-21
• [Presentation] Hall effect and band-like carrier transport in high mobility polymer transistors (2016)
  • Author(s): Yu Yamashita
  • Organizer: APS March Meeting 2016
  • Place of Presentation: Baltimore, USA
  • Year and Date: 2016-03-18
  • Int'l Joint Research
• [Presentation] Fabrication of Fully-printed Organic Thin-film Transistors using Donor/acceptor Type Polymer Semiconductor (2016)
  • Author(s): Tomohide Murase, Noriyuki Kida, Rei Shiwaku, Hiroyuki Matsui, Daisuke Kumaki, and Shizuo Tokito
  • Organizer: ICFPE 2016
  • Place of Presentation: 山形大学（山形県、米沢市）
  • Int'l Joint Research
• [Presentation] Printed Organic D-Flipflops with Compact Design (2016)
  • Author(s): Kazuma Hayasaka, Hiroyuki Matsui, Yasunori Takeda, Rei Shiwaku, Yasuhiro Tanaka, Takeo Shiba, Daisuke Kumaki, Shizuo Tokito
  • Organizer: ICFPE 2016
  • Place of Presentation: 山形大学（山形県、米沢市）
  • Int'l Joint Research
• [Presentation] Hybrid Complementary D-Flipflops of Carbon Nanotubes and Organic Semiconductors (2016)
  • Author(s): Hiroyuki Matsui, Vladimir Derenskyi, Jorge Mario Salazar-Rios, Artem Shulga, Widianta Gomulya, Shinji Kishimura, Jun Takeya, Maria Antonietta Loi
  • Organizer: ICFPE 2016
  • Place of Presentation: 山形大学（山形県、米沢市）
  • Int'l Joint Research
• [Presentation] Overview of Organic Transistors: From Device Physics to Applications (2015)
  • Author(s): Hiroyuki Matsui
  • Organizer: IEEE/ACM Workshop on Variability Modeling and Characterization (VMC) 2015
  • Place of Presentation: Austin, USA
  • Year and Date: 2015-11-05
  • Int'l Joint Research / Invited
• [Remarks] 松井研究室
  • URL: http://matsui-lab.yz.yamagata-u.ac.jp/
• [Remarks]
  • URL: http://matsui-lab.yz.yamagata-u.ac.jp/