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Precision supramolecular polymerization under kinetic control

Research Project

Project/Area Number 15H05483
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional solid state chemistry
Research InstitutionNational Institute for Materials Science

Principal Investigator

Sugiyasu Kazunori  国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 主幹研究員 (80469759)

Research Collaborator FUKUI Tomoya  
SASAKI Norihiko  
Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥25,090,000 (Direct Cost: ¥19,300,000、Indirect Cost: ¥5,790,000)
Fiscal Year 2017: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2016: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2015: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Keywords超分子ポリマー / 精密超分子重合 / ポルフィリン / アゾベンゼン / 自己集合 / 超分子化学 / 精密重合
Outline of Final Research Achievements

In this research program, we aimed at establishing a method that allows the precision supramolecular polymerization. As demonstrated in polymer chemistry, molecular weight (or length) of a polymer is one of the most fundamental structural parameters that determine function and property of polymeric materials.
During the last two years, we have succeeded in (1) controlled supramolecular polymerization in two-dimension, and (2) photoregulated controlled supramolecular polymerization. Further studies on the structure-property relationship of the thus-obtained supramolecular polymers are expected to shed light on a new aspect of supramolecular polymeric materials.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (37 results)

All 2018 2017 2016 2015 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results) Presentation (26 results) (of which Int'l Joint Research: 7 results,  Invited: 17 results) Remarks (1 results)

  • [Int'l Joint Research] Universitat Wurzburg(ドイツ)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Autocatalytic Time-Dependent Evolution of Metastable Two-Component Supramolecular Assemblies to Self-Sorted or Coassembled State2017

    • Author(s)
      Fukui Tomoya、Takeuchi Masayuki、Sugiyasu Kazunori
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 1-7

    • DOI

      10.1038/s41598-017-02524-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Impact of a subtle structural difference on the kinetic behavior of metastable supramolecular assemblies2017

    • Author(s)
      Tomoya Fukui, Masayuki Takeuchi, Kazunori Sugiyasu
    • Journal Title

      Polymer

      Volume: 印刷中 Pages: 311-316

    • DOI

      10.1016/j.polymer.2016.12.027

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 光異性化を利用するリビング超分子重合2017

    • Author(s)
      杉安和憲
    • Journal Title

      日本化学会コロイド界面部会ニュースレター

      Volume: 42 Pages: 14-14

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 一次元にも二次元にもリビング超分子重合2017

    • Author(s)
      杉安和憲
    • Journal Title

      高分子

      Volume: 66 Pages: 667-667

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control over differentiation of a metastable supramolecular assembly in one and two dimensions2017

    • Author(s)
      T. Fukui, S. Kawai, S. Fujinuma, Y. Matsushita, T. Yasuda, T. Sakurai, S. Seki, M. Takeuchi, K. Sugiyasu
    • Journal Title

      Nature Chem.

      Volume: 9 Issue: 5 Pages: 493-499

    • DOI

      10.1038/nchem.2684

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoregulated Living Supramolecular Polymerization Established by Combining Energy Landscapes of Photoisomerization and Nucleation Elongation Processes2016

    • Author(s)
      M. Endo, T. Fukui, S. Jung, S. Yagai, M. Takeuchi, K. Sugiyasu
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 43 Pages: 14347-14353

    • DOI

      10.1021/jacs.6b08145

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Supramolecular Assembly that Propagates Like Amyloid Fibrils: Elucidation of the Mechanism and Programming of the Time-Evolution2015

    • Author(s)
      福井智也,大城宗一郎,竹内正之,杉安和憲
    • Journal Title

      Seibutsu Butsuri

      Volume: 55 Issue: 3 Pages: 154-156

    • DOI

      10.2142/biophys.55.154

    • NAID

      130005072024

    • ISSN
      0582-4052, 1347-4219
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 超分子ポリマーの長さをそろえる2015

    • Author(s)
      杉安
    • Journal Title

      現代化学

      Volume: 9月号 Pages: 32-36

    • NAID

      40020555310

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Mechanism of Self-Assembly Process and Seeded Supramolecular Polymerization of Perylene Bisimide Organogelator2015

    • Author(s)
      S. Ogi, V. Stepanenko, K. Sugiyasu, M. Takeuchi, F. Wurthner
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 9 Pages: 3300-3307

    • DOI

      10.1021/ja511952c

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 高速AFMによる超分子重合のその場観察とマニピュレーション2018

    • Author(s)
      福井智也 内橋貴之 佐々木紀彦 渡辺大輝 竹内正之 杉安和憲
    • Organizer
      日本化学会 第98春季年会 (2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] フルオロアルキル基を修飾したポルフィリン誘導体の自己集合挙動2018

    • Author(s)
      佐々木紀彦 福井智也 竹内正之 杉安和憲
    • Organizer
      日本化学会 第98春季年会 (2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 時間発展する超分子集合体2018

    • Author(s)
      杉安和憲
    • Organizer
      日本化学会 第98春季年会 (2018)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 2種類のエネルギーランドスケープを重ね合わせて実現する光 リビング超分子重合2017

