Challenges for complete demonstration of charge carrier transport states in organic semiconductors based on ultra-high sensitivity photoelectron detection
Project/Area Number |
15H05498
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Research Category |
Grant-in-Aid for Young Scientists (A)
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Allocation Type | Single-year Grants |
Research Field |
Device related chemistry
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Research Institution | Tokyo University of Science |
Principal Investigator |
Nakayama Yasuo 東京理科大学, 理工学部先端化学科, 講師 (30451751)
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Research Collaborator |
TSURUTA Ryohei
HIKASA Masataka
YAMANAKA Soichiro
YOSHIDA Koki
MORI Toshiaki
MIZUNO Yuta
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Project Period (FY) |
2015-04-01 – 2018-03-31
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Project Status |
Completed (Fiscal Year 2017)
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Budget Amount *help |
¥25,220,000 (Direct Cost: ¥19,400,000、Indirect Cost: ¥5,820,000)
Fiscal Year 2017: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
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Keywords | 半導体デバイス / ギャップ内準位 / 有機半導体 / 光電子分光 / 光電子収量分光 / 電子バンド / エピタキシャル成長 / モデル界面 / 分子性固体 / 表面・界面物性 / 有機エレクトロニクス / 有機単結晶 / 価電子バンド / 有機無機ペロブスカイト / エピタキシー / 光電子収量分光法 / 有機半導体単結晶 / ペンタセン / フラーレン / X線光電子分光法 / 真空劈開 / 微小角入射X線回折法 / X線反射率法 / ヘテロエピタキシャル成長 |
Outline of Final Research Achievements |
While organic electronic devices have undergone rapid paced progress, fundamental mechanisms of charge carrier transport is still under debate mainly because of insufficient knowledge on the electronic structures of organic semiconductor materials. This study has targeted at complete demonstration of the electronic states which contribute to the charge carrier transport in the organic semiconductor materials through development of original photoemission measurement techniques of high-precision and high-sensitivity. As a representative achievement, valence band dispersion of the single crystal pentacene, a proto-typical p-type organic semiconductor molecule, were experimentally figured out for the first time. Inter-molecular transfer integral and the effective mass of conductive holes were derived from the present results, which suggests an intermediate character of the charge carrier transport between inter-molecular hopping of localized particles and continuous propagation of waves.
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Report
(4 results)
Research Products
(78 results)
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[Journal Article] Epitaxial growth of an organic pn-heterojunction: C60 on single crystal pentacene2016
Author(s)
Yasuo Nakayama, Yuta Mizuno, Takuya Hosokai, Tomoyuki Koganezawa, Ryohei Tsuruta, Alexander Hinderhofer, Alexander Gerlach, Katharina Broch, Valentina Belova, Heiko Frank, Masayuki Yamamoto, Jens Niederhausen, Hendrik Glowatzki, Jurgen P. Rabe, Norbert Koch, Hisao Ishii, Frank Schreiber, Nobuo Ueno
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Journal Title
ACS Applied Materials & Interfaces
Volume: 8
Issue: 21
Pages: 13499-13505
DOI
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Presentation] Intrinsic Electronic Structures of the Single Crystal Pentacene2017
Author(s)
Masataka Hikasa, Koki Yoshida, Matthias Meissner, Mimi Murata, Yuta Mizuno, Keiichirou Yonezawa, Kazuhiko Mase, Shinichiro Ideta, Kiyohisa Tanaka, Nobuo Ueno, Takahiro Ueba, Satoshi Kera, Yasuo Nakayama
Organizer
Materials Research Society 2017 Fall Meeting; Boston (USA)
Related Report
Int'l Joint Research
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[Presentation] Electronic Structures of Methylammonium Lead Trihalide Single Crystals Probed by X-ray and Ultraviolet Photoemission2017
Author(s)
Soichiro Yamanaka, Ko Tonami, Masataka Hikasa, Ryohei Tsuruta, Koki Yoshida, Kazuhiko Mase, Shinichiro Ideta, Kiyohisa Tanaka, Koji Yamada, Hiroyuki Yoshida, Yasuo Nakayama
Organizer
The 8th International Symposium on Surface Science and Nanotechnology (ISSS-8); Tsukuba (Japan)
Related Report
Int'l Joint Research
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[Presentation] Valence Electronic Structures of the CH3NH3PbI3 Single Crystal2017
Author(s)
Soichiro Yamanaka, Ko Tonami, Masataka Hikasa, Ryohei Tsuruta, Koki Yoshida, Kazuhiko Mase, Shinichiro Ideta, Kiyohisa Tanaka, Koji Yamada, Hiroyuki Yoshida, Yasuo Nakayama
