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Development of flexible energy-storage paper devices

Research Project

Project/Area Number 15H05627
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Wood science
Research InstitutionOsaka University

Principal Investigator

Koga Hirotaka  大阪大学, 産業科学研究所, 特任助教(常勤) (30634539)

Project Period (FY) 2015-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥23,920,000 (Direct Cost: ¥18,400,000、Indirect Cost: ¥5,520,000)
Fiscal Year 2017: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2015: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Keywordsペーパーエレクトロニクス / 蓄電紙 / 機能紙 / 酸化グラフェン / 抄紙技術 / 光還元 / スーパーキャパシタ / ナノセルロース / パルプ / ナノカーボン / イオン液体 / 多孔質材料 / 蓄電デバイス / ナノ構造 / マイクロ構造
Outline of Final Research Achievements

Recent progress in portable and wearable electronics has promoted a growing demand for affordable and flexible energy-storage devices. Although reduced graphene oxide (rGO) serves as high performance electrode, rGO-based flexible electrodes remain challenging with respect to scalability and eco-friendliness concerning both the compositing process of rGO with a flexible matrix and the reduction process of GO.
In this study, we demonstrated that papermaking and successive in situ flash-reduction can be prospective to achieve this goal. Single-layer GO sheets were composited with wood-derived cellulose paper (even with waste paper) by a papermaking process with a filtration time of 4 s, followed by a room-temperature and chemical-free flash reduction process for 0.036 s. The rGO/paper electrodes showed high specific capacitance, up to 212 F/g, for a paper-based supercapacitor. This finding opens new doors for affordable and flexible energy-storage papers in future wearable electronics.

Report

(4 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • Research Products

    (58 results)

All 2018 2017 2016 2015 Other

All Journal Article (9 results) (of which Peer Reviewed: 4 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (36 results) (of which Int'l Joint Research: 9 results,  Invited: 24 results) Book (10 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Ionic liquid-mediated dispersion and support of functional molecules on cellulose fibers for stimuli-responsive chromic paper devices2017

    • Author(s)
      H. Koga, M. Nogi, A. Isogai
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 9(46) Issue: 46 Pages: 40914-40920

    • DOI

      10.1021/acsami.7b14827

    • NAID

      120006955461

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Renewable wood pulp paper reactor with hierarchical micro/nanopores for continuous-flow nanocatalysis2017

    • Author(s)
      H. Koga, N. Namba, T. Takahashi, M. Nogi, Y. Nishina
    • Journal Title

      ChemSusChem

      Volume: 10(12) Issue: 12 Pages: 2560-2565

    • DOI

      10.1002/cssc.201700576

    • NAID

      120006955457

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A High-sensitivity printed antenna prepared by rapid low-temperature sintering of silver ink2016

    • Author(s)
      Hirotaka Koga, Tetsuji Inui, Itaru Miyamoto, Takuya Sekiguchi, Masaya Nogi, Katsuaki Suganuma
    • Journal Title

      RSC Advance

      Volume: 6 Issue: 87 Pages: 84363-84368

    • DOI

      10.1039/c6ra19687j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 紙で作る最先端機能材料2016

    • Author(s)
      古賀大尚
    • Journal Title

      加工技術

      Volume: 51 Pages: 344-350

    • NAID

      40020866823

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Paper Electronics Based on Nanocellulose2016

    • Author(s)
      古賀大尚
    • Journal Title

      NIHON GAZO GAKKAISHI (Journal of the Imaging Society of Japan)

      Volume: 55 Issue: 3 Pages: 361-368

    • DOI

      10.11370/isj.55.361

    • NAID

      130005156450

    • ISSN
      1344-4425, 1880-4675
    • Related Report
      2016 Annual Research Report
  • [Journal Article] Fast, Scalable, and Eco-Friendly Fabrication of an Energy Storage Paper Electrode2016

    • Author(s)
      Koga H., Tonomura H., Nogi M., Suganuma K. and Nishina Y.
    • Journal Title

      Green Chemistry

      Volume: 18 Issue: 4 Pages: 1117-1124

    • DOI

      10.1039/c5gc01949d

    • NAID

      120006955456

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of Paper Electronics by Using Paper-Specific Properties2015

