| Budget Amount *help |
¥24,310,000 (Direct Cost: ¥18,700,000、Indirect Cost: ¥5,610,000)
Fiscal Year 2018: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2017: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
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| Outline of Final Research Achievements |
It is well-known that the structure and nature of reaction field created around the reactive sites play important role on the excellent catalytic activity of natural enzymes. In this research project, we aimed to construct framework catalysts, which is formed by the self-assembly of catalyst modules with inter-molecular interaction sites. In particular, we developed new catalyst modules which have coordinatively unsaturated sites (open-metal sites) and non-covalent interaction sites and successfully constructed novel porous structures. We also unveiled the physical proprieties and reactivities of the obtained frame work catalysts.
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