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Stability of hydrous phase H and water behavior in the lower mantle

Research Project

Project/Area Number 15H05469
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Petrology/Mineralogy/Economic geology
Research InstitutionEhime University

Principal Investigator

Nishi Masayuki  愛媛大学, 地球深部ダイナミクス研究センター, 講師 (10584120)

Project Period (FY) 2015-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥22,100,000 (Direct Cost: ¥17,000,000、Indirect Cost: ¥5,100,000)
Fiscal Year 2018: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2017: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Keywords含水鉱物 / 地球深部水 / マルチアンビル装置 / 高圧実験 / ダイヤモンドアンビルセル / 下部マントル / 地球・惑星内部構造 / マントル / 核 / 水素 / 高圧 / 中心核 / 含水相 / 高温高圧実験 / 焼結ダイヤモンドアンビル / 沈み込むプレート / 相転移 / 高温高圧
Outline of Final Research Achievements

Several recent studies have reported hydrous minerals to be stable at pressure and temperature conditions representative of Earth’s deep interior, implying that surface water may be transported to the deep mantle. However,the dehydration decomposition of hydrous minerals generally occurs at pressures before reaching those corresponding to the deep lower mantle. In this study, stabilities of hydrous phases, FeOOH and AlOOH, have been studied at the pressure and temperature conditions of the deep lower mantle, based on first-principles calculations and in situ X-ray diffraction experiments. The formation of a new FeOOH and AlOOH phases, which are stable at the conditions of the base of the mantle, have been observed.

Academic Significance and Societal Importance of the Research Achievements

本研究結果は、含水鉱物が地球マントルの深部環境で分解するという従来の学説を覆す発見であり、いまだに解明されていない地球深部における水の循環を明らかにするための新たな知見となると期待される。本研究結果によると、水は地表からマントルと地球中心核の境界付近の 2,900km程度の深さまで運ばれる可能性がり、この領域で水がどのようなふるまいをするかが盛んに研究され始めている。

Report

(5 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (22 results)

All 2018 2017 2016 2015

All Journal Article (10 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 10 results,  Open Access: 7 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 7 results,  Invited: 5 results)

  • [Journal Article] Thermal equation of state of MgSiO4H2 phase H determined by in situ X-ray diffraction and a multianvil apparatus2018

    • Author(s)
      Nishi, M., Tsuchiya, J., Arimoto, T., Kakizawa, S., Kunimoto, T., Tange, Y., Higo, Y. and Irifune, T.
    • Journal Title

      Physics and Chemistry of Minerals

      Volume: 45(10) Issue: 10 Pages: 995-1001

    • DOI

      10.1007/s00269-018-0980-z

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] High-pressure phase relation of KREEP basalts: A clue for finding the lost Hadean crust?2018

    • Author(s)
      Greaux S., Nishi M., Tateno S., Kuwayama Y., Hirao N,, Kawai K., Maruyama S., Irifune T.
    • Journal Title

      Physics of the Earth and Planetary Interiors

      Volume: 274 Pages: 184-194

    • DOI

      10.1016/j.pepi.2017.12.004

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] High-pressure phase transitions of anorthosite crust in the Earth’s deep mantle2017

    • Author(s)
      Nishi M., Greaux S., Tateno S., Kuwayama Y., Kawai K., Irifune T., Maruyama S.
    • Journal Title

      Geoscience Frontiers

      Volume: in press Issue: 6 Pages: 1-13

    • DOI

      10.1016/j.gsf.2017.10.002

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] The pyrite-type high-pressure form of FeOOH2017

    • Author(s)
      Nishi Masayuki、Kuwayama Yasuhiro、Tsuchiya Jun、Tsuchiya Taku
    • Journal Title

      Nature

      Volume: 547 Issue: 7662 Pages: 205-208

    • DOI

      10.1038/nature22823

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Phase Relations in the System MgSiO3‐Al2O3 up to 2300 K at Lower Mantle Pressures2017

    • Author(s)
      Zhaodong Liu, Masayuki Nishi, Takayuki Ishii, Hongzhan Fei, Nobuyoshi Miyajima, Tiziana Boffa Ballaran, Hiroaki Ohfuji, Takeshi Sakai, Lin Wang, Svyatoslav Shcheka, Takeshi Arimoto, Yoshinori Tange, Yuji Higo, Tetsuo Irifune, Tomoo Katsura
    • Journal Title

      Journal of Geophysical Research: Solid Earth

      Volume: 122 Issue: 10 Pages: 7775-7788

    • DOI

      10.1002/2017jb014579

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Melting temperatures of MgO under high pressure by micro-texture analysis2017

    • Author(s)
      T. Kimura, H. Ohfuji, M. Nishi, T. Irifune
    • Journal Title

      Nature communications

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The pyrite-type high-pressure form of FeOOH2017

