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Frontier of dynamic biomimetics based on the spatio-temporal structurization of block copolymers

Research Project

Project/Area Number 15H05495
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionNational Institute for Materials Science

Principal Investigator

UEKI Takeshi  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究員 (00557415)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥21,840,000 (Direct Cost: ¥16,800,000、Indirect Cost: ¥5,040,000)
Fiscal Year 2017: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2016: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2015: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
Keywords自己組織化 / ブロック共重合体 / ゲル / 化学振動反応 / 分子機械 / 複合材料・物性
Outline of Final Research Achievements

Block copolymers (BCPs) are macromoleucles that are made from incompatible polymer components covalently connected together, and form spatially regulated structure with the size range from nm to um under thermodynamically static states. In this research, we provided periodicity to such spatio-structure formed by BCP self-assembly and aimed to develop novel biomimetic materials that can express dynamic functions, usually observed in biological materials in nature. In particular, the transducer of the Belousov-Zhabotinsky (BZ) reaction, a well-known chemical oscillation reaction, was introduced into the chemical architecture of BCPs. By combining BCPs molecular platform that chemical energy from BZ reaction substances with mechanical energy of BCPs themselves, we proposed preparation of novel soft materials that could exhibit periodic oscillation of spatial scale ranging from nm to um.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (27 results)

All 2018 2017 2016 2015 Other

All Journal Article (19 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 19 results,  Open Access: 7 results,  Acknowledgement Compliant: 10 results) Presentation (4 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Macroscopic adhesion of thermoreversible ABC triblock copolymer-based hydrogels via boronic acid-sugar complexion2018

    • Author(s)
      Ryota Tamate, Kotomi Takahashi, Takeshi Ueki, Aya Mizutani Akimoto, Ryo Yoshida
    • Journal Title

      Macromol. Rapid Commun.

      Volume: 印刷中 Issue: 9

    • DOI

      10.1002/marc.201700835

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocurable ABA triblock copolymer-based ion gels utilizing photodimerization of coumarin2018

    • Author(s)
      Tamate Ryota、Ueki Takeshi、Akimoto Aya Mizutani、Yoshida Ryo、Oyama Toshiyuki、Kokubo Hisashi、Watanabe Masayoshi
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 7 Pages: 3418-3422

    • DOI

      10.1039/c7ra13181j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Thermosensitive Phase Separation Behavior of Poly(benzyl methacrylate)/Solvate Ionic Liquid Solutions2017

    • Author(s)
      Kobayashi Yumi、Kitazawa Yuzo、Hashimoto Kei、Ueki Takeshi、Kokubo Hisashi、Watanabe Masayoshi
    • Journal Title

      Langmuir

      Volume: 33 Issue: 49 Pages: 14105-14114

    • DOI

      10.1021/acs.langmuir.7b03378

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Substrate Concentrations on the Aggregation Behavior and Dynamic Oscillatory Properties of the Self-Oscillating Block Copolymers2017

    • Author(s)
      Tamate, R; Ueki, T; Shibayama, M; Yoshida, R.
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 31 Pages: 20627-20634

    • DOI

      10.1039/c7cp03969g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Microscopic Structure of Solvated Poly(benzyl methacrylate) in an Imidazolium-Based Ionic Liquid: High-Energy X-ray Total Scattering and All-Atom MD Simulation Study2017

    • Author(s)
      Fujii Kenta、Ueki Takeshi、Hashimoto Kei、Kobayashi Yumi、Kitazawa Yuzo、Hirosawa Kazu、Matsugami Masaru、Ohara Koji、Watanabe Masayoshi、Shibayama Mitsuhiro
    • Journal Title

      Macromolecules

      Volume: 50 Issue: 12 Pages: 4780-4786

    • DOI

      10.1021/acs.macromol.7b00840

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Amoeba-like self-oscillating polymeric fluids with autonomous sol-gel transition2017

    • Author(s)
      Onoda Michika、Ueki Takeshi、Tamate Ryota、Shibayama Mitsuhiro、Yoshida Ryo
    • Journal Title

      Nat. Commun.

      Volume: 8 Issue: 1 Pages: 15862-15862

    • DOI

      10.1038/ncomms15862

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Protic Ionic Liquids for the Belousov-Zhabotinsky Reaction: Aspects of the BZ Reaction in Protic Ionic Liquids and Its Use for the Autonomous Coil-Globule Oscillation of a Linear Polymer2017

    • Author(s)
      Takeshi Ueki, Ko Matsukawa, Tsukuru Masuda, Ryo Yoshida
    • Journal Title

      J. Phys. Chem. B

      Volume: 印刷中 Issue: 17 Pages: 4592-4599

    • DOI

      10.1021/acs.jpcb.7b01309

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Autonomous unimer-vesicle oscillation by totally synthetic diblock copolymers: effect of block length and polymer concentration on spatio-temporal structures2017

    • Author(s)
      R. Tamate, T. Ueki, M. Shibayama, R. Yoshida
    • Journal Title

      Soft Matter

      Volume: 印刷中 Issue: 26 Pages: 4559-4568

    • DOI

      10.1039/c7sm00563f

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Self-assembly of thermo-reversible hydrogels via molecular recognition toward a spatially organized co-culture system2017

    • Author(s)
      Ryota Tamate, Kotomi Takahashi, Takeshi Ueki, Aya Mizutani Akimoto, Ryo Yoshida
    • Journal Title

      Biomacromolecules

      Volume: 18 Issue: 1 Pages: 281-287

    • DOI

      10.1021/acs.biomac.6b01672

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Pressure Response of a Thermo-responsive Polymer in an Ionic Liquid2016

    • Author(s)
      Kazu Hirosawa, Kenta Fujii, Takeshi Ueki, Yuzo Kitazawa, Masayoshi Watanabe, Mitsuhiro Shibayama
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 21 Pages: 8249-8253

    • DOI

      10.1021/acs.macromol.6b01987

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanically tunable, readily processable ion gels by self-assembly of block copolymers in ionic liquids2016

    • Author(s)
      Timothy P. Lodge, Takeshi Ueki
    • Journal Title

      Acc. Chem. Res.

