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Solving the problem of zeolite synthesis utilizing layered silicate

Research Project

Project/Area Number 15H06425
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionHiroshima University

Principal Investigator

Tsunoji Nao  広島大学, 工学研究院, 助教 (40758166)

Project Period (FY) 2015-08-28 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords層状ケイ酸塩 / ゼオライト / 光触媒 / 触媒 / 多孔質材料 / 層状化合物 / 酸化触媒 / 分子ふるい / 多孔体 / 吸着材
Outline of Final Research Achievements

Zeolite like ordered microporous material having molecular sieving and tuned organic functional group was successfully synthesized by using layered silicate HUS. The effect of its property on the selective adsorption ability was investigated under vapor or solution phase adsorption experiments with single or multi components.
The grafting of various metal complexes with different functional group was performed and selective metallosilicate catalyst attempted to synthesis.
The catalytic property of metal species, that was immobilized by condensation reaction of surface silanol group of layered silicate with high surface density, was investigated by flow or batch catalytic oxidation-reduction reaction system using oxigen, water, hydrogen peroxide as an oxidant.

Report

(3 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • Research Products

    (32 results)

All 2017 2016 2015

All Journal Article (14 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 14 results,  Acknowledgement Compliant: 9 results,  Open Access: 4 results) Presentation (18 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Mesoporous MCM-48 immobilized with aminopropyltriethoxysilane: a potential catalyst for transesterification of triacetin2017

    • Author(s)
      Mahuya Bandyopadhyay, Nao Tsunoji, Tsuneji Sano
    • Journal Title

      Catal. Lett.

      Volume: 147 Issue: 4 Pages: 1040-1050

    • DOI

      10.1007/s10562-017-1997-5

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of epsilon-Keggin-Type Cobaltomolybdate-Based 3D Framework Material and Characterization Using Atomic-Scale HAADF-STEM and XANES2017

    • Author(s)
      Igarashi, T; Zhang, ZX; Haioka, T; Iseki, N; Hiyoshi, N; Sakaguchi, N; Kato, C; Nishihara, S; Inoue, K; Yamamoto, A; Yoshida, H; Tsunoji, N; Ueda, W; Sano, T; Sadakane, M
    • Journal Title

      INORGANIC CHEMISTRY

      Volume: 56 Issue: 4 Pages: 2042-2049

    • DOI

      10.1021/acs.inorgchem.6b02748

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Incorporation of various heterometal atoms in CHA zeolites by hydrothermal conversion of FAU zeolite and their performance for selective catalytic reduction of NOx with ammonia2017

    • Author(s)
      Tomoka Takata, Nao Tsunoji, Yasuyuki Takamitsu, Masahiro Sadakane, and Tsuneji Sano
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 246 Pages: 89-101

    • DOI

      10.1016/j.micromeso.2017.03.018

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] One-pot Synthesis of Phosphorus-modified AEI Zeolites Derived by the Dual-template Method as a Durable Catalyst with Enhanced Thermal/Hydrothermal Stability for Selective Catalytic Reduction of NO<i><sub>x</sub></i> by NH<sub>3</sub>2016

    • Author(s)
      Y. Kakiuchi, Y. Yamasaki, N. Tsunoji, Y. Takamitsu, M. Sadakane, T. Sano
    • Journal Title

      Chemistry Letters

      Volume: 45 Issue: 2 Pages: 122-124

    • DOI

      10.1246/cl.150997

    • NAID

      130005124756

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of phosphorus-modified small-pore zeolites utilizing tetraalkyl phosphonium cations as both structure-directing and phosphorous modification agents2016

    • Author(s)
      Y. Yamasaki, N. Tsunoji, Y. Takamitsu, M. Sadakane, T. Sano
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 223 Pages: 129-139

    • DOI

      10.1016/j.micromeso.2015.10.038

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanosized CHA zeolites with high thermal and hydrothermal stability derived from the hydrothermal conversion of FAU zeolite2016

    • Author(s)
      T.Takata, N.Tsunoji, Y.Takamitsu, M.Sadakane, T.Sano
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 225 Pages: 524-533

    • DOI

      10.1016/j.micromeso.2016.01.045

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Remarkable Charge Separation and Photocatalytic Efficiency Enhancement through Interconnection of TiO2 Nanoparticles by Hydrothermal Treatment2016

    • Author(s)
      Yusuke Ide, Nozomu Inami, Hideya Hattori, Kanji Saito, Minoru Sohmiya, Nao Tsunoji, Kenji Komaguchi, Tsuneji Sano, Yoshio Bando, Dmitri Golberg, Yoshiyuki Sugawara
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 11 Pages: 3600-3605

    • DOI

      10.1002/anie.201510000

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrothermal conversion of titanated FAU to AEI zeolite and its enhanced catalytic performance for NOx reduction2016

    • Author(s)
      N.Funase, T.Takata, N.Tsunoji,, Y.Takamitsu, M.Sadakane, T.Sano
    • Journal Title

      Adv. Porous Mater.

