| Budget Amount *help |
¥23,140,000 (Direct Cost: ¥17,800,000、Indirect Cost: ¥5,340,000)
Fiscal Year 2018: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2015: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
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| Outline of Final Research Achievements |
We have uniquely focused on the high potential of base metals and developed copper- and nickel-catalyzed highly selective carbon-carbon and carbon-nitrogen bond forming reactions via C-H bond cleavage. The newly developed base metal catalysis can replace the reported noble metals such as palladium and rhodium. Additionally, the aforementioned copper and nickel catalysis are found to promote some challenging C-H transformations even under noble metal catalysis. Moreover, we successfully prepare some nitrogen-containing, highly condensed pi-conjugated molecules, which are of high potential in material chemistry.
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