Organizer
The 9th International Workshop on Electronic Structure and Processes at Molecular-based Interfaces (ESPMI 9); Singapore (Singapore)
Related Report
Int'l Joint Research
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[Presentation] C60 Overlayer Epitaxial Grows on Rubrene Single Crystal2017
Author(s)
Ryohei Tsuruta, Yuta Togami, Kento Imai, Yuta Mizuno, Soichiro Yamanaka, Toshiaki Mori, Koki Yoshida, Tomoyuki Koganezawa, Takuya Hosokai, Yasuo Nakayama
Organizer
The 8th International Symposium on Surface Science and Nanotechnology (ISSS-8); Tsukuba (Japan)
Related Report
Int'l Joint Research
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[Presentation] Functional Organic and Organic-Inorganic-Hybrid Materials Studied by Excitation Energy Dependence of the X-ray Photoelectron Spectroscopy2016
Author(s)
Yasuo Nakayama, Yuta Mizuno, Soichiro Yamanaka, Tomoya Sato, Ryohei Tsuruta, Yuki Uragami, Masayuki Yamamoto, Keiichirou Yonezawa, Kei Hayakawa, Ludmila Cojocaru, Satoshi Kera, Nobuo Ueno, Satoshi Uchida, Hisao Ishii, Kazuhiko Mase
Organizer
The 8th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications (ASOMEA8)
Place of Presentation
岡崎コンファレンスセンター(岡崎市)
Year and Date
2016-11-23
Related Report
Int'l Joint Research / Invited
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[Presentation] Valence Band Structures of the Pentacene Single Crystal2016
Author(s)
Masataka Hikasa, Yuta Mizuno, Shinichiro Ideta, Kiyohisa Tanaka, Hisao Ishii, Yasuo Nakayama
Organizer
The 8th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications (ASOMEA8)
Place of Presentation
岡崎コンファレンスセンター(岡崎市)
Year and Date
2016-11-23
Related Report
Int'l Joint Research
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[Presentation] Heteroepitaxial Organic pn-junction: C60 on the pentacene single crystal2016
Author(s)
Yasuo Nakayama, Yuta Mizuno, Takuya Hosokai, Tomoyuki Koganezawa, Ryohei Tsuruta, Alexander Hinderhofer, Alexander Gerlach, Katharina Broch, Valentina Belova, Heiko Frank, Masayuki Yamamoto, Jens Niederhausen, Hendrik Glowatzki, Jurgen P. Rabe, Norbert Koch, Hisao Ishii, Frank Schreiber, Nobuo Ueno
Organizer
EMN (Energy Materials Nanotechnology) Organic Electronics and Photonics Meeting
Place of Presentation
San Sebastian (Spain)
Year and Date
2016-09-11
Related Report
Int'l Joint Research / Invited
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[Presentation] Heteroepitaxy of C60 on the Pentacene Single Crystal Surface2016
Author(s)
Yuta Mizuno, Takuya Hosokai, Tomoyuki Koganezawa, Ryohei Tsuruta, Alexander Hinderhofer, Alexander Gerlach, Katharina Broch, Valentina Belova, Heiko Frank, Masayuki Yamamoto, Hisao Ishii, Frank Schreiber, Nobuo Ueno, Yasuo Nakayama
Organizer
The 18th International Conference on Crystal Growth and Epitaxy (ICCGE-18)
Place of Presentation
名古屋国際会議場(名古屋市)
Year and Date
2016-08-11
Related Report
Int'l Joint Research
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[Presentation] ペンタセン単結晶上C60ヘテロエピタキシャル構造の精密決定2016
Author(s)
中山泰生,水野裕太,鶴田諒平,細貝拓也,小金澤智之,山本真之,Alexander Hinderhofer, Alexander Gerlach, Heiko Frank, Frank Schreiber, 石井久夫,上野信雄
Organizer
第63回応用物理学会春季学術講演会
Place of Presentation
東京工業大学(東京都目黒区)
Year and Date
2016-03-22
Related Report
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[Presentation] Core and valence electronic structures of pentacene single crystal2015
Author(s)
Yasuo Nakayama, Yuta Mizuno, Masayuki Yamamoto, Masataka Hikasa, Yuki Uragami, Keiichirou Yonezawa, Kazuhiko Mase, Satoshi Kera, Masaharu Matsunami, Shinichiro Ideta, Kiyohisa Tanaka, Hisao Ishii, and Nobuo Ueno
Organizer
The 3rd Workshop on Physics in Organic Optoelectronics (Joint JSPS-NSFC research program)
Place of Presentation
自然科学研究機構(愛知県岡崎市)
Year and Date
2015-12-10
Related Report
Int'l Joint Research / Invited
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[Presentation] Core-levels and Valence Band Electronic Structures of the Pentacene Single Crystal2015
Author(s)
Yasuo Nakayama, Masayuki Yamamoto, Yuta Mizuno, Yuki Uragami, Keiichirou Yonezawa, Hiroumi Kinjo, Kazuhiko Mase, Masaharu Matsunami, Satoshi Kera, Hisao Ishii, Nobuo Ueno
Organizer
Eighth international conference on molecular electronics and bioelectronics (M&BE8)
Place of Presentation
タワーホール船堀(東京都江戸川区)
Year and Date
2015-06-23
Related Report
Int'l Joint Research
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