    • Author(s)
      杉安和憲・遠藤瑞紀・福井智也・ SungHo Jung・矢貝史樹・竹内正之
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      慶應大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Control over differentiation of a metastable supramolecular assembly in one- and two-dimensions2017

    • Author(s)
      FUKUI, Tomoya; TAKEUCHI, Masayuki; SUGIYASU, Kazunori
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      慶應大学日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Control over differentiation of a metastable supramolecular assembly in one- and two-dimensions2017

    • Author(s)
      T. Fukui, M. Takeuchi, K. Sugiyasu
    • Organizer
      新学術領域研究「動的秩序と機能」第5回国際シンポジウム
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2017-01-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoregulated Living Supramolecular Polymerization Established by Combining Energy Landscapes of Photoisomerization and Nucleation-Elongation Processes2017

    • Author(s)
      K. Sugiyasu, M. Endo, M. Takeuchi
    • Organizer
      新学術領域研究「動的秩序と機能」第5回国際シンポジウム
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2017-01-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 分化する超分子集合体:エネルギーランドスケープに基づく高次構造と機能の制御2016

    • Author(s)
      福井智也, 竹内正之, 杉安和憲
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2016-12-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分化する超分子集合体:エネルギーランドスケープに基づく高次構造の制御2016

    • Author(s)
      杉安和憲, 福井智也, 竹内正之
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分化する超分子集合体2016

    • Author(s)
      杉安和憲
    • Organizer
      新学術領域「動的秩序と機能」全体班会議
    • Place of Presentation
      長浜ロイヤルホテル
    • Year and Date
      2016-06-11
    • Related Report
      2016 Annual Research Report
  • [Presentation] 時間発展する超分子集合体2016

    • Author(s)
      杉安和憲
    • Organizer
      東京大学化学生命工学専攻 本郷談話会
    • Place of Presentation
      東京大学本郷キャンパス
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 時間発展する超分子集合体2016

    • Author(s)
      杉安和憲
    • Organizer
      錯体化学若手の会 関東支部勉強会
    • Place of Presentation
      早稲田大学
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 超分子化学的に精密設計された高分子 and vice versa2016

    • Author(s)
      杉安和憲
    • Organizer
      学術講演会
    • Place of Presentation
      鳥取大学
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Living supramolecualr polymerization2016

    • Author(s)
      K. Sugiyasu
    • Organizer
      Chemical and Biological Engineering Seminar
    • Place of Presentation
      Seoul National University
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Living supramolecualr polymerization2016

    • Author(s)
      K. Sugiyasu
    • Organizer
      ECNIS Symposium at Ewha
    • Place of Presentation
      Ewha Woman University
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Living supramolecualr polymerization2016

    • Author(s)
      K. Sugiyasu, S. Ogi, M. Takeuchi
    • Organizer
      YONSEI UNIVERSITY Chemistry Seminar
    • Place of Presentation
      YONSEI UNIVERSITY
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Living supramolecualr polymerization2016

    • Author(s)
      K. Sugiyasu
    • Organizer
      SUNGKYUNKWAN UNIVERSITY Department of Chemistry Seminar
    • Place of Presentation
      SUNGKYUNKWAN UNIVERSITY
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 超分子ポリマーの精密合成2015

    • Author(s)
      杉安 和憲
    • Organizer
      高分子講演会(東海)
    • Place of Presentation
      信州大学
    • Year and Date
      2015-12-18
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 絶縁被覆された共役系高分子の物性と機能2015

    • Author(s)
      杉安 和憲
    • Organizer
      高分子茨城地区講演会
    • Place of Presentation
      筑波大学
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Dynamic Ordering of Supramolecular Assemblies Developed on a Complex Energy Landscape2015

    • Author(s)
      K. Sugiyasu
    • Organizer
      4th International Symposium on Dynamical Ordering of Biomolecular Systems for Creation of Integrated Functions
    • Place of Presentation
      福岡
    • Year and Date
      2015-11-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 孤立化されたπ共役系高分子の物性と機能2015

    • Author(s)
      杉安 和憲
    • Organizer
      名古屋大学大学院理学研究科 学生セミナー
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-10-30
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Living Supramolecular Polymerization2015

    • Author(s)
      K. Sugiyasu
    • Organizer
      International Conference on Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2015-10-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Living Supramolecular Polymerization2015

    • Author(s)
      K. Sugiyasu
    • Organizer
      International Symposium for Photo- and Electro-Molecular Machine
    • Place of Presentation
      Toulouse
    • Year and Date
      2015-10-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Living Supramolecular Polymerization2015

    • Author(s)
      K. Sugiyasu
    • Organizer
      IMS Asian International Symposium, Institute for Molecular Science
    • Place of Presentation
      分子科学研究所
    • Year and Date
      2015-06-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 非平衡系を操る精密超分子重合2015

    • Author(s)
      杉安 和憲
    • Organizer
      15-1超分子研究会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Living Supramolecular Polymerization2015

    • Author(s)
      K. Sugiyasu, T. Fukui, S. Ogi, M. Takeuchi
    • Organizer
      π-System Figuration
    • Place of Presentation
      大阪 中之島
    • Year and Date
      2015-04-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] http://www.nims.go.jp/macromol/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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