    • Author(s)
      M. Nishi, Y. Kuwayama, J. Tsuchiya, T. Tsuchiya
    • Journal Title

      Nature

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Growth kinetics of forsterite reaction rims at high-pressure2016

    • Author(s)
      Y. Nishihara, G. Maruyama, M. Nishi
    • Journal Title

      Physics of the Earth and Planetary Interiors

      Volume: 257 Pages: 220-229

    • DOI

      10.1016/j.pepi.2016.06.008

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Partition of al between phase D and phase H at high pressure: Results from a simultaneous structure refinement of the two phases coexisting in an unique grain2015

    • Author(s)
      L. Bindi, M. Nishi, and T. Irifune
    • Journal Title

      American Mineralogist

      Volume: 100(7) Issue: 7 Pages: 1637-1640

    • DOI

      10.2138/am-2015-5327

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Phase transitions of serpentine in the lower mantle2015

    • Author(s)
      Nishi, N., T. Irifune, S. Greaux, Y. Tange, and Y. Higo
    • Journal Title

      Phys. Earth Planet. Inter.

      Volume: 245 Pages: 52-58

    • DOI

      10.1016/j.pepi.2015.05.007

    • NAID

      130007617602

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Thermal equations of state of MgSiO4H2 phase H up to 63 GPa determined by in situ X-ray diffraction measurement in a multianvil apparatus2018

    • Author(s)
      西真之、土屋旬、有本岳史、柿澤翔、國本健広、丹下慶範、肥後祐司、入舩徹男
    • Organizer
      日本地球惑星科学連合2018年大会
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 地球惑星深部における水酸化物の高圧相転移2018

    • Author(s)
      西真之,桑山靖弘,土屋旬,丹下慶範,入舩徹男
    • Organizer
      第59回高圧討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Thermal equations of state of MgSiO4H2 phase H2018

    • Author(s)
      Nishi, M., Tsuchiya, J., Arimoto, T., Kakizawa, S., Kunimoto, T., Tange, Y., Higo Y., Irifune, T.
    • Organizer
      Interaction and Coevolution of the Core and Mantle Toward Integrated Deep Earth Science, International Symposium FY2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-pressure phase transitions in AlOOH and FeOOH2017

    • Author(s)
      Nishi, M., Kuwayama, Y., Tsuchiya, J., Tsuchiya, T. and Irifune, T.
    • Organizer
      High-Pressure Mineral Physics Seminar (HPMPS-9)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] The high-pressure phase transitions of hydroxides2017

    • Author(s)
      Nishi, M., Kuwayama, Y., Tsuchiya, J., Tsuchiya, T. and Irifune, T.
    • Organizer
      AGU Fall Meeting, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] First principles investigation of the high-pressure behavior of the FeOOH-AlOOH-phase H (MgSiO4H2) system2017

    • Author(s)
      Tsuchiya, J., Thompson, E. C., Tsuchiya, T., Nishi, M. and Kuwayama, Y.
    • Organizer
      Association of Geodesy and the International Association of Seismology and Physics of the Earth's Interior, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] First principles investigation of high pressure behavior of FeOOH-AlOOH-phase H (MgSiO4H2) system2017

    • Author(s)
      Tsuchiya, J., Thompson, E. C., Tsuchiya, T., Nishi, M. and Kuwayama, Y
    • Organizer
      AGU Fall Meeting, 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マントル遷移層の非平衡鉱物構成2017

    • Author(s)
      西真之,入舩徹男
    • Organizer
      第58回高圧討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Experimental investigation of high-pressure phase transitions in AlOOH and FeOOH2017

    • Author(s)
      西真之,桑山靖弘,土屋旬,土屋卓久
    • Organizer
      日本地球惑星科学連合会大会, 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] In-situ X-ray diffraction studies of hydrous phases up to ~50 GPa2016

    • Author(s)
      西真之,入舩徹男, 土屋旬, 有本岳史, 柿澤翔, 丹下慶範
    • Organizer
      日本地球惑星科学連合2016年大会
    • Place of Presentation
      幕張メッセ国際会議場・千葉県・千葉市
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] The stability of Al,Fe-bearing phase H and a new pyrite-type hydroxide at high pressures2015

    • Author(s)
      Masayuki Nishi, Yasuhiro Kuwayama, Jun Tsuchiya, Tetsuo Irifune
    • Organizer
      AGU fall meeting 2015
    • Place of Presentation
      サンフランシスコ(米国)
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高温高圧条件下におけるAlOOHのパイライト構造への相転移2015

    • Author(s)
      西真之,桑山靖弘,土屋旬
    • Organizer
      第56回高圧討論会
    • Place of Presentation
      JMSアステールプラザ(広島県・広島市)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report

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Published: 2015-04-16   Modified: 2020-03-30  

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