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Treatment of wastewater with highly concentrated organic compounds using multiple plasmas generated within gas bubbles

Research Project

Project/Area Number 15H05516
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Power engineering/Power conversion/Electric machinery
Research InstitutionTokyo Institute of Technology

Principal Investigator

Takeuchi Nozomi  東京工業大学, 工学院, 准教授 (80467018)

Project Period (FY) 2015-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥21,060,000 (Direct Cost: ¥16,200,000、Indirect Cost: ¥4,860,000)
Fiscal Year 2016: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Fiscal Year 2015: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
KeywordsOHラジカル / 促進酸化処理 / 水中気泡内プラズマ / 高濃度有機排水 / 気液界面プラズマ
Outline of Final Research Achievements

Plasma generated within oxygen gas bubbles was used for the decomposition of persistent organic compounds in water. The plasma was generated at 21 treatment holes in parallel, and hydrogen peroxide and ozone were selectively generated in each hole. In addition to the OH radicals generated by the plasma directly, OH radicals generated by the reaction involving hydrogen peroxide and ozone were effectively used for the decomposition of organic compounds. This plasma treatment achieved a higher energy efficiency and a higher decomposition rate than other plasma methods. Quantitative estimation of the amount of OH radical in water was also achieved using a chemical probe. Furthermore, the generation mechanism of hydrogen peroxide in plasma with liquid electrode was revealed by a numerical simulation model.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • Research Products

    (15 results)

All 2017 2016 2015 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] Quantitative Estimation of OH Radicals Reacting in Liquid Using a Chemical Probe for Plasma in Contact with Liquid2016

    • Author(s)
      D. Shiraki, N. Ishibashi, and N. Takeuchi
    • Journal Title

      IEEE Transactions on Plasma Science

      Volume: 44 Issue: 12 Pages: 3158-3163

    • DOI

      10.1109/tps.2016.2603157

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Investigation of the loss mechanisms of hydroxyl radicals in the decomposition of organic compounds using plasma generated over water2015

    • Author(s)
      Nozomi Takeuchi, Mizuki Ando, and Koichi Yasuoka
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 11 Pages: 116201-116201

    • DOI

      10.7567/jjap.54.116201

    • NAID

      210000145834

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 多並列水中気泡内交流プラズマによる酢酸分解2017

    • Author(s)
      竹内希,石橋直人
    • Organizer
      平成29年電気学会全国大会
    • Place of Presentation
      富山大学
    • Year and Date
      2017-03-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Efficient Decomposition of Persistent Organic Compounds in Water by Plasma-Liquid Interfacial Reaction2016

    • Author(s)
      N. Takeuchi and H. Eto
    • Organizer
      2016 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, Massachusetts
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 気液界面プラズマの水処理応用の現状と課題2016

    • Author(s)
      竹内希
    • Organizer
      第32回九州・山口プラズマ研究会
    • Place of Presentation
      佐賀大学
    • Year and Date
      2016-11-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 水中気泡内プラズマにおける活性種の選択的生成を用いた酢酸の分解2016

    • Author(s)
      石橋直人,杉山剛志, 竹内希
    • Organizer
      電気学会プラズマ/パルスパワー/放電合同研究会
    • Place of Presentation
      佐賀大学
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] Advanced Oxidation Process Using Plasmas within Gas Bubbles2016

    • Author(s)
      T. Sugiyama, N. Ishibashi, and N. Takeuchi
    • Organizer
      ICFD 2016
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Accurate Quantification of Hydroxyl Radicals Produced by Plasma Using Disodium Terephthalate Solution2016

    • Author(s)
      D. Shiraki and N. Takeuchi
    • Organizer
      ICOPS 2016
    • Place of Presentation
      Banff, Alberta, Canada
    • Year and Date
      2016-06-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characteristics of Reactive Species Produced by AC Plasma Generated in Gas Bubbles2016

    • Author(s)
      T. Sugiyama and N. Takeuchi
    • Organizer
      ICOPS 2016
    • Place of Presentation
      Banff, Alberta, Canada
    • Year and Date
      2016-06-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Decomposition of Persistent Organic Compounds Using Plasmas Generated in Solution2016

    • Author(s)
      T. Sugiyama, H. Eto, and N. Takeuchi
    • Organizer
      SPM-4
    • Place of Presentation
      Pilsen, Czech Republic
    • Year and Date
      2016-06-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] テレフタル酸ナトリウムを用いた液相OH ラジカルの生成量の精査2016

    • Author(s)
      白木大地,竹内希
    • Organizer
      電気学会プラズマ/パルスパワー/放電合同研究会
    • Place of Presentation
      岩手大学
    • Year and Date
      2016-05-26
    • Related Report
      2016 Annual Research Report
  • [Presentation] Investigation of the Generation of Mechanism of Hydroxyl Radicals in Plasma in Contact with Liquid by Using Radical Scavengers2015

    • Author(s)
      Daichi Shiraki and Nozomi Takeuchi
    • Organizer
      APSPT-9/SPSM-28
    • Place of Presentation
      Nagasaki, Japan
    • Year and Date
      2015-12-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characteristics of Reactive Species Production in AC Plasma Generated within Bubbles2015

    • Author(s)
      Tsuyoshi Sugiyama, Daichi Shiraki, and Nozomi Takeuchi
    • Organizer
      APSPT-9/SPSM-28
    • Place of Presentation
      Nagasaki, Japan
    • Year and Date
      2015-12-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Generation Mechanisms of Hydroxyl Radical and Hydrogen Peroxide in Plasma Generated over Solution2015

    • Author(s)
      Nozomi Takeuchi, Naoto Ishibashi, and Daichi Shiraki
    • Organizer
      GEC-68/ICRP-9
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2015-10-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 東京工業大学 工学院 電気電子系 安岡・竹内研ホームページ

    • URL

      http://www.plasma.ee.titech.ac.jp/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2018-03-22  

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