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Conversion of low carbonaceous materials into phenolic compounds by partial oxidation and hydrogenolysis

Research Project

Project/Area Number 15H06208
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Reaction engineering/Process system
Research InstitutionTokyo Institute of Technology

Principal Investigator

Fujitsuka Hiroyasu  東京工業大学, 物質理工学院, 助教 (90757105)

Project Period (FY) 2015-08-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsリグニン転換 / 部分酸化 / 水素化分解 / 単環フェノール類 / ベンゾフラン / 白金アルミナ / in-situ水素化分解 / 白金担持触媒 / メタノール分解 / 化学工学 / 反応工学 / 触媒・化学プロセス / バイオマス / リグニン / 部分酸化処理 / 反応速度解析
Outline of Final Research Achievements

Production of monophenolic compounds from lignin by using partial oxidation and hydrogenolysis in the absence of gaseous hydrogen addition. The weight change of lignin during oxidation was measured using temperature-programmed reaction method and the oxidation uptake rate was successfully formulated. To develop a new hydrogenation system, which requires no hydrogen addition, hydrogenation of benzofuran, which is model compound for depolymerized lignin, over platinum loaded catalyst in methanol solvent was examined. It was found that hydrogen production from methanol over platinum catalyst and hydrogenation of the furan moiety of benzofuran with hydrogen produced in-situ occur in this reaction system.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • Research Products

    (4 results)

All 2017 2016

All Presentation (4 results)

  • [Presentation] メタノールを水素源とした液相in-situ水素化分解反応によるベンゾフランのフェノール類への転換2017

    • Author(s)
      田村真樹、藤墳大裕、多湖輝興
    • Organizer
      第82回化学工学会年会
    • Place of Presentation
      第82回化学工学会年会
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] メタノールを水素源としたPt 担持アルミナ触媒によるリグニンモデル含酸素官能基の水素化分解2017

    • Author(s)
      藤墳大裕、田村真樹、多湖輝興
    • Organizer
      第12回バイオマス科学会議
    • Place of Presentation
      東京大学(東京)
    • Year and Date
      2017-01-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水素キャリア分解による水素を利用した リグニンモデル物質のin-situ 水素化分解2016

    • Author(s)
      藤墳大裕、田村真樹、多湖輝興
    • Organizer
      第46回石油・石油科学討論会
    • Place of Presentation
      京都リサーチパーク(京都)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] メタノールを水素源としたベンゾフランのin-situ水素化分解による単環フェノール類生成2016

    • Author(s)
      田村真樹、藤墳大裕、多湖輝興
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report

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Published: 2015-08-26   Modified: 2018-03-22  

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