      Volume: 4 Issue: 1 Pages: 62-72

    • DOI

      10.1166/apm.2016.1101

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A BODIPY sensor for water based on a photo-induced electron transfer method with fluorescence enhancement and attenuation systems2016

    • Author(s)
      Yousuke Ooyama, Marin Hato, Toshiaki Enoki, Satoshi Aoyama, Kensuke Furue, Nao Tsunoji, Joji Ohshita
    • Journal Title

      New J. Chem.

      Volume: 40 Issue: 9 Pages: 7278-7281

    • DOI

      10.1039/c6nj01467d

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fe oxide nanoparticle/Ti-modified mesoporous silica as photocatalyst for efficient and selective cyclohexane conversion with O2 and solar light2016

    • Author(s)
      Yusuke Ide, Mikayo Iwata, Yuya Yagenji, Nao Tsunoji, Minoru Somiya, Kenji Komaguchi, Tsuneji Sano, Yoshiyuki Sugahara
    • Journal Title

      J. Mater. Chem. A

      Volume: 4 Issue: 41 Pages: 15892-15835

    • DOI

      10.1039/c6ta04222h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Encapsulation of two Potassium Cations in Preyssler-type Phosphotungstates: Preparation, Structural Characterization, Thermal Stability, Activity as an Acid Catalyst, and HAADF-STEM images2016

    • Author(s)
      Akio Hayashi, Hiromi Ota, Xavier Lopez, Norihito Hiyoshi, Nao Tsunoji, Tsuneji Sano, Masahiro Sadakane
    • Journal Title

      Inorg. Chem.

      Volume: 55 Issue: 21 Pages: 11583-11592

    • DOI

      10.1021/acs.inorgchem.6b02116

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Design of Microporous Material HUS-10 with Tunable Hydrophilicity, Molecular Sieving, and CO2 Adsorption Ability Derived from Interlayer Silylation of Layered Silicate HUS-22015

    • Author(s)
      Nao Tsunoji, Sota Yuki, Yasunori Oumi, Miyuki Sekikawa, Yukichi Sasaki, Masahiro Sadakane and Tsuneji Sano
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 7 Issue: 43 Pages: 24360-24369

    • DOI

      10.1021/acsami.5b07996

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly active and selective Ti-incorporated porous silica catalysts derived from grafting of titanium(IV) acetylacetonate2015

    • Author(s)
      7.Miki Fukuda, Nao Tsunoji, Yuya Yagenji, Yusuke Ide, Shinjiro Hayakawa, Masahiro Sadakane and Tsuneji Sano
    • Journal Title

      J. Mater. Chem. A

      Volume: 3 Issue: 29 Pages: 15280-15291

    • DOI

      10.1039/c5ta02975a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective catechol synthesis by TiO2 photocatalysis with the aid of a layered silicate adsorbent2015

    • Author(s)
      Yusuke Ide, Masato Torii, Nao Tsunoji, and Tsuneji Sano
    • Journal Title

      CLAY SCIENCE

      Volume: 19 Pages: 56-62

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] シリカ担体へのチタン錯体のグラフティングによる高活性チタノシリケート触媒の設計とシクロヘキサンの光触媒的部分酸化反応における性能評価2017

    • Author(s)
      西田英央、津野地直、井出裕介、薬研地祐也、定金正洋、佐野庸治
    • Organizer
      第119回触媒討論会
    • Place of Presentation
      首都大学東京 南大沢キャンパス、東京
    • Related Report
      2016 Annual Research Report
  • [Presentation] 種々の金属アセチルアセトナートのグラフティングによるメ タロシリケート触媒の合成とそのオレフィンのエポキシ化触媒としての性能評価2016

    • Author(s)
      藪下 翔、津野地直、薬研地裕也、佐野庸治、定金正洋
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学、京都
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 種々のシリカ担体を活用した高活性チタノシリケート触媒の設計2016

    • Author(s)
      津野地直、薬研地裕也、井出祐介、定金正洋、佐野庸治
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学、京都
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 層状ケイ酸塩 HUS を活用した高活性チタノシリケート触媒の設計2016

    • Author(s)
      津野地直、薬研地裕也、井出祐介、定金正洋、佐野庸治
    • Organizer
      第117回触媒討論会
    • Place of Presentation
      大阪府立大学、大阪
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] Design of Highly-active Titanosilicate Catalysts utilizing Grafting of Titanium(IV) Complex on the Surface of Various Silica Supports2016

    • Author(s)
      Nao Tsunoji, Masahiro Sadakane and Tsuneji Sano
    • Organizer
      5th Annual Symposium of Forum on Low-dimensional Photo-functional Materials
    • Place of Presentation
      Kagaku Kaikan, Tokyo, Japan
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Highly active and selective Ti-incorporated porous silica catalysts derived from grafting of titanium(IV) acetylacetona2016

    • Author(s)
      Nao Tsunoji, Miki Fukuda, Yuya Yagenji, Masahiro Sadakane, Tsuneji Sano
    • Organizer
      18th International Zeolite conference (IZC18)
    • Place of Presentation
      Rio de Janeiro, Brazil
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリカ担体表面へのグラフティング反応を活用した高活性チタノシリケート触媒設計2016

    • Author(s)
      津野地直、薬研地裕也、井出祐介、定金正洋、佐野庸治
    • Organizer
      石油学会 第59回年会(第65回研究発表会)
    • Place of Presentation
      タワーホール船堀、東京
    • Related Report
      2016 Annual Research Report
  • [Presentation] 種々のシリカ担体への四塩化チタンのグラフティングによる高活性チタノシリケート設計2016

    • Author(s)
      西田英央、津野地直、井出裕介、定金正洋、佐野庸治
    • Organizer
      日本化学会「低次元系光機能材料研究会」第5 回サマーセミナー in 島根
    • Place of Presentation
      美保館、島根県松江市
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高活性塩基触媒設計のための膨潤・剥離による層状ケイ酸塩層表面の有効活用2016

    • Author(s)
      津野地直、薬研地裕也、M. Bandypadhyay、定金正洋、佐野庸治
    • Organizer
      第46回石油・石油化学討論会
    • Place of Presentation
      京都リサーチパーク、京都
    • Related Report
      2016 Annual Research Report
  • [Presentation] 膨潤・剥離させた層状ケイ酸塩層表面の有効利用による高活性塩基触媒の設計2016

    • Author(s)
      津野地直、薬研地裕也、西田英央、M. Bandypadhyay、定金正洋、佐野庸治
    • Organizer
      第32回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀、東京
    • Related Report
      2016 Annual Research Report
  • [Presentation] High oxidation activity of Ti-incorporated silica catalysts derived by grafting of titanium(IV) acetylacetonate2015

    • Author(s)
      Nao Tsunoji, Yuya Yagenji, Miki Fukuda, Yusuke Ide, Masahiro Sadakane and Tsuneji Sano
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      Hyatt Regency Waikiki, Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 新規層状ケイ酸塩HUSを活用した吸着剤、多孔体および触媒の設計2015

    • Author(s)
      津野地直、佐野庸治
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館、鳥取
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新規層状ケイ酸塩HUS-7のピラー化による高活性チタノシリケート触媒の設計2015

    • Author(s)
      薬研地祐也、津野地直、井出祐介、定金正洋、佐野庸治
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館、鳥取
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] TiおよびFe固定化メソポーラスシリカ光触媒によるシクロヘキサンの選択酸化2015

    • Author(s)
      岩田三佳誉、井出裕介、宗宮穣、薬研地祐也、津野地直、佐野庸治、菅原義之
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館、鳥取
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 層状ケイ酸塩層間でのMOF構造の構築2015

    • Author(s)
      奥山泰樹、井出裕介、宗宮穣、津野地直、佐野庸治、菅原義之
    • Organizer
      第31回ゼオライト研究発表会
    • Place of Presentation
      とりぎん文化会館、鳥取
    • Year and Date
      2015-11-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新規層状ケイ酸塩HUS:高機能な吸着材および触媒のための構造設計2015

    • Author(s)
      津野地直、定金正洋、佐野庸治
    • Organizer
      2015年日本化学会中国四国支部大会
    • Place of Presentation
      岡山大学、岡山
    • Year and Date
      2015-11-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 層状ケイ酸塩HUS-7のピラー化による高活性チタノシリケート触媒の設計2015

    • Author(s)
      薬研地祐也、津野地直、井出裕介、定金正洋、佐野庸治
    • Organizer
      低次元系光機能材料研究会第4回サマーセミナー
    • Place of Presentation
      休暇村志賀島、福岡
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] 新規チタノシリケートナノシートを用いた高性能酸化触媒の設計とその触媒性能評価2015

    • Author(s)
      薬研地裕也、津野地直、井出祐介、定金正洋、佐野庸治
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学、三重
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report

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Published: 2015-08-26   Modified: 2018-03-22  

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