| Project/Area Number |
15H06143
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | The University of Tokyo |
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Principal Investigator |
JIN XIONGJIE 東京大学, 大学院工学系研究科(工学部), 特任研究員 (00761412)
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| Project Period (FY) |
2015-08-28 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 担持金属ナノ粒子触媒 / 分子状酸素 / 脱水素 / 酸素化 / 芳香環形成反応 / 脱水素型クロスカップリング反応 / 担持金属触媒 / 脱水素反応 / 酸素化反応 / 脱水素型クロスカップリング |
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| Outline of Final Research Achievements |
In this study, several aerobic oxidative dehydrogenation reactions have successfully been developed using supported metal catalysts. For example, (1) Au/OMS-2-catalyzed dehydrogenation of β-heteroatom substituted ketones to the corresponding α,β-unsaturated ketones, (2) Au-Pd/LDH-catalyzed dehydrogenation of cyclohexanols and cyclohexanones to phenols, and (c) Au/Al2O3-catalyzed α-oxygenation of secondary and tertiary amines to the corresponding amides, have been successfully developed. These reactions utilize molecular oxygen as the terminal oxidant and produce water as the sole by-product, which demonstrates the environmentally benign nature of these reactions. A Pd/NiMgAl_LTH-catalyzed acceptorless dehydrogenative aromatization of cyclohexanols, cyclohexanones and cyclohexylamines has also been developed.
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