| Budget Amount *help |
¥164,840,000 (Direct Cost: ¥126,800,000、Indirect Cost: ¥38,040,000)
Fiscal Year 2019: ¥25,610,000 (Direct Cost: ¥19,700,000、Indirect Cost: ¥5,910,000)
Fiscal Year 2018: ¥28,080,000 (Direct Cost: ¥21,600,000、Indirect Cost: ¥6,480,000)
Fiscal Year 2017: ¥39,260,000 (Direct Cost: ¥30,200,000、Indirect Cost: ¥9,060,000)
Fiscal Year 2016: ¥46,930,000 (Direct Cost: ¥36,100,000、Indirect Cost: ¥10,830,000)
Fiscal Year 2015: ¥24,960,000 (Direct Cost: ¥19,200,000、Indirect Cost: ¥5,760,000)
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| Outline of Final Research Achievements |
We have established basic theories to develop the beyond-Born-Oppenheimer chemistry and apply to explore novel chemical phenomena. The main results we have successfully studied include: 1) Mechanism of charge-separation dynamics and catalytic cycle of water splitting in Photo System II by Mn4CaO5 cluster in plants: We have also found what we call collision induced charge separation.2) Chemistry without potential energy surfaces: The dynamics in dense manifolds of quasi-degenerate electronic states has been scrutinized, in which the notion of neither adiabatic potential states nor potential energy surface lose their senses. A characteristic chemical bonding has been found in boron clusters, which we call the dynamical chemical bonds, based on what we call hyper-resonance.
3) Symmetry breaking in multi-dimensional nonadiabatic chemical dynamics: We have found a novel nonadiabatic interaction, which can distinguish right and left in molecular mirror symmetry.
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