| Budget Amount *help |
¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Fiscal Year 2017: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2016: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2015: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
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| Outline of Final Research Achievements |
Although a great advancement has been made in the development of acid-base organocatalysis in recent years, organocatalyzed redox reactions have less investigated. We interested in the redox ability (hypervalent ability) of iodine as an alternative to heavy metals and transition metals. We developed several redox organocatalysis for the highly efficient and selective oxidative transformations based on iodine chemistry. Importantly, the catalytic active species could be generated in situ from the corresponding stable and safe precursors (iodoarenes or onium iodides) in the presence of appropriate oxidants under environmentally friendly conditions.
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