    • Author(s)
      古賀大尚
    • Journal Title

      Annals of the High Performance Paper Society, Japan

      Volume: 54 Issue: 0 Pages: 37-41

    • DOI

      10.11332/kinoushi.54.37

    • NAID

      130005145518

    • ISSN
      0288-5867, 2187-2740
    • Related Report
      2016 Annual Research Report
  • [Journal Article] ナノカーボン/ナノペーパーエレクトロニクス2015

    • Author(s)
      古賀大尚
    • Journal Title

      光アライアンス

      Volume: 26 Pages: 10-14

    • Related Report
      2015 Annual Research Report
  • [Journal Article] 紙の高誘電率化による小型フレキシブルペーパーアンテナの開発2015

    • Author(s)
      古賀大尚、能木雅也
    • Journal Title

      機能材料

      Volume: 35 Pages: 33-38

    • Related Report
      2015 Annual Research Report
  • [Presentation] Structural design of cellulose paper composites for green chemistry and electronics2018

    • Author(s)
      H. Koga
    • Organizer
      255th ACS National Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of hierarchical micro-meso-macro porous structures in a cellulose nanofiber paper for electrode applications2018

    • Author(s)
      D. Fukushima, H. Koga, M. Nogi
    • Organizer
      The 21st SANKEN International The 16th SANKEN Nanotechnology Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノセルロースで実現するグリーンケミストリー・エレクトロニクス2018

    • Author(s)
      古賀大尚
    • Organizer
      高分子学会、高分子同友会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ナノセルロースを用いた革新的機能紙の開発2018

    • Author(s)
      古賀大尚
    • Organizer
      繊維加工技術研究会第54回講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] フレキシブルエレクトロニクス応用に向けたセルロースナノペーパー開発最前線2018

    • Author(s)
      古賀大尚
    • Organizer
      ネプコンジャパン、プリント配線板EXPO
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] リサイクル可能な固定化触媒ペーパーリアクターの開発2017

    • Author(s)
      古賀大尚、高橋司、能木雅也、仁科勇太
    • Organizer
      第67回日本木材学会大会
    • Place of Presentation
      福岡
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 紙のリノベーション ~CNFの触媒・電子材料応用~2017

    • Author(s)
      古賀大尚
    • Organizer
      ふじのくにCNFフォーラム 第5回技術講演会
    • Place of Presentation
      浜松
    • Year and Date
      2017-03-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーと無機ナノ物質の複合技術と応用2017

    • Author(s)
      古賀大尚
    • Organizer
      生産技術振興協会アライアンス委員会 ナノ技術応用分科会講演会
    • Place of Presentation
      大阪
    • Year and Date
      2017-02-28
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] High frequency characteristics of printed silver nanowire transmission line2017

    • Author(s)
      Y. Kakuya, H. Dawei, H. Koga, K. Suganuma
    • Organizer
      12th IEEE Nanotechnology Materials and Devices Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノセルロースによるグリーンデバイスの創出2017

    • Author(s)
      古賀大尚
    • Organizer
      第33回FPDフォーラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 紙の材料・構造再設計による新機能創発2017

    • Author(s)
      古賀大尚
    • Organizer
      第5回アライアンス若手研究交流会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] セルロースナノファイバーを用いたグリーンエレクトロニクスの創出2017

    • Author(s)
      古賀大尚
    • Organizer
      日本繊維機械学会、第69回不織布研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] セルロース繊維と無機ナノ材料の複合化による紙の新機能創発2017

    • Author(s)
      古賀大尚
    • Organizer
      セルロース学会第24回年次大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 紙を用いた化成品合成・デバイス開発戦略2017

    • Author(s)
      古賀大尚
    • Organizer
      ファインケミカルジャパン
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 木材ナノセルロースで実現するグリーンエレクトロニクス2017

    • Author(s)
      古賀大尚
    • Organizer
      ファインテック PEフォーラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Paper Composites for Flexible and Disposable Electronics2016

    • Author(s)
      H. Koga, K. Nagashima, Y. Nishina, T. Yanagida, M. Nogi
    • Organizer
      The 20th SANKEN International The 15th SANKEN Nanotechnology Symposium
    • Place of Presentation
      大阪
    • Year and Date
      2016-12-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 紙のリノベーションに向けて2016

