• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Magnesium Rechargeable Battery Based on Electrode/electrolyte Interface Reaction Analysis

Research Project

Project/Area Number 15H05500
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Device related chemistry
Research InstitutionRitsumeikan University (2016-2017)
Kyoto University (2015)

Principal Investigator

Orikasa Yuki  立命館大学, 生命科学部, 准教授 (20589733)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥24,570,000 (Direct Cost: ¥18,900,000、Indirect Cost: ¥5,670,000)
Fiscal Year 2017: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2016: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2015: ¥13,260,000 (Direct Cost: ¥10,200,000、Indirect Cost: ¥3,060,000)
Keywords二次電池 / マグネシウム / 電極/電解質界面 / マグネシウム二次電池 / 正極材料 / 充放電特性 / 蓄電池 / 無機工業化学 / 電気化学
Outline of Final Research Achievements

Magnesium rechargeable batteries are expected as one of the candidates for next-generation batteries. However, magnesium ions, which are divalent ions, are difficult to diffuse in solids, and at present, there are no positive electrode materials comparable to lithium-ion battery electrodes. In this study, by using composite structure between carbon and active nano-materials enables stable magnesium ion insertion/extraction. Analysis of the reaction mechanism in the composite electrode, during magnesium ion insertion/extraction reaction, the middle range of ordering structure is maintained, which contributes the good cycle performance. We have developed a new electrode design guideline that can overcome the drawbacks of the multi-valent battery electrode.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (22 results)

All 2018 2017 2016 2015 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 1 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 7 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Surface analysis of topmost layer of epitaxial layered oxide thin film: Application to delafossite oxide for oxygen evolution reaction2018

    • Author(s)
      Toyoda Kenji、Adachi Hideaki、Miyata Nobuhiro、Hinogami Reiko、Orikasa Yuki、Uchimoto Yoshiharu
    • Journal Title

      Surface Science

      Volume: 668 Pages: 93-99

    • DOI

      10.1016/j.susc.2017.10.018

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge-Discharge Property of Non-Stoichiometric Lithium Iron Silicate2017

    • Author(s)
      R. Matsui, M. Katayama, Y. Inada, Y. Orikasa
    • Journal Title

      ECS Transactions

      Volume: 80 Issue: 10 Pages: 111-116

    • DOI

      10.1149/08010.0111ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and Electronic-State Changes of a Sulfide Solid Electrolyte during the Li Deinsertion-Insertion Processes2017

    • Author(s)
      Hakari Takashi、Deguchi Minako、Mitsuhara Kei、Ohta Toshiaki、Saito Kohei、Orikasa Yuki、Uchimoto Yoshiharu、Kowada Yoshiyuki、Hayashi Akitoshi、Tatsumisago Masahiro
    • Journal Title

      Chemistry of Materials

      Volume: 29 Issue: 11 Pages: 4768-4774

    • DOI

      10.1021/acs.chemmater.7b00551

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In operando quantitation of Li concentration for a commercial Li-ion rechargeable batteryusing high-energy X-ray Compton scattering2017

    • Author(s)
      Kosuke Suzuki, Ayahito Suzuki, Taiki Ishikawa, Masayoshi Itou, Hisao Yamashige, Yuki Orikasa, Yoshiharu Uchimoto, Yoshiharu Sakurai and Hiroshi Sakurai
    • Journal Title

      J. Synchrotron Rad.

      Volume: 24 Issue: 5 Pages: 1006-1011

    • DOI

      10.1107/s1600577517010098

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hidden Two-Step Phase Transition and Competing Reaction Pathways in LiFePO42017

    • Author(s)
      Y. Koyama, T. Uyama, Y. Orikasa, T. Naka, H. Komatsu, K. Shimoda, H. Murayama, K. Fukuda, H. Arai, E. Matsubara, Y. Uchimoto, Z. Ogumi
    • Journal Title

      Chem. Mater.

      Volume: 29 Issue: 7 Pages: 2855-2863

    • DOI

      10.1021/acs.chemmater.6b05000

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anti-site mixing governs the electrochemical performances of olivine-type MgMnSiO4 cathodes for rechargeable magnesium batteries2016

    • Author(s)
      T. Mori, T. Masese, Y. Orikasa, Z.D. Huang, T. Okado, J. Kim, Y. Uchimoto
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 19 Pages: 13524-13529

    • DOI

      10.1039/c6cp00448b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Discharge/charge reaction mechanisms of FeS2 cathode material for aluminum rechargeable batteries at 55°C2016

    • Author(s)
      T. Mori, Y. Orikasa, K. Nakanishi, C. Kezheng, M. Hattori, T. Ohta, Y. Uchimoto
    • Journal Title

      J. Power Sources

      Volume: 313 Pages: 9-14

    • DOI

      10.1016/j.jpowsour.2016.02.062

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ionic Conduction in Lithium Ion Battery Composite Electrode Governs Cross-sectional Reaction Distribution2016