      Volume: 49 Issue: 10 Pages: 2107-2114

    • DOI

      10.1021/acs.accounts.6b00308

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Photo-dimerization induced dynamic viscoelastic changes in ABA triblock copolymer-based hydrogels for 3D cell culture2016

    • Author(s)
      Ryota Tamate, Takeshi Ueki, Yuzo Kitazawa, Morinobu Kuzunuki, Masayoshi Watanabe, Aya Mizutani Akimoto, Ryo Yoshida
    • Journal Title

      Chem. Mater.

      Volume: 28 Issue: 17 Pages: 6401-6408

    • DOI

      10.1021/acs.chemmater.6b02839

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] SANS study on the solvated structure and molecular interactions of a thermo-responsive polymer in a room temperature ionic liquid2016

    • Author(s)
      Kazu Hirosawa, Kenta Fujii, Takeshi Ueki, Yuzo Kitazawa, Kenneth C. Littrell, Masayoshi Watanabe, Mitsuhiro Shibayama
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 27 Pages: 17881-17889

    • DOI

      10.1039/c6cp02254e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evolved colloidosomes undergoing cell-like autonomous shape oscillations with buckling2016

    • Author(s)
      Ryota Tamate, Takeshi Ueki, Ryo Yoshida
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 17 Pages: 5179-5183

    • DOI

      10.1002/anie.201511871

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hierarchical sol-gel transition induced by thermo-sensitive self-assembly of an ABC triblock copolymer in an ionic liquid2016

    • Author(s)
      Yuzo Kitazawa, Takeshi Ueki, Lucas McIntosh, Saki Tamura, Kazuyuki Niitsuma, Satoru Imaizumi, Timothy P. Lodge, Masayoshi Watanabe
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 4 Pages: 1414-1423

    • DOI

      10.1021/acs.macromol.5b02616

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Direct visualization of swollen microgels via scanning electron microscopy using ionic liquids2016

    • Author(s)
      Koji Horigome, Takeshi Ueki, Daisuke Suzuki
    • Journal Title

      Polym. J.

      Volume: 48 Issue: 3 Pages: 273-279

    • DOI

      10.1038/pj.2015.103

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ABA triblock copolymer exhibiting spatio-temporal structure with autonomous viscosity oscillation2015

    • Author(s)
      Michika Onoda, Takeshi Ueki, Mitsuhiro Shibayama, Ryo Yoshida
    • Journal Title

      Sci. Rep.

      Volume: 5 Issue: 1 Pages: 15792-15792

    • DOI

      10.1038/srep15792

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Thermally reversible ion gels with photohealing properties based on triblock copolymer self-assembly2015

    • Author(s)
      Takeshi Ueki, Ryoji Usui, Yuzo Kitazawa, Timothy P. Lodge, Masayoshi Watanabe
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 16 Pages: 5928-5933

    • DOI

      10.1021/acs.macromol.5b01366

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Self-oscillating AB diblock copolymer developed by post modification strategy2015

    • Author(s)
      Takeshi Ueki, Michika Onoda, Ryota Tamate, Mitsuhiro Shibayama
    • Journal Title

      Chaos

      Volume: 25 Issue: 6 Pages: 064605-1

    • DOI

      10.1063/1.4921687

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ブロック共重合体の自己組織化 ー自己集合によるソフト材料と散逸構造を基盤とした動的バイオミメティクスー2017

    • Author(s)
      上木岳士
    • Organizer
      第6回山口大学生命分子インターネットワークセンターコロキウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Self-oscillating block copolymers2015

    • Author(s)
      Takeshi Ueki, Mitsuhiro Shibayama, Ryo Yoshida
    • Organizer
      14th Pacific Polymer Conference
    • Place of Presentation
      Kauai, Hawaii, USA
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] イオン液体とブロック共重合体を用いた自己組織化に関する研究2015

    • Author(s)
      上木岳士
    • Organizer
      第30回茨城地区「若手の会」
    • Place of Presentation
      つくば
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 自励振動ブロック共重合体の動的構造転移2015

    • Author(s)
      上木岳士、玉手亮多、小野田実真、柴山充弘、渡邉正義
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Book] 光二量化により粘弾性を変化できるABAトリブロックコポリマーを基盤とした動的ハイドロゲルの創製と三次元細胞培養への応用2017

    • Author(s)
      玉手亮多、上木岳士、北沢侑造、葛貫森信、渡邉正義、秋元文、吉田亮
    • Total Pages
      7
    • Publisher
      合成樹脂工業協会、ネットワークポリマー編集委員会
    • Related Report
      2016 Annual Research Report
  • [Book] "第2編 物質・材料設計 第7章 イオン液体中への高分子の溶解性と材料化” 「イオン液体研究最前線と社会実装」2016

    • Author(s)
      上木岳士、渡邉正義
    • Total Pages
      9
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Annual Research Report
  • [Book] ネットワークポリマー2016

    • Author(s)
      北沢侑造、上木岳士、小林優美、渡邉正義
    • Total Pages
      12
    • Publisher
      合成樹脂工業協会・ネットワークポリマー編集委員会
    • Related Report
      2015 Annual Research Report
  • [Remarks] NIMS研究者データベースSAMURAI

    • URL

      https://samurai.nims.go.jp/profiles/ueki_takeshi

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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