    • Author(s)
      古賀大尚
    • Organizer
      セルロース学会 第21回ミクロシンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Highly Efficient and Recyclable Flow Reactor Based on Wood Pulp Paper Composites2016

    • Author(s)
      H. Koga, M. Nogi
    • Organizer
      ICGC-9
    • Place of Presentation
      神戸
    • Year and Date
      2016-11-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] セルロースナノファイバーのエレクトロニクス応用最前線2016

    • Author(s)
      古賀大尚
    • Organizer
      リグニン・セルロースの特性制御・製造・応用最前線
    • Place of Presentation
      大阪
    • Year and Date
      2016-09-28
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Reduced Graphene Oxide/Cellulose Paper Composite Electrode Prepared by Papermaking and Flash-Reduction Processes2016

    • Author(s)
      H. Koga, M. Nogi
    • Organizer
      ICFPE 2016
    • Place of Presentation
      米沢
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of Conductive Nanomaterials on Radio-waves Transmission Performance of Printed Antenna2016

    • Author(s)
      Y. Goya, H. Koga, M. Nogi, K. Suganuma
    • Organizer
      IEEE NANO 2016
    • Place of Presentation
      仙台
    • Year and Date
      2016-08-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 木材繊維と酸化グラフェンの複合化による蓄電紙の開発2016

    • Author(s)
      古賀大尚、能木雅也、菅沼克昭、仁科勇太
    • Organizer
      第83回紙パルプ研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2016-06-22
    • Related Report
      2016 Annual Research Report
  • [Presentation] セルロースナノファイバーでつくる最先端機能紙2016

    • Author(s)
      古賀大尚
    • Organizer
      日本化学会 R&D懇話会187回
    • Place of Presentation
      東京
    • Year and Date
      2016-06-03
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] プリンテッドアンテナに向けた導電ナノ物質の伝送特性解析2016

    • Author(s)
      合家勇輔、古賀大尚、能木雅也、菅沼克昭
    • Organizer
      第30回エレクトロニクス実装学会春季講演大会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 紙抄きとフラッシュ還元技術によるスーパーキャパシタ用ペーパー電極の開発2016

    • Author(s)
      古賀大尚、大籏英樹、内田博、能木雅也、菅沼克昭
    • Organizer
      第30回エレクトロニクス実装学会春季講演大会
    • Place of Presentation
      東京
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 紙が機能するフレキシブルエレクトロニクス2016

    • Author(s)
      古賀大尚
    • Organizer
      エレクトロニクス実装学会・プリンタブルデバイス実装研究会
    • Place of Presentation
      東京
    • Year and Date
      2016-01-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Paper Electronics for All Paper-Based Displays2015

    • Author(s)
      Koga H.
    • Organizer
      IDW’15
    • Place of Presentation
      Shiga
    • Year and Date
      2015-12-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ペーパーエレクトロニクスの開発と計測2015

    • Author(s)
      古賀大尚
    • Organizer
      先端計測開発センター講演会
    • Place of Presentation
      宮城
    • Year and Date
      2015-11-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 紙らしさを追求するペーパーエレクトロニクス開発2015

    • Author(s)
      古賀大尚
    • Organizer
      第54回機能紙研究会発表講演会
    • Place of Presentation
      香川
    • Year and Date
      2015-10-29
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 植物繊維を用いるバイオ・ペーパーエレクトロニクス2015

    • Author(s)
      古賀大尚
    • Organizer
      応用物理学会有機分子・バイオエレクトロニクス分科会
    • Place of Presentation
      長野
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 紙基板の誘電率制御によるフレキシブルアンテナの小型化2015

    • Author(s)
      乾哲治、古賀大尚、能木雅也、菅沼克昭
    • Organizer
      MES2015
    • Place of Presentation
      大阪
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 紙のナノ-マイクロ空間を活用するペーパーエレクトロニクス開発2015

    • Author(s)
      古賀大尚
    • Organizer
      印刷学会P&I研究会
    • Place of Presentation
      東京
    • Year and Date
      2015-07-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ナノセルロースペーパーコンポジットの開発とエレクトロニクス応用展開2015

    • Author(s)
      古賀大尚
    • Organizer
      第6回ナノファイバー学会
    • Place of Presentation
      東京
    • Year and Date
      2015-07-06
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Structural and Material Design of Cellulose Paper Composites2015

    • Author(s)
      Koga H. and Nogi M.
    • Organizer
      The 5th International Conference on Bio-based Polymers
    • Place of Presentation
      Singapore
    • Year and Date
      2015-06-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 紙内部の繊維積層空間を活用したペーパーエレクトロニクス開発2015

    • Author(s)
      古賀大尚、能木雅也
    • Organizer
      第82回紙パルプ研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2015-06-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] 紙ならではのフレキシブルデバイス開発2015

    • Author(s)
      古賀大尚
    • Organizer
      日本画像学会シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Book] セルロースナノファイバー~実用化に向けた製造・複合化・評価技術~, 第4章・第3節・第1項2018

    • Author(s)
      古賀大尚(分担執筆)
    • Total Pages
      266
    • Publisher
      情報機構
    • ISBN
      9784865021462
    • Related Report
      2017 Annual Research Report
  • [Book] Lignocellulosics 1st Edition, Renewable Feedstock for (Tailored) Functional Materials and Nanotechnology, Chapter 112018

    • Author(s)
      Hirotaka Koga(分担執筆)
    • Total Pages
      510
    • Publisher
      Elsevier
    • ISBN
      9780128040775
    • Related Report
      2017 Annual Research Report
  • [Book] プリンテッド・エレクトロニクスに向けた材料、プロセス技術の開発と最新事例, 第13章・第4節2017

    • Author(s)
      古賀大尚、外村英嗣、乾哲治、菅沼克昭、宮本格、関口卓也、名和成明(分担執筆)
    • Total Pages
      523
    • Publisher
      技術情報協会
    • ISBN
      9784861046810
    • Related Report
      2017 Annual Research Report
  • [Book] 機能紙最前線2017

    • Author(s)
      古賀大尚、能木雅也(分担執筆)
    • Total Pages
      350
    • Publisher
      加工技術研究会
    • Related Report
      2016 Annual Research Report
  • [Book] ナノセルロースの製造技術と応用2016

    • Author(s)
      古賀大尚(分担執筆)
    • Total Pages
      245
    • Publisher
      シーエムシー・リサーチ
    • Related Report
      2016 Annual Research Report
  • [Book] セルロースナノファイバー技術資料集2016

    • Author(s)
      古賀大尚(分担執筆)
    • Total Pages
      246
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Annual Research Report
  • [Book] バイオマス由来の高機能材料2016

    • Author(s)
      古賀大尚、能木雅也(分担執筆)
    • Total Pages
      312
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2016 Annual Research Report
  • [Book] 高機能フィルムの開発と応用(金井俊孝 編)2016

    • Author(s)
      古賀大尚、能木雅也
    • Total Pages
      303
    • Publisher
      シーエムシー出版
    • Related Report
      2015 Annual Research Report
  • [Book] Organic Electronics Materials and Devices, Shuichiro Ogawa (Ed.)2015

    • Author(s)
      Koga H. and Nogi M.
    • Total Pages
      245
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report
  • [Book] 図解よくわかるナノセルロース(ナノセルロースフォーラム 編)2015

    • Author(s)
      古賀大尚
    • Total Pages
      214
    • Publisher
      日刊工業新聞社
    • Related Report
      2015 Annual Research Report
  • [Remarks] 阪大セルロースナノファイバー研究-古賀大尚

    • URL

      http://kogahirotaka.com/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 阪大セルロースナノファイバー研究-特任助教古賀大尚

    • URL

      http://kogahirotaka.com/

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 導電性ナノセルロース集合体の製造方法2015

    • Inventor(s)
      古賀大尚、菅沼克昭、能木雅也、内田博、大籏英樹
    • Industrial Property Rights Holder
      古賀大尚、菅沼克昭、能木雅也、内田博、大籏英樹
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-170120
    • Filing Date
      2015-08-31
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2015-04-16   Modified: 2019-03-29  

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