    • Author(s)
      Y. Orikasa, Y. Gogyo, H. Yamashige, M. Katayama, K.Z. Chen, T. Mori, K. Yamamoto, T. Masese, Y. Inada, T. Ohta, Z. Siroma, S. Kato, H. Kinoshita, H. Arai, Z. Ogumi, Y. Uchimoto
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 26382-26382

    • DOI

      10.1038/srep26382

    • NAID

      120005770751

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Operando X-ray Analysis of Hierarchical Reaction in Lithium-ion Battery2017

    • Author(s)
      Yuki Orikasa
    • Organizer
      International Battery Association 2017
    • Place of Presentation
      奈良春日野国際フォーラム(奈良県・奈良市)
    • Year and Date
      2017-03-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Advanced Analysis of Nonequilibrium Phase Transition between LiFePO4 and FePO4 during Battery Operation2017

    • Author(s)
      Yuki Orikasa
    • Organizer
      41th International Conference and Exposition on Advanced Ceramics and Composites
    • Place of Presentation
      アメリカ フロリダ
    • Year and Date
      2017-01-24
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Current Stage of Positive Electrode for Magnesium Rechargeable Battery2017

    • Author(s)
      Yuki Orikasa
    • Organizer
      International union of materials research society-International conference of advanced materials (IUMRS-ICAM) 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] X線吸収分光法を用いたリチウムイオン二次電池反応機構解明2017

    • Author(s)
      折笠 有基
    • Organizer
      日本分光学会 関西支部 2017年度講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Reaction Distribution Analysis on Lithium-Ion Battery Electrode2017

    • Author(s)
      Yuki Orikasa
    • Organizer
      The 9th Asian Conference on Electrochemical Power Sources 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Charge-discharge Mechanism of Nonstoichiometric Lithium Iron Silicate2017

    • Author(s)
      Ryoji Matsui, Junya Furutani, Keisuke Yamanaka, Koji Nakanishi, Misaki Katayama, Yasuhiro Inada, Toshiaki Ohta, and Yuki Orikasa
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnesium Rechargeable Battery using Polyanion Compound Cathode and Ether-Based Electrolyte2016

    • Author(s)
      Yuki Orikasa, Yoshiharu Uchimoto
    • Organizer
      1st International Symposium on Magnesium Batteries
    • Place of Presentation
      ドイツ ウルム
    • Year and Date
      2016-07-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 放射光を用いた蓄電池研究の最前線2016

    • Author(s)
      折笠 有基
    • Organizer
      立命館大学SRセンター研究成果報告会
    • Place of Presentation
      立命館大学びわこ・くさつキャンパス(滋賀県・草津市)
    • Year and Date
      2016-06-11
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] オペランド軟X線吸収分光法によるマグネシウム二次電池負極の負極・電解質界面における反応機構解析2016

    • Author(s)
      服部 将司,山本 健太郎,森 拓弥,折笠 有基,中西 康次,谷田 肇,下田 景二,森 正弘,小山 幸典,為則 雄祐,内本 喜晴
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学 吹田キャンパス
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] その場軟X線吸収分光法を用いたマグネシウム二次電池負極の反応支配因子解明2015

    • Author(s)
      服部将司, 山本健太郎, 森拓弥, 折笠有基, 中西康次, 谷田肇, 下田景二, 森正弘, 小山幸典, 為則雄祐, 小久見善八, 内本喜晴
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知産業労働センター
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Operando X-ray absorption spectroscopic study on magnesium metal anode reaction for magnesium rechargeable battery2015

    • Author(s)
      Masashi Hattori, Kentaro Yamamoto, Koji Nakanishi, Takuya Mori, Titus Masese, Yuki Orikasa, Yukinori Koyama, Zempachi Ogumi, Yoshiharu Uchimoto
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction Mechanism of Magnesium Deposition/dissolution for Magnesium Rechargeable Battery2015

    • Author(s)
      Masashi Hattori, Kentaro Yamamoto, Takuya Mori, Yuki Orikasa, Koji Nakanishi, Hajime Tanida, Yusuke Tamenori, Keiji Shimoda, Masahiro Mori, Yukinori Koyama, Zempachi Ogumi, Yoshiharu Uchimoto
    • Organizer
      The 8th Asian Conference on Electrochemical Power Sources
    • Place of Presentation
      Kunming, China
    • Year and Date
      2015-08-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Book] ポストリチウムに向けた革新的二次電池の材料開発2018

    • Author(s)
      境 哲男(監修)
    • Total Pages
      344
    • Publisher
      エヌ・ティー・エス
    • ISBN
      4860435230
    • Related Report
      2017 Annual Research Report
  • [Remarks] 研究内容

    • URL

      http://www.rits-electrochemistry.com/invastigation/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-08-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi