| Project/Area Number |
15H06737
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Ritsumeikan University |
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Principal Investigator |
Haketa Yohei 立命館大学, 総合科学技術研究機構, 研究員 (70757195)
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| Project Period (FY) |
2015-08-28 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | イオンペア集合体 / アニオンレセプター / π電子系 / 液晶 / 有機化学 / 超分子化学 / イオン |
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| Outline of Final Research Achievements |
Precise design of π-electronic ion pairs enabled the fabrication of highly organized dimension-controlled ion-pairing assemblies, including nanoscale specific morphologies, supramolecular gels, liquid crystals, etc. The π-electronic ion pairs were prepared by utilization of the receptor-anion complexes based on anion-responsive π-electronic molecules, and modified “genuine” π-electronic ions. Such π-electronic ion pairs afforded fine-tuned geometries and electronic states, which are suitable for ion-pairing assemblies. Appropriately designed ion-exchange conditions for such π-electronic ion pairs also enabled the fabrication of various π-electronic ion pairs. The π-electronic ion pairs afforded dimension-controlled assemblies as charge-by-charge and charge-segregated modes, exhibiting promising electronic properties such as charge-carrier transport